31 research outputs found
2,5-Dihydro-1,2-oxaphosphol-2-ium Ions, as Highly Reactive Phosphorus-Centered Electrophiles: Generation, NMR Study, and Reactions
No full text5-H-1,2-Oxaphosphole 2-oxides, key building blocks for diversity oriented chemical libraries
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Synthesis of new racemic and optically active N-phosphonoalkyl bicyclic 尾-amino acids via the kabachnik-fields reaction as potential biologically active compounds
No full textSquaramide-Catalyzed Enantioselective Michael Addition of Diphenyl Phosphite to Nitroalkenes
No full textSquaramide-Catalyzed Enantioselective Michael Addition of Diphenyl Phosphite to Nitroalkenes
No full textNew quinoline-2, -3, and 4-yl-(amino) methylphosphonates: Synthesis and study on the CP bond cleavage in quinoline-2 and -4 derivatives under acidic conditions
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Organocatalytic hydrophosphonylation reaction of carbonyl groups
No full textThis revision is covering the limited examples reported for a pivotal strategy in the formation of C-P bonds such as the asymmetric organocatalytic hydrophosphonylation of carbonyl groups (Pudovik reaction). The scope and limitations, and the proposed mechanisms for the scarce different possibilities of asymmetric induction are also shown. The recent evolution and future trends of this undeveloped approach are commented.I thank the Spanish High Research Council (CSIC) (PIE201580I010) and Gobierno de Aragon-Fondo Social Europeo (E104) for financial support of our research.Peer reviewe
