218 research outputs found

    The representation of solar cycle signals in stratospheric ozone – Part 1: A comparison of satellite observations

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    Changes in incoming solar ultraviolet radiation over the 11-year solar cycle affect stratospheric ozone abundances. It is important to quantify the magnitude, structure, and seasonality of the associated solar-ozone response (SOR) to understand the impact of the 11-year solar cycle on climate. Part 1 of this two-part study uses multiple linear regression analysis to extract the SOR in a number of recently updated satellite ozone datasets covering different periods within the epoch 1970 to 2013. The annual mean SOR in the updated version 7.0 (v7.0) Stratospheric Aerosol and Gas Experiment (SAGE) II number density dataset (1984–2004) is very consistent with that found in the previous v6.2. In contrast, we find a substantial decrease in the magnitude of the SOR in the tropical upper stratosphere in the SAGE II v7.0 mixing ratio dataset (∼ 1 %) compared to the v6.2 (∼ 4 %). This difference is shown to be largely attributable to the change in the independent stratospheric temperature dataset used to convert SAGE II ozone number densities to mixing ratios. Since these temperature records contain substantial uncertainties, we suggest that datasets based on SAGE II number densities are currently most reliable for evaluating the SOR. We further analyse three extended ozone datasets that combine SAGE II v7.0 number densities with more recent GOMOS (Global Ozone Monitoring by Occultation of Stars) or OSIRIS (Optical Spectrograph and Infrared Imager System) measurements. The extended SAGE–OSIRIS dataset (1984–2013) shows a smaller and less statistically significant SOR across much of the tropical upper stratosphere compared to the SAGE II data alone. In contrast, the two SAGE–GOMOS datasets (1984–2011) show SORs that are in closer agreement with the original SAGE II data and therefore appear to provide a more reliable estimate of the SOR. We also analyse the SOR in the recent Solar Backscatter Ultraviolet Instrument (SBUV) Merged Ozone Dataset (SBUVMOD) version 8.6 (VN8.6) (1970–2012) and SBUV Merged Cohesive VN8.6 (1978–2012) datasets and compare them to the previous SBUVMOD VN8.0 (1970–2009). Over their full lengths, the three records generally agree in terms of the broad magnitude and structure of the annual mean SOR. The main difference is that SBUVMOD VN8.6 shows a smaller and less significant SOR in the tropical upper stratosphere and therefore more closely resembles the SAGE II v7.0 mixing ratio data than does the SBUV Merged Cohesive VN8.6, which has a more continuous SOR of ∼ 2 % in this region. The sparse spatial and temporal sampling of limb satellite instruments prohibits the extraction of sub-annual variations in the SOR from SAGE-based datasets. However, the SBUVMOD VN8.6 dataset suggests substantial month-to-month variations in the SOR, particularly in the winter extratropics, which may be important for the proposed high-latitude dynamical response to the solar cycle. Overall, the results highlight substantial uncertainties in the magnitude and structure of the observed SOR from different satellite records. The implications of these uncertainties for understanding and modelling the effects of solar variability on climate should be explored

    Space Station Engineering Design Issues

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    Space Station Freedom topics addressed include: general design issues; issues related to utilization and operations; issues related to systems requirements and design; and management issues relevant to design

    Valorisation of Potato (Solanum tuberosum) Peel Waste: Extraction of Fibre, Monosaccharides and Uronic Acids

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    Purpose: The food and starch industries generate large quantities of potato peel waste (PPW) that can be exploited for a range of biotechnological and biofuel applications. The purpose of this study was to characterise the ultrastructure and monosaccharide composition of PPW. Methods: The ultrastructure of PPW was observed using light and immunofluorescence microscopy. Fibre was prepared from PPW using mild detergent and subjected to sequential acid hydrolysis followed by high performance anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD). Results: Potato peels are composed of small, stacked cells which generally lack starch granules. These cells are surrounded by thick cell walls rich in pectic polysaccharides. Following sequential extraction, seven different sugars and two uronic acids were identified including (in order of abundance) mannose, galacturonic acid, xylose, glucose, fucose, glucuronic acid, galactose, rhamnose and arabinose. The monosaccharides and uronic acid products showed good stability in the acidic conditions during storage, which would facilitate their downstream purification and eventual commercialisation. Conclusion: PPW is a readily available source of fibre, monosaccharides and uronic acids

    The impact of CdSe/ZnS Quantum Dots in cells of Medicago sativa in suspension culture

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    <p>Abstract</p> <p>Background</p> <p>Nanotechnology has the potential to provide agriculture with new tools that may be used in the rapid detection and molecular treatment of diseases and enhancement of plant ability to absorb nutrients, among others. Data on nanoparticle toxicity in plants is largely heterogeneous with a diversity of physicochemical parameters reported, which difficult generalizations. Here a cell biology approach was used to evaluate the impact of Quantum Dots (QDs) nanocrystals on plant cells, including their effect on cell growth, cell viability, oxidative stress and ROS accumulation, besides their cytomobility.</p> <p>Results</p> <p>A plant cell suspension culture of <it>Medicago sativa </it>was settled for the assessment of the impact of the addition of mercaptopropanoic acid coated CdSe/ZnS QDs. Cell growth was significantly reduced when 100 mM of mercaptopropanoic acid -QDs was added during the exponential growth phase, with less than 50% of the cells viable 72 hours after mercaptopropanoic acid -QDs addition. They were up taken by <it>Medicago sativa </it>cells and accumulated in the cytoplasm and nucleus as revealed by optical thin confocal imaging. As part of the cellular response to internalization, <it>Medicago sativa </it>cells were found to increase the production of Reactive Oxygen Species (ROS) in a dose and time dependent manner. Using the fluorescent dye H<sub>2</sub>DCFDA it was observable that mercaptopropanoic acid-QDs concentrations between 5-180 nM led to a progressive and linear increase of ROS accumulation.</p> <p>Conclusions</p> <p>Our results showed that the extent of mercaptopropanoic acid coated CdSe/ZnS QDs cytotoxicity in plant cells is dependent upon a number of factors including QDs properties, dose and the environmental conditions of administration and that, for <it>Medicago sativa </it>cells, a safe range of 1-5 nM should not be exceeded for biological applications.</p

    Ixora fulgida

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    Ixora fulgida is a small tree, endemic to Sabah. The estimated area of occupancy (AOO) and extent of occurrence (EOO) are 120 km2 and 54,978 km2, respectively. It is widespread across the state and occurs in at least 11 protected areas in Sabah with no major threat to its population. It is assessed as Least Concern. Ixora fulgida is endemic to Sabah, Malaysia. It is widespread across the stat

    Solar forcing for CMIP6 (v3.2)

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    This paper describes the recommended solar forcing dataset for CMIP6 and highlights changes with respect to CMIP5. The solar forcing is provided for radiative properties, namely total solar irradiance (TSI), solar spectral irradiance (SSI), and the F10.7 index as well as particle forcing, including geomagnetic indices Ap and Kp, and ionization rates to account for effects of solar protons, electrons, and galactic cosmic rays. This is the first time that a recommendation for solar-driven particle forcing has been provided for a CMIP exercise. The solar forcing datasets are provided at daily and monthly resolution separately for the CMIP6 preindustrial control, historical (1850–2014), and future (2015–2300) simulations. For the preindustrial control simulation, both constant and time-varying solar forcing components are provided, with the latter including variability on 11-year and shorter timescales but no long-term changes. For the future, we provide a realistic scenario of what solar behavior could be, as well as an additional extreme Maunder-minimum-like sensitivity scenario. This paper describes the forcing datasets and also provides detailed recommendations as to their implementation in current climate models. For the historical simulations, the TSI and SSI time series are defined as the average of two solar irradiance models that are adapted to CMIP6 needs: an empirical one (NRLTSI2–NRLSSI2) and a semi-empirical one (SATIRE). A new and lower TSI value is recommended: the contemporary solar-cycle average is now 1361.0 W m−2. The slight negative trend in TSI over the three most recent solar cycles in the CMIP6 dataset leads to only a small global radiative forcing of −0.04 W m−2. In the 200–400 nm wavelength range, which is important for ozone photochemistry, the CMIP6 solar forcing dataset shows a larger solar-cycle variability contribution to TSI than in CMIP5 (50 % compared to 35 %). We compare the climatic effects of the CMIP6 solar forcing dataset to its CMIP5 predecessor by using time-slice experiments of two chemistry–climate models and a reference radiative transfer model. The differences in the long-term mean SSI in the CMIP6 dataset, compared to CMIP5, impact on climatological stratospheric conditions (lower shortwave heating rates of −0.35 K day−1 at the stratopause), cooler stratospheric temperatures (−1.5 K in the upper stratosphere), lower ozone abundances in the lower stratosphere (−3 %), and higher ozone abundances (+1.5 % in the upper stratosphere and lower mesosphere). Between the maximum and minimum phases of the 11-year solar cycle, there is an increase in shortwave heating rates (+0.2 K day−1 at the stratopause), temperatures ( ∼  1 K at the stratopause), and ozone (+2.5 % in the upper stratosphere) in the tropical upper stratosphere using the CMIP6 forcing dataset. This solar-cycle response is slightly larger, but not statistically significantly different from that for the CMIP5 forcing dataset. CMIP6 models with a well-resolved shortwave radiation scheme are encouraged to prescribe SSI changes and include solar-induced stratospheric ozone variations, in order to better represent solar climate variability compared to models that only prescribe TSI and/or exclude the solar-ozone response. We show that monthly-mean solar-induced ozone variations are implicitly included in the SPARC/CCMI CMIP6 Ozone Database for historical simulations, which is derived from transient chemistry–climate model simulations and has been developed for climate models that do not calculate ozone interactively. CMIP6 models without chemistry that perform a preindustrial control simulation with time-varying solar forcing will need to use a modified version of the SPARC/CCMI Ozone Database that includes solar variability. CMIP6 models with interactive chemistry are also encouraged to use the particle forcing datasets, which will allow the potential long-term effects of particles to be addressed for the first time. The consideration of particle forcing has been shown to significantly improve the representation of reactive nitrogen and ozone variability in the polar middle atmosphere, eventually resulting in further improvements in the representation of solar climate variability in global models
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