392 research outputs found
Enantioselective SâH Insertion Reactions of αâCarbonyl Sulfoxonium Ylides
The first example of enantioselective SâH insertion reactions of sulfoxonium ylides is reported. Under the influence of thiourea catalysis, excellent levels of enantiocontrol (up to 95% ee) and yields (up to 97%) are achieved for 31 examples in SâH insertion reactions of aryl thiols and αâcarbonyl sulfoxonium ylides
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Fluids, evaporation and precipitates at Gale Crater
The Mars Science Laboratory (MSL) mission landed in Gale Crater, Mars, on 6th August 2012, and has explored the Yellowknife Bay area. The detailed mineralogical and sedimentological studies provide a unique opportunity to characterise the secondary fluids associated with this habitable environment
Yet Another Extension of the Standard Model: Oases in the Desert?
We have searched for conceptually simple extensions of the standard model,
and describe here a candidate model which we find attractive. Our starting
point is the assumption that off-diagonal CKM mixing matrix elements are
directly related by lowest order perturbation theory to the quark mass
matrices. This appears to be most easily and naturally implemented by assuming
that all off-diagonal elements reside in the down-quark mass matrix. This
assumption is in turn naturally realized by introducing three generations of
heavy, electroweak-singlet down quarks which couple to the Higgs sector
diagonally in flavor, while mass-mixing off-diagonally with the light
down-quarks. Anomaly cancellation then naturally leads to inclusion of
electroweak vector-doublet leptons. It is then only a short step to completing
the extension to three generations of fundamental representations of E(6).
Assuming only that the third generation B couples to the Higgs sector at least
as strongly as does the top quark, the mass of the B is roughly estimated to
lie between 1.7 TeV and 10 TeV, with lower-generation quarks no heavier. The
corresponding guess for the new leptons is a factor two lower. Within the
validity of the model, flavor and CP violation are ``infrared'' in nature,
induced by semi-soft mass mixing terms, not Yukawa couplings. If the Higgs
couplings of the new quarks are flavor symmetric, then there necessarily must
be at least one ``oasis'' in the desert, induced by new radiative corrections
to the top quark and Higgs coupling constants, and roughly at 1000 TeV.Comment: LaTex, 40 page
Muon anomalous magnetic moment in string inspired extended family models
We propose a standard model minimal extension with two lepton weak SU(2)
doublets and a scalar singlet to explain the deviation of the measured
anomalous magnetic moment of the muon from the standard model expectation. This
scheme can be naturally motivated in string inspired models such as E_6 and
AdS/CFT.Comment: 9 pages, RevTeX, 2 figures, version to be published in Phys. Rev.
Dark Force Detection in Low Energy e-p Collisions
We study the prospects for detecting a light boson X with mass m_X < 100 MeV
at a low energy electron-proton collider. We focus on the case where X
dominantly decays to e+ e- as motivated by recent "dark force" models. In order
to evade direct and indirect constraints, X must have small couplings to the
standard model (alpha_X 10 MeV).
By comparing the signal and background cross sections for the e- p e+ e- final
state, we conclude that dark force detection requires an integrated luminosity
of around 1 inverse attobarn, achievable with a forthcoming JLab proposal.Comment: 38 pages, 19 figures; v2, references adde
Screening for Chronic Conditions Using a Patient Internet Portal: Recruitment for an Internet-based Primary Care Intervention
Background: Patient Internet portals have created new opportunities for assessment and management of chronic conditions. Objective: To conduct an online screening survey for a study recruitment using a secure patient Internet portal to identify primary care patients with untreated depression, chronic pain, or mobility difficulty before nonurgent office visits. Design: Internet-based screening survey for a randomized trial. Participants: Patients who were registered portal users who had scheduled primary care appointments. Approach: Electronic study invitations via the portal were sent to 4,047 patients with scheduled visits to 34 primary care physicians participating in the study. After clicking on a link in the study invitation, patients were consecutively shown the study description, consent form, and lastly, the screening survey to determine final eligibility for study participation. Results: Of the 2,113 (52%) patients who opened the study invitation, 1,001 consented online to join the study and 981 (98%) of these completed the screening survey. Of the respondents, 319 (33%) screened positive for 1 or more of the 3 conditions. Conclusions: The online screening survey conducted through the patient portal was effective in identifying patients with chronic conditions in advance of scheduled primary care visits for participation in an intervention study
Measurement of the forward-backward asymmetries for charm- and bottom-quark pair productions at =58GeV with electron tagging
We have measured, with electron tagging, the forward-backward asymmetries of
charm- and bottom-quark pair productions at =58.01GeV, based on
23,783 hadronic events selected from a data sample of 197pb taken with
the TOPAZ detector at TRISTAN. The measured forward-backward asymmetries are
and , which are consistent with the standard model
predictions.Comment: 19 pages, Latex format (article), 5 figures included. to be published
in Phys. Lett.
Associated Charm Production in Neutrino-Nucleus Interactions
In this paper a search for associated charm production both in neutral and
charged current -nucleus interactions is presented. The improvement of
automatic scanning systems in the {CHORUS} experiment allows an efficient
search to be performed in emulsion for short-lived particles. Hence a search
for rare processes, like the associated charm production, becomes possible
through the observation of the double charm-decay topology with a very low
background. About 130,000 interactions located in the emulsion target
have been analysed. Three events with two charm decays have been observed in
the neutral-current sample with an estimated background of 0.180.05. The
relative rate of the associated charm cross-section in deep inelastic
interactions, has been
measured. One event with two charm decays has been observed in charged-current
interactions with an estimated background of 0.180.06 and the
upper limit on associated charm production in charged-current interactions at
90% C.L. has been found to be .Comment: 10 pages, 4 figure
Fluids during diagenesis and sulfate vein formation in sediments at Gale crater, Mars
We model the fluids involved in the alteration processes recorded in the Sheepbed Member mudstones of Yellowknife Bay (YKB), Gale crater, Mars, as revealed by the Mars Science Laboratory Curiosity rover investigations. We compare the Gale crater waters with fluids modeled for shergottites, nakhlites, and the ancient meteorite ALH 84001, as well as rocks analyzed by the Mars Exploration rovers, and with terrestrial ground and surface waters. The aqueous solution present during sediment alteration associated with phyllosilicate formation at Gale was high in Na, K, and Si; had low Mg, Fe, and Al concentrationsârelative to terrestrial groundwaters such as the Deccan Traps and other modeled Mars fluids; and had near neutral to alkaline pH. Ca and S species were present in the 10â3 to 10â2 concentration range. A fluid local to Gale crater strata produced the alteration products observed by Curiosity and subsequent evaporation of this groundwater-type fluid formed impure sulfate- and silica-rich depositsâveins or horizons. In a second, separate stage of alteration, partial dissolution of this sulfate-rich layer in Yellowknife Bay, or beyond, led to the pure sulfate veins observed in YKB. This scenario is analogous to similar processes identified at a terrestrial site in Triassic sediments with gypsum veins of the Mercia Mudstone Group in Watchet Bay, UK
Preliminary Geological Map of the Peace Vallis Fan Integrated with In Situ Mosaics From the Curiosity Rover, Gale Crater, Mars
A geomorphically defined alluvial fan extends from Peace Vallis on the NW wall of Gale Crater, Mars into the Mars Science Laboratory (MSL) Curiosity rover landing ellipse. Prior to landing, the MSL team mapped the ellipse and surrounding areas, including the Peace Vallis fan. Map relationships suggest that bedded rocks east of the landing site are likely associated with the fan, which led to the decision to send Curiosity east. Curiosity's mast camera (Mastcam) color images are being used to refine local map relationships. Results from regional mapping and the first 100 sols of the mission demonstrate that the area has a rich geological history. Understanding this history will be critical for assessing ancient habitability and potential organic matter preservation at Gale Crater
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