133 research outputs found
Magnetocaloric properties of spheroidal La(Fe,Mn,Si)13Hy granules and their performance in epoxy-bonded active magnetic regenerators
Electromechanical Modulations in Transition Metal Dichalcogenide Nanosheets: Implications for Environmental Sensors
Transition metal dichalcogenides (TMDs) are key players in the two-dimensional materials nanoarena due to their exquisite optoelectronic properties under a standard environment (room temperature and atmospheric pressure). Nevertheless, as reported in the literature, they may also portray interesting physical properties under different environments. Here, we show two distinct and significant electromechanical modulations in TMD nanosheets which are tuned by the environmental conditions (applied pressure and adsorbents). Using scanning probe microscopy techniques, we modify the environmental conditions and observe steplike rises in the electrical response of all studied TMDs (MoS2, WS2, MoSe2, and WSe2—monolayers and few layers). Ab initio calculations enable full understanding of specific mechanisms behind these electromechanical modulations, which may find important applications in the design of TMD-based environmental sensors
Characterization of Metal Oxide-Based Gas Nanosensors and Microsensors Fabricated via Local Anodic Oxidation Using Atomic Force Microscopy
This work reports on nanoscale and microscale metal oxide gas sensors, consisting of metal-semiconductor-metal barriers designed via scanning probe microscopy. Two distinct metal oxides, molybdenum and titanium oxides, were tested at different temperatures using CO2 and H2 as test gases. Sensitivities down to ppm levels are demonstrated, and the influence of dry and humid working atmospheres on these metal oxide conductivities was studied. Furthermore, the activation energy was evaluated and analyzed within working sensor temperature range. Finally, full morphological, chemical, and structural analyses of the oxides composites are provided allowing their identification as MoO3 and Ti
Phyllosilicates as earth-abundant layered materials for electronics and optoelectronics: Prospects and challenges in their ultrathin limit
Phyllosilicate minerals are an emerging class of naturally occurring layered
insulators with large bandgap energy that have gained attention from the
scientific community. This class of lamellar materials has been recently
explored at the ultrathin two-dimensional level due to their specific
mechanical, electrical, magnetic, and optoelectronic properties, which are
crucial for engineering novel devices (including heterostructures). Due to
these properties, phyllosilicates minerals can be considered promising low-cost
nanomaterials for future applications. In this Perspective article, we will
present relevant features of these materials for their use in potential
2D-based electronic and optoelectronic applications, also discussing some of
the major challenges in working with them.Comment: 29 pages, 4 figure
Portuguese recommendations for the use of biological therapies in patients with psoriatic arthritis - 2015 update
OBJECTIVE: To update recommendationsforthe treatment
of psoriatic arthritis with biological therapies, endorsed
by the Portuguese Society of Rheumatology (SPR).
METHODS: These treatment recommendations were formulated
by Portuguese rheumatologists based on literature
evidence and consensus opinion. At a national
meeting the 16 recommendations included in this
document were discussed and updated. The level of
agreement among Portuguese Rheumatologists was assessed
using an online survey. A draft of the full text of
the recommendations was then circulated and suggestions
were incorporated. A final version was again circulated
before publication.
RESULTS: A consensus was achieved regarding the initiation,
assessment of response and switching biological
therapies in patients with psoriatic arthritis (PsA).
Specific recommendations were developed for several
disease domains: peripheral arthritis, axial disease, enthesitis
and dactylitis.
CONCLUSION: These recommendations may be used for
guidance in deciding which patients with PsA should be
treated with biological therapies. They cover a rapidly
evolving area oftherapeutic intervention.Asmore evidence
becomes available and more biological therapies are licensed,
these recommendations will have to be updated
Cell walls of the dimorphic fungal pathogens Sporothrix schenckii and Sporothrix brasiliensis exhibit bilaminate structures and sloughing of extensive and intact layers
This work was supported by the Fundação Carlos Chagas de Amparo à Pesquisa do Estado do Rio de Janeiro (FAPERJ), grants E-26/202.974/2015 and Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq), grants 229755/2013-5, Brazil. LMLB is a senior research fellow of CNPq and Faperj. NG acknowledged support from the Wellcome Trust (Trust (097377, 101873, 200208) and MRC Centre for Medical Mycology (MR/N006364/1). The funders had no role in study design, data collection and analysis, decision to publish, or preparation of the manuscript.Peer reviewedPublisher PD
Evaluation of the effect of an extract of sabugueiro (Sambucus australis) on the labeling of blood constituents with technetium-99m
The Oldest Case of Decapitation in the New World (Lapa do Santo, East-Central Brazil)
We present here evidence for an early Holocene case of decapitation in the New World (Burial 26), found in the rock shelter of Lapa do Santo in 2007. Lapa do Santo is an archaeological site located in the Lagoa Santa karst in east-central Brazil with evidence of human occupation dating as far back as 11.7-12.7 cal kyBP (95.4% interval). An ultra-filtered AMS age determination on a fragment of the sphenoid provided an age range of 9.1-9.4 cal kyBP (95.4% interval) for Burial 26. The interment was composed of an articulated cranium, mandible and first six cervical vertebrae. Cut marks with a v-shaped profile were observed in the mandible and sixth cervical vertebra. The right hand was amputated and laid over the left side of the face with distal phalanges pointing to the chin and the left hand was amputated and laid over the right side of the face with distal phalanges pointing to the forehead. Strontium analysis comparing Burial 26's isotopic signature to other specimens from Lapa do Santo suggests this was a local member of the group. Therefore, we suggest a ritualized decapitation instead of trophy-taking, testifying for the sophistication of mortuary rituals among hunter-gatherers in the Americas during the early Archaic period. In the apparent absence of wealth goods or elaborated architecture, Lapa do Santo's inhabitants seemed to use the human body to express their cosmological principles regarding death
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