Thermal expansion and crystal structure of cementite, Fe3C, between 4 and 600K determined by time-of-flight neutron powder diffraction

The cementite phase of Fe3C has been studied by high-resolution neutron powder diffraction at 4.2 K and at 20 K intervals between 20 and 600 K. The crystal structure remains orthorhombic (Pnma) throughout, with the fractional coordinates of all atoms varying only slightly (the magnetic structure of the ferromagnetic phase could not be determined). The ferromagnetic phase transition, with Tc 480 K, greatly affects the thermal expansion coefficient of the material. The average volumetric coefficient of thermal expansion above Tc was found to be 4.1 (1) × 10-5 K-1; below Tc it is considerably lower (< 1.8 × 10-5 K-1) and varies greatly with temperature. The behaviour of the volume over the full temperature range of the experiment may be modelled by a third-order Grüneisen approximation to the zero-pressure equation of state, combined with a magnetostrictive correction based on mean-field theory

Reproducibility of quantitative indices of lung function and microstructure from 129Xe chemical shift saturation recovery (CSSR) MR spectroscopy

Purpose To evaluate the reproducibility of indices of lung microstructure and function derived from 129Xe chemical shift saturation recovery (CSSR) spectroscopy in healthy volunteers and patients with chronic obstructive pulmonary disease (COPD), and to study the sensitivity of CSSR-derived parameters to pulse sequence design and lung inflation level. Methods Preliminary data were collected from five volunteers on three occasions, using two implementations of the CSSR sequence. Separately, three volunteers each underwent CSSR at three different lung inflation levels. After analysis of these preliminary data, five COPD patients were scanned on three separate days, and nine age-matched volunteers were scanned three times on one day, to assess reproducibility. Results CSSR-derived alveolar septal thickness (ST) and surface-area-to-volume (S/V) ratio values decreased with lung inflation level (P < 0.001; P = 0.057, respectively). Intra-subject standard deviations of ST were lower than the previously measured differences between volunteers and subjects with interstitial lung disease. The mean coefficient of variation (CV) values of ST were 3.9 ± 1.9% and 6.0 ± 4.5% in volunteers and COPD patients, respectively, similar to CV values for whole-lung carbon monoxide diffusing capacity. The mean CV of S/V in volunteers and patients was 14.1 ± 8.0% and 18.0 ± 19.3%, respectively. Conclusion 129Xe CSSR presents a reproducible method for estimation of alveolar septal thickness

Spin-charge separation in the single hole doped Mott antiferromagnet

The motion of a single hole in a Mott antiferromagnet is investigated based on the t-J model. An exact expression of the energy spectrum is obtained, in which the irreparable phase string effect [Phys. Rev. Lett. 77, 5102 (1996)] is explicitly present. By identifying the phase string effect with spin backflow, we point out that spin-charge separation must exist in such a system: the doped hole has to decay into a neutral spinon and a spinless holon, together with the phase string. We show that while the spinon remains coherent, the holon motion is deterred by the phase string, resulting in its localization in space. We calculate the electron spectral function which explains the line shape of the spectral function as well as the ``quasiparticle'' spectrum observed in angle-resolved photoemission experiments. Other analytic and numerical approaches are discussed based on the present framework.Comment: 16 pages, 9 figures; references updated; to appear in Phys. Rev.

Comparison of 3He and129Xe MRI for evaluation of lung microstructure and ventilation at 1.5T

BACKGROUND: To support translational lung MRI research with hyperpolarized129Xe gas, comprehensive evaluation of derived quantitative lung function measures against established measures from3He MRI is required. Few comparative studies have been performed to date, only at 3T, and multisession repeatability of129Xe functional metrics have not been reported. PURPOSE/HYPOTHESIS: To compare hyperpolarized129Xe and3He MRI-derived quantitative metrics of lung ventilation and microstructure, and their repeatability, at 1.5T. STUDY TYPE: Retrospective. POPULATION: Fourteen healthy nonsmokers (HN), five exsmokers (ES), five patients with chronic obstructive pulmonary disease (COPD), and 16 patients with nonsmall-cell lung cancer (NSCLC). FIELD STRENGTH/SEQUENCE: 1.5T. NSCLC, COPD patients and selected HN subjects underwent 3D balanced steady-state free-precession lung ventilation MRI using both3He and129Xe. Selected HN, all ES, and COPD patients underwent 2D multislice spoiled gradient-echo diffusion-weighted lung MRI using both hyperpolarized gas nuclei. ASSESSMENT: Ventilated volume percentages (VV%) and mean apparent diffusion coefficients (ADC) were derived from imaging. COPD patients performed the whole MR protocol in four separate scan sessions to assess repeatability. Same-day pulmonary function tests were performed. STATISTICAL TESTS: Intermetric correlations: Spearman's coefficient. Intergroup/internuclei differences: analysis of variance / Wilcoxon's signed rank. Repeatability: coefficient of variation (CV), intraclass correlation (ICC) coefficient. RESULTS: A significant positive correlation between3He and129Xe VV% was observed (r = 0.860, P < 0.001). VV% was larger for3He than129Xe (P = 0.001); average bias, 8.79%. A strong correlation between mean3He and129Xe ADC was obtained (r = 0.922, P < 0.001). MR parameters exhibited good correlations with pulmonary function tests. In COPD patients, mean CV of3He and129Xe VV% was 4.08% and 13.01%, respectively, with ICC coefficients of 0.541 (P = 0.061) and 0.458 (P = 0.095). Mean3He and129Xe ADC values were highly repeatable (mean CV: 2.98%, 2.77%, respectively; ICC: 0.995, P < 0.001; 0.936, P < 0.001). DATA CONCLUSION:129Xe lung MRI provides near-equivalent information to3He for quantitative lung ventilation and microstructural MRI at 1.5T. LEVEL OF EVIDENCE: 3 Technical Efficacy Stage

Annotation Search: the FAST Way

Περιέχει το πλήρες κείμενοThis paper discusses how annotations can be exploited to develop information access and retrieval algorithms that take them into account. The paper proposes a general framework for developing such algorithms that specifically deals with the problem of accessing and retrieving topical information from annotations and annotated documents

A mean-field kinetic lattice gas model of electrochemical cells

We develop Electrochemical Mean-Field Kinetic Equations (EMFKE) to simulate electrochemical cells. We start from a microscopic lattice-gas model with charged particles, and build mean-field kinetic equations following the lines of earlier work for neutral particles. We include the Poisson equation to account for the influence of the electric field on ion migration, and oxido-reduction processes on the electrode surfaces to allow for growth and dissolution. We confirm the viability of our approach by simulating (i) the electrochemical equilibrium at flat electrodes, which displays the correct charged double-layer, (ii) the growth kinetics of one-dimensional electrochemical cells during growth and dissolution, and (iii) electrochemical dendrites in two dimensions.Comment: 14 pages twocolumn, 17 figure

Emergent eddy saturation from an energy constrained eddy parameterisation

The large-scale features of the global ocean circulation and the sensitivity of these features with respect to forcing changes are critically dependent upon the influence of the mesoscale eddy field. One such feature, observed in numerical simulations whereby the mesoscale eddy field is at least partially resolved, is the phenomenon of eddy saturation, where the time-mean circumpolar transport of the Antarctic Circumpolar Current displays relative insensitivity to wind forcing changes. Coarse-resolution models employing the Gent--McWilliams parameterisation with a constant Gent--McWilliams coefficient seem unable to reproduce this phenomenon. In this article, an idealised model for a wind-forced, zonally symmetric flow in a channel is used to investigate the sensitivity of the circumpolar transport to changes in wind forcing under different eddy closures. It is shown that, when coupled to a simple parameterised eddy energy budget, the Gent--McWilliams coefficient of the form described in Marshall et al. (2012) [A framework for parameterizing eddy potential vorticity fluxes, J. Phys. Oceanogr., vol. 42, 539--557], which includes a linear eddy energy dependence, produces eddy saturation as an emergent property.Comment: 22 pages, 10 figures, Elsevier template, submitted to Ocean Modelling; comments welcom

On the dynamical influence of ocean eddy potential vorticity fluxes

AbstractThe impact of eddy potential vorticity fluxes on the dynamical evolution of the flow is obscured by the presence of large and dynamically-inert rotational fluxes. However, the decomposition of eddy potential vorticity fluxes into rotational and divergent components is non-unique in a bounded domain and requires the imposition of an additional boundary condition. Here it is proposed to invoke a one-to-one correspondence between divergent eddy potential vorticity fluxes and non-divergent eddy momentum tendencies in the quasi-geostrophic residual-mean equations in order to select a unique divergent eddy potential vorticity flux. The divergent eddy potential vorticity flux satisfies a zero tangential component boundary condition. In a simply connected domain, the resulting divergent eddy potential vorticity flux satisfies a powerful optimality condition: it is the horizontally oriented divergent flux with minimum L2 norm. Hence there is a well-defined sense in which this approach removes as much of the dynamically inactive eddy potential vorticity flux as possible, and extracts an underlying dynamically active divergent eddy potential vorticity flux. It is shown that this approach leads to a divergent eddy potential vorticity flux which has an intuitive physical interpretation, via a direct relationship to the resulting forcing of the mean circulation

A new gauge-invariant method for diagnosing eddy diffusivities

Coarse resolution numerical ocean models must typically include a parameterisation for mesoscale turbulence. A common recipe for such parameterisations is to invoke down-gradient mixing, or diffusion, of some tracer quantity, such as potential vorticity or buoyancy. However, it is well known that eddy fluxes include large rotational components which necessarily do not lead to any mixing; eddy diffusivities diagnosed from unfiltered fluxes are thus contaminated by the presence of these rotational components. Here a new methodology is applied whereby eddy diffusivities are diagnosed directly from the eddy force function. The eddy force function depends only upon flux divergences, is independent of any rotational flux components, and is inherently non-local and smooth. A one-shot inversion procedure is applied, minimising the mis-match between parameterised force functions and force functions derived from eddy resolving calculations. This enables diffusivities associated with the eddy potential vorticity and buoyancy fluxes to be diagnosed. The methodology is applied to multi-layer quasi-geostrophic ocean gyre simulations. It is found that: (i) a strictly down-gradient mixing scheme has limited success in reducing the mis-match compared to one with no sign constraint on the diffusivity; (ii) negative signals of diffusivities are prevalent around the time-mean jet; (iii) there is some indication that the magnitude of the diffusivity correlates well the eddy energy. Implications for parameterisation are discussed in light of these diagnostic results.Comment: 22 pages, 14 figures, Elsevier template, submitted to Ocean Modelling; comments welcom