295 research outputs found

    1,4-Bis(iodo­meth­yl)benzene

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    The centrosymmetric title compound, C8H8I2, was prepared by metathesis from the dibromo analogue. In the crystal structure, weak C—H⋯I inter­actions link the mol­ecules into stacks down the b axis. The structure is further stabilized by short I⋯I contacts [3.8433 (2) Å], forming undulating sheets in the (101) plane

    6-Hy­droxy-5,7,8-trimethyl­chroman-2-one

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    The title compound, C12H14O3, consists of a chromanone unit with an –OH substituent at the 4-position and methyl substituents on the remaining C atoms of the aromatic ring. The fused pyran­one ring adopts a distorted envelope conformation with the methyl­ene group adjacent to the carbonyl carbon as the flap atom. The crystal structure is stabilized by classical O—H⋯O hydrogen bonds and weak C—H⋯O and C—H⋯π inter­actions, generating a three-dimensional network

    Total orthotopic small bowel transplantation in swine under FK 506

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    Previous experimental studies in rodents and in dogs have established the efficacy of FK 506 in controlling the immunologic events following small bowel or multivisceral transplantation.1–5 To complete the assessment of FK 506 in experimental small bowel transplantation, we present here our experience with the frequently used swine model

    Nonlinear quantum model for atomic Josephson junctions with one and two bosonic species

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    We study atomic Josephson junctions (AJJs) with one and two bosonic species confined by a double-well potential. Proceeding from the second quantized Hamiltonian, we show that it is possible to describe the zero-temperature AJJs microscopic dynamics by means of extended Bose-Hubbard (EBH) models, which include usually-neglected nonlinear terms. Within the mean-field approximation, the Heisenberg equations derived from such two-mode models provide a description of AJJs macroscopic dynamics in terms of ordinary differential equations (ODEs). We discuss the possibility to distinguish the Rabi, Josephson, and Fock regimes, in terms of the macroscopic parameters which appear in the EBH Hamiltonians and, then, in the ODEs. We compare the predictions for the relative populations of the Bose gases atoms in the two wells obtained from the numerical solutions of the two-mode ODEs, with those deriving from the direct numerical integration of the Gross-Pitaevskii equations (GPEs). Our investigations shows that the nonlinear terms of the ODEs are crucial to achieve a good agreement between ODEs and GPEs approaches, and in particular to give quantitative predictions of the self-trapping regime.Comment: Accepted for the publication in J. Phys. B: At. Mol. Opt. Phy

    Estimation of functional connectivity from electromagnetic signals and the amount of empirical data required

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    An increasing number of neuroimaging studies are concerned with the identification of interactions or statistical dependencies between brain areas. Dependencies between the activities of different brain regions can be quantified with functional connectivity measures such as the cross-correlation coefficient. An important factor limiting the accuracy of such measures is the amount of empirical data available. For event-related protocols, the amount of data also affects the temporal resolution of the analysis. We use analytical expressions to calculate the amount of empirical data needed to establish whether a certain level of dependency is significant when the time series are autocorrelated, as is the case for biological signals. These analytical results are then contrasted with estimates from simulations based on real data recorded with magnetoencephalography during a resting-state paradigm and during the presentation of visual stimuli. Results indicate that, for broadband signals, 50–100 s of data is required to detect a true underlying cross-correlations coefficient of 0.05. This corresponds to a resolution of a few hundred milliseconds for typical event-related recordings. The required time window increases for narrow band signals as frequency decreases. For instance, approximately 3 times as much data is necessary for signals in the alpha band. Important implications can be derived for the design and interpretation of experiments to characterize weak interactions, which are potentially important for brain processing

    2-Methyl-4,6-bis­(1-methyl­hydrazino)pyrimidine

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    In the title compound, C7H14N6, the amine groups of the two methyl­hydrazino substituents are orientated in the opposite direction to the methyl substituent at the 2-position of the pyrimidine ring. The mol­ecule is almost planar with only the two amine N atoms lying substanti­ally out of the mean plane of the pyrimidine ring [by 0.1430 (2) and 0.3092 (2) Å]. The H atoms on these amine groups point inwards towards the aromatic ring, such that the lone pair of electrons points outwards from the mol­ecule. Each mol­ecule is linked to two others through N—H⋯N hydrogen bonds between the two amino groups, forming a one-dimensional chain in the [010] direction. Offset face-to-face π–π stacking inter­actions between the pyrimidine rings organize these chains into a two-dimensional array [centroid–centroid distance = 3.789 (2) Å]

    Gel actuators based on polymeric radicals

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    Low-voltage electrochemical actuation of radical polymer gels has been demonstrated in an organic electrolyte. Polymer gels were prepared by post-modification of active-ester precursor gels with an amine-functionalised radical. A combination of few-layer graphene and multiwall carbon nanotubes gave high conductivity and improved actuation in the gels, with 32% linear actuation. The actuator system showed good stability over at least 10 cycles, showing its promise. The cycle time was several hours due to mass-transport limited transport of ions and solvent into the device

    Atomic Josephson junction with two bosonic species

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    We study an atomic Josephson junction (AJJ) in presence of two interacting Bose-Einstein condensates (BECs) confined in a double well trap. We assume that bosons of different species interact with each other. The macroscopic wave functions of the two components obey to a system of two 3D coupled Gross-Pitaevskii equations (GPE). We write the Lagrangian of the system, and from this we derive a system of coupled ordinary differential equations (ODE), for which the coupled pendula represent the mechanic analogous. These differential equations control the dynamical behavior of the fractional imbalance and of the relative phase of each bosonic component. We perform the stability analysis around the points which preserve the symmetry and get an analytical formula for the oscillation frequency around the stable points. Such a formula could be used as an indirect measure of the inter-species s-wave scattering length. We also study the oscillations of each fractional imbalance around zero and non zero - the macroscopic quantum self-trapping (MQST) - time averaged values. For different values of the inter-species interaction amplitude, we carry out this study both by directly solving the two GPE and by solving the corresponding coupled pendula equations. We show that, under certain conditions, the predictions of these two approaches are in good agreement. Moreover, we calculate the crossover value of the inter-species interaction amplitude which signs the onset of MQST.Comment: Accepted for the publication in J. Phys. B: At. Mol. Opt. Phy

    UGIJAR AND CANJAYAR NEOGENE BASINS (SE SPAIN): AN EXAMPLE OF STRIKE-SLIP BASIN EVOLUTION IN TRANSPRESSIVE REGIME

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    The present study has been carried out in the eastern part of the Alpujarran corridor (Betic Chain), an E-W trending basin, 80 km long, of Neogene-Quaternary age. In particular, the Ugijar and Canjayar basins (respectively named Basin 1 and Basin 2), controlled by an E-W trending left stepping right lateral strike­slip system, associated with NE-SW trending thrust faults, have been investigated. The stratigraphic sequence of the forementioned two basins, which can be up to 2000 m thick, is mainly due to tectonic subsidence and is here interpreted in terms of Sequence Stratigraphy. The age of the whole sequence, dated by means of planktonic foraminifera, is Late Serravallian-Pliocene

    N-Methacryloyl-4-(piperidin-1-yl)-1,8-naphthalimide

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    In the title compound, C21H20N2O3, the naphthalimide unit is almost planar (r.m.s. deviation for the 15 non-H atoms = 0.059 Å). The carboximide N atom and the five C atoms of the 2-methyl­prop-2-enoyl substituent also lie in a plane (r.m.s. deviation = 0.009 Å), which subtends an angle of 84.34 (7)° to the naphthalamide plane. This orients the =CH2 group of the vinyl fragment towards the naphthalimide rings, giving the mol­ecule an extended configuration. The piperidine ring adopts a chair conformation and there is evidence for some delocalization between the naphthalene and piperidine units, the C—Npip bond length being 1.404 (4) Å. In the crystal structure, π–π contacts with centroid–centroid distances of 3.5351 (18) and 3.7794 (18) Å supported by C—H⋯O hydrogen bonds link adjacent mol­ecules in a head-to-tail fashion, forming dimers. These are further stabilized by other C—H⋯O contacts of varying strength, which stack the mol­ecules down the b axis
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