2,284 research outputs found
Modelling of a dynamic multiphase flash: the positive flash. Application to the calculation of ternary diagrams
A general and polyvalent model for the dynamic simulation of a vapor, liquid, liquid-liquid, vapor-liquid or vapor-liquid-liquid stage is proposed. This model is based on the -method introduced as a minimization problem by Han & Rangaiah (1998) for steady-state simulation. They suggested modifying the mole fraction summation such that the same set of governing equations becomes valid for all phase regions. Thanks to judicious additional switch equations, the -formulation is extended to dynamic simulation and the minimization problem is transformed into a set of differential algebraic equations (DAE). Validation of the model consists in testing its capacity to overcome phase number changes and to be able to solve several problems with the same set of equations: calculation of heterogeneous residue curves, azeotropic points and distillation boundaries in ternary diagrams
Coffee and tomato share common gene repertoires as revealed by deep sequencing of seed and cherry transcripts
An EST database has been generated for coffee based on sequences from approximately 47,000 cDNA clones derived from five different stages/tissues, with a special focus on developing seeds. When computationally assembled, these sequences correspond to 13,175 unigenes, which were analyzed with respect to functional annotation, expression profile and evolution. Compared with Arabidopsis, the coffee unigenes encode a higher proportion of proteins related to protein modification/turnover and metabolism—an observation that may explain the high diversity of metabolites found in coffee and related species. Several gene families were found to be either expanded or unique to coffee when compared with Arabidopsis. A high proportion of these families encode proteins assigned to functions related to disease resistance. Such families may have expanded and evolved rapidly under the intense pathogen pressure experienced by a tropical, perennial species like coffee. Finally, the coffee gene repertoire was compared with that of Arabidopsis and Solanaceous species (e.g. tomato). Unlike Arabidopsis, tomato has a nearly perfect gene-for-gene match with coffee. These results are consistent with the facts that coffee and tomato have a similar genome size, chromosome karyotype (tomato, n=12; coffee n=11) and chromosome architecture. Moreover, both belong to the Asterid I clade of dicot plant families. Thus, the biology of coffee (family Rubiacaeae) and tomato (family Solanaceae) may be united into one common network of shared discoveries, resources and information
Impurity-enhanced solid-state amorphization : the Ni-Si thin film reaction altered by nitrogen
Solid-state amorphization, the growth of an amorphous phase during annealing, has been studied in a wide variety of thin film structures. Whereas research on the remarkable growth of such a metastable phase has mostly focused on strictly binary systems, far less is known about the influence of impurities on such reactions. In this paper, the influence of nitrogen, introduced via ion implantation, is studied on the solid-state amorphization reaction of thin (35 nm) Ni films with Si, using in situ x-ray diffraction (XRD), ex situ Rutherford backscattering spectrometry, XTEM, and synchrotron XRD. It is shown that due to small amounts of nitrogen (<2 at.%), an amorphous Ni-Si phase grows almost an order of magnitude thicker during annealing than for unimplanted samples. Nitrogen hinders the nucleation of the first crystalline phases, leading to a new reaction path: the formation of the metal-rich crystalline silicides is suppressed in favour of an amorphous Ni-Si alloy; during a brief temperature window between 330 and 350 degrees C, the entire film is converted to an amorphous phase. The first crystalline structure to grow is the orthorhombic NiSi phase. We demonstrate that this impurity-enchanced solid-state amorphization reaction occurs only under specific implantation conditions. In particular, the initial distribution of nitrogen upon implantation is crucial: sufficient nitrogen impurities must be present at the interface throughout the reaction. Introducing implantation damage without nitrogen impurities (e.g. by implanting a noble gas) does not cause the enhanced solid-state amorphization reaction. Moreover, we show that the stabilizing effect of nitrogen on amorphous Ni-Si films (with a composition ranging from 40% to 50% Si) is not restricted to thin film reactions, but is a general feature of the Ni-Si system
F-theory and Neutrinos: Kaluza-Klein Dilution of Flavor Hierarchy
We study minimal implementations of Majorana and Dirac neutrino scenarios in
F-theory GUT models. In both cases the mass scale of the neutrinos m_nu ~
(M_weak)^2/M_UV arises from integrating out Kaluza-Klein modes, where M_UV is
close to the GUT scale. The participation of non-holomorphic Kaluza-Klein mode
wave functions dilutes the mass hierarchy in comparison to the quark and
charged lepton sectors, in agreement with experimentally measured mass
splittings. The neutrinos are predicted to exhibit a "normal" mass hierarchy,
with masses m_3,m_2,m_1 ~ .05*(1,(alpha_GUT)^(1/2),alpha_GUT) eV. When the
interactions of the neutrino and charged lepton sectors geometrically unify,
the neutrino mixing matrix exhibits a mild hierarchical structure such that the
mixing angles theta_23 and theta_12 are large and comparable, while theta_13 is
expected to be smaller and close to the Cabibbo angle: theta_13 ~ theta_C ~
(alpha_GUT)^(1/2) ~ 0.2. This suggests that theta_13 should be near the current
experimental upper bound.Comment: v2: 83 pages, 10 figures, references adde
Slow nonequilibrium dynamics: parallels between classical and quantum glasses and gently driven systems
We review an scenario for the non-equilibrium dynamics of glassy systems that
has been motivated by the exact solution of simple models. This approach allows
one to set on firmer grounds well-known phenomenological theories. The old
ideas of entropy crisis, fictive temperatures, free-volume... have clear
definitions within these models. Aging effects in the glass phase are also
captured. One of the salient features of the analytic solution, the breakdown
of the fluctuation-dissipation relations, provides a definition of a bonafide
{\it effective temperature} that is measurable by a thermometer, controls heat
flows, partial equilibrations, and the reaction to the external injection of
heat. The effective temperature is an extremely robust concept that appears in
non-equilibrium systems in the limit of small entropy production as, for
instance, sheared fluids, glasses at low temperatures when quantum fluctuations
are relevant, tapped or vibrated granular matter, etc. The emerging scenario is
one of partial equilibrations, in which glassy systems arrange their internal
degrees of freedom so that the slow ones select their own effective
temperatures. It has been proven to be consistent within any perturbative
resummation scheme (mode coupling, etc) and it can be challenged by
experimental and numerical tests, some of which it has already passed.Comment: 15 pages, 8 figure
ruvA Mutants that resolve Holliday junctions but do not reverse replication forks
RuvAB and RuvABC complexes catalyze branch migration and resolution of Holliday junctions (HJs) respectively. In addition to their action in the last steps of homologous recombination, they process HJs made by replication fork reversal, a reaction which occurs at inactivated replication forks by the annealing of blocked leading and lagging strand ends. RuvAB was recently proposed to bind replication forks and directly catalyze their conversion into HJs. We report here the isolation and characterization of two separation-of-function ruvA mutants that resolve HJs, based on their capacity to promote conjugational recombination and recombinational repair of UV and mitomycin C lesions, but have lost the capacity to reverse forks. In vivo and in vitro evidence indicate that the ruvA mutations affect DNA binding and the stimulation of RuvB helicase activity. This work shows that RuvA's actions at forks and at HJs can be genetically separated, and that RuvA mutants compromised for fork reversal remain fully capable of homologous recombination
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