Chromatographic identification and determination of organic acids in water

Reprinted from Analytical Chemistry, v.30, January, 1958.Bibliography: p. [44]

"TNOs are Cool": A survey of the trans-Neptunian region X. Analysis of classical Kuiper belt objects from Herschel and Spitzer observations

The classical Kuiper belt contains objects both from a low-inclination, presumably primordial, distribution and from a high-inclination dynamically excited population. Based on a sample of classical TNOs with observations at thermal wavelengths we determine radiometric sizes, geometric albedos and thermal beaming factors as well as study sample properties of dynamically hot and cold classicals. Observations near the thermal peak of TNOs using infra-red space telescopes are combined with optical magnitudes using the radiometric technique with near-Earth asteroid thermal model (NEATM). We have determined three-band flux densities from Herschel/PACS observations at 70.0, 100.0 and 160.0 $\mu$m and Spitzer/MIPS at 23.68 and 71.42 $\mu$m when available. We have analysed 18 classical TNOs with previously unpublished data and re-analysed previously published targets with updated data reduction to determine their sizes and geometric albedos as well as beaming factors when data quality allows. We have combined these samples with classical TNOs with radiometric results in the literature for the analysis of sample properties of a total of 44 objects. We find a median geometric albedo for cold classical TNOs of 0.14 and for dynamically hot classical TNOs, excluding the Haumea family and dwarf planets, 0.085. We have determined the bulk densities of Borasisi-Pabu (2.1 g/cm^3), Varda-Ilmare (1.25 g/cm^3) and 2001 QC298 (1.14 g/cm^3) as well as updated previous density estimates of four targets. We have determined the slope parameter of the debiased cumulative size distribution of dynamically hot classical TNOs as q=2.3 +- 0.1 in the diameter range 100<D<500 km. For dynamically cold classical TNOs we determine q=5.1 +- 1.1 in the diameter range 160<D<280 km as the cold classical TNOs have a smaller maximum size.Comment: 22 pages, 7 figures Accepted to be published in Astronomy and Astrophysic

"TNOs are Cool": A survey of the trans-Neptunian region VI. Herschel/PACS observations and thermal modeling of 19 classical Kuiper belt objects

Trans-Neptunian objects (TNO) represent the leftovers of the formation of the Solar System. Their physical properties provide constraints to the models of formation and evolution of the various dynamical classes of objects in the outer Solar System. Based on a sample of 19 classical TNOs we determine radiometric sizes, geometric albedos and beaming parameters. Our sample is composed of both dynamically hot and cold classicals. We study the correlations of diameter and albedo of these two subsamples with each other and with orbital parameters, spectral slopes and colors. We have done three-band photometric observations with Herschel/PACS and we use a consistent method for data reduction and aperture photometry of this sample to obtain monochromatic flux densities at 70.0, 100.0 and 160.0 \mu m. Additionally, we use Spitzer/MIPS flux densities at 23.68 and 71.42 \mu m when available, and we present new Spitzer flux densities of eight targets. We derive diameters and albedos with the near-Earth asteroid thermal model (NEATM). As auxiliary data we use reexamined absolute visual magnitudes from the literature and data bases, part of which have been obtained by ground based programs in support of our Herschel key program. We have determined for the first time radiometric sizes and albedos of eight classical TNOs, and refined previous size and albedo estimates or limits of 11 other classicals. The new size estimates of 2002 MS4 and 120347 Salacia indicate that they are among the 10 largest TNOs known. Our new results confirm the recent findings that there are very diverse albedos among the classical TNOs and that cold classicals possess a high average albedo (0.17 +/- 0.04). Diameters of classical TNOs strongly correlate with orbital inclination in our sample. We also determine the bulk densities of six binary TNOs.Comment: 21 pages, 9 figures, accepted for publication in Astronomy and Astrophysic

PhosphoPep—a phosphoproteome resource for systems biology research in Drosophila Kc167 cells

The ability to analyze and understand the mechanisms by which cells process information is a key question of systems biology research. Such mechanisms critically depend on reversible phosphorylation of cellular proteins, a process that is catalyzed by protein kinases and phosphatases. Here, we present PhosphoPep, a database containing more than 10 000 unique high-confidence phosphorylation sites mapping to nearly 3500 gene models and 4600 distinct phosphoproteins of the Drosophila melanogaster Kc167 cell line. This constitutes the most comprehensive phosphorylation map of any single source to date. To enhance the utility of PhosphoPep, we also provide an array of software tools that allow users to browse through phosphorylation sites on single proteins or pathways, to easily integrate the data with other, external data types such as protein–protein interactions and to search the database via spectral matching. Finally, all data can be readily exported, for example, for targeted proteomics approaches and the data thus generated can be again validated using PhosphoPep, supporting iterative cycles of experimentation and analysis that are typical for systems biology research

Two-photon Lithography for 3D Magnetic Nanostructure Fabrication

Ferromagnetic materials have been utilised as recording media within data storage devices for many decades. Confinement of the material to a two dimensional plane is a significant bottleneck in achieving ultra-high recording densities and this has led to the proposition of three dimensional (3D) racetrack memories that utilise domain wall propagation along nanowires. However, the fabrication of 3D magnetic nanostructures of complex geometry is highly challenging and not easily achievable with standard lithography techniques. Here, by using a combination of two-photon lithography and electrochemical deposition, we show a new approach to construct 3D magnetic nanostructures of complex geometry. The magnetic properties are found to be intimately related to the 3D geometry of the structure and magnetic imaging experiments provide evidence of domain wall pinning at a 3D nanostructured junction

TNOs are Cool: A survey of the trans-Neptunian region V. Physical characterization of 18 Plutinos using Herschel PACS observations

We present Herschel PACS photometry of 18 Plutinos and determine sizes and albedos for these objects using thermal modeling. We analyze our results for correlations, draw conclusions on the Plutino size distribution, and compare to earlier results. Flux densities are derived from PACS mini scan-maps using specialized data reduction and photometry methods. In order to improve the quality of our results, we combine our PACS data with existing Spitzer MIPS data where possible, and refine existing absolute magnitudes for the targets. The physical characterization of our sample is done using a thermal model. Uncertainties of the physical parameters are derived using customized Monte Carlo methods. The correlation analysis is performed using a bootstrap Spearman rank analysis. We find the sizes of our Plutinos to range from 150 to 730 km and geometric albedos to vary between 0.04 and 0.28. The average albedo of the sample is 0.08 \pm 0.03, which is comparable to the mean albedo of Centaurs, Jupiter Family comets and other Trans-Neptunian Objects. We were able to calibrate the Plutino size scale for the first time and find the cumulative Plutino size distribution to be best fit using a cumulative power law with q = 2 at sizes ranging from 120-400 km and q = 3 at larger sizes. We revise the bulk density of 1999 TC36 and find a density of 0.64 (+0.15/-0.11) g cm-3. On the basis of a modified Spearman rank analysis technique our Plutino sample appears to be biased with respect to object size but unbiased with respect to albedo. Furthermore, we find biases based on geometrical aspects and color in our sample. There is qualitative evidence that icy Plutinos have higher albedos than the average of the sample.Comment: 18 pages, 8 figures, 8 tables, accepted for publication in A&

Miscellaneous Problems

Contains reports on eleven research projects