Synthesis Characterization and Antimicrobial Activity of Metal Chelates of 1, 7-Di (2-hydroxyphenyl) 1, 7 di (N-methyl) aza-1, 3, 5 heptarine-3-ol hydrochloride

Abstract: The Schiff base complexes derived from 2-furancarboxaldehyde and N-methyl-2-amino phenol have been prepared and characterized using several physical techniques, like elemental analysis, thermogravimetric analysis, magnetic moment measurements, infrared and resonance spectra. N-Methyl-2-amino phenol was condensed stoichiometrically with 2-furancarboxaldehyde in presence of methanol. The resulting 1,7-di(2-hydroxyphenyl) 1,7 di(N-methyl) aza-1,3,5 heptarine-3-ol hydrochloride was characterized by elemental analysis and spectral studies. The transition metal complexes of Cu 2+ , Zn 2+ , Ni 2+ , Co 2+ and Mn 2+ of the synthesized complexes were prepared. Metal ligand (M:L) ratio, IR, reflectance spectral studies, magnetic properties and antimicrobial activity of the synthesized complexes and its metal complexes were carried out

The extended epoch of galaxy formation: age dating of ~3600 galaxies with 2<z<6.5 in the VIMOS Ultra-Deep Survey

We aim at improving constraints on the epoch of galaxy formation by measuring the ages of 3597 galaxies with spectroscopic redshifts 2<z<6.5 in the VIMOS Ultra Deep Survey (VUDS). We derive ages and other physical parameters from the simultaneous fitting with the GOSSIP+ software of observed UV rest-frame spectra and photometric data from the u-band up to 4.5 microns using composite stellar population models. We conclude from extensive simulations that at z>2 the joint analysis of spectroscopy and photometry combined with restricted age possibilities when taking into account the age of the Universe substantially reduces systematic uncertainties and degeneracies in the age derivation. We find galaxy ages ranging from very young with a few tens of million years to substantially evolved with ages up to ~1.5-2 Gyr. The formation redshifts z_f derived from the measured ages indicate that galaxies may have started forming stars as early as z_f~15. We produce the formation redshift function (FzF), the number of galaxies per unit volume formed at a redshift z_f, and compare the FzF in increasing redshift bins finding a remarkably constant 'universal' FzF. The FzF is parametrized with (1+z)^\zeta, with \zeta~0.58+/-0.06, indicating a smooth 2 dex increase from z~15 to z~2. Remarkably this observed increase is of the same order as the observed rise in the star formation rate density (SFRD). The ratio of the SFRD with the FzF gives an average SFR per galaxy of ~7-17Msun/yr at z~4-6, in agreement with the measured SFR for galaxies at these redshifts. From the smooth rise in the FzF we infer that the period of galaxy formation extends from the highest possible redshifts that we can probe at z~15 down to redshifts z~2. This indicates that galaxy formation is a continuous process over cosmic time, with a higher number of galaxies forming at the peak in SFRD at z~2 than at earlier epochs. (Abridged)Comment: Submitted to A&A, 24 page

Clues to AGN Growth from Optically Variable Objects in the Hubble Ultra Deep Field

We present a photometric search for objects with point-source components that are optically variable on timescales of weeks--months in the Hubble Ultra Deep Field (HUDF) to i'(AB)=28.0 mag. The data are split into four sub-stacks of approximately equal exposure times. Objects exhibiting the signature of optical variability are selected by studying the photometric error distribution between the four different epochs, and selecting 622 candidates as 3.0 sigma outliers from the original catalog of 4644 objects. Of these, 45 are visually confirmed as free of contamination from close neighbors or various types of image defects. Four lie within the positional error boxes of Chandra X-ray sources, and two of these are spectroscopically confirmed AGN. The photometric redshift distribution of the selected variable sample is compared to that of field galaxies, and we find that a constant fraction of ~1% of all field objects show variability over the range of 0.1<z<4.5. Combined with other recent HUDF results, as well as those of recent state-of-the-art numerical simulations, we discuss a potential link between the hierarchical merging of galaxies and the growth of AGN.Comment: 9 pages, 6 figures, accepted for publication in Astrophysical Journal, minor changes to reference

Limits on the LyC signal from z~3 sources with secure redshift and HST coverage in the E-CDFS field

Aim: We aim to measure the LyC signal from a sample of sources in the Chandra deep field south. We collect star-forming galaxies (SFGs) and active galactic nuclei (AGN) with accurate spectroscopic redshifts, for which Hubble Space Telescope (HST) coverage and multi-wavelength photometry are available. Method: We selected a sample of about 200 sources at z~3. Taking advantage of HST resolution, we applied a careful cleaning procedure and rejected sources showing nearby clumps with different colours, which could be lower-z interlopers. Our clean sample consisted of 86 SFGs (including 19 narrow-band selected Lya emitters) and 8 AGN (including 6 detected in X-rays). We measured the LyC flux from aperture photometry in four narrow-band filters covering wavelengths below a 912 A rest frame (3.11<z<3.53). We estimated the ratio between ionizing (LyC flux) and 1400 A non-ionizing emissions for AGN and galaxies. Results: By running population synthesis models, we assume an average intrinsic L(1400 A)/L(900 A) ratio of 5 as the representative value for our sample. With this value and an average treatment of the lines of sight of the inter-galactic medium, we estimate the LyC escape fraction relative to the intrinsic value (fesc_rel(LyC)). We do not directly detect ionizing radiation from any individual SFG, but we are able to set a 1(2)sigma upper limit of fesc_rel(LyC)<12(24)%. This result is consistent with other non-detections published in the literature. No meaningful limits can be calculated for the sub-sample of Lya emitters. We obtain one significant direct detection for an AGN at z=3.46, with fesc_rel(LyC) = (72+/-18)%. Conclusions: Our upper limit on fescrel(LyC) implies that the SFGs studied here do not present either the physical properties or the geometric conditions suitable for efficient LyC-photon escape.Comment: Accepted for publication in A&A on Jan 5th, 201

Discovery of a rich proto-cluster at z=2.9 and associated diffuse cold gas in the VIMOS Ultra-Deep Survey (VUDS)

[Abridged] We characterise a massive proto-cluster at z=2.895 that we found in the COSMOS field using the spectroscopic sample of the VIMOS Ultra-Deep Survey (VUDS). This is one of the rare structures at z~3 not identified around AGNs or radio galaxies, so it is an ideal laboratory to study galaxy formation in dense environments. The structure comprises 12 galaxies with secure spectroscopic redshift in an area of 7'x8', in a z bin of Dz=0.016. The measured galaxy number overdensity is delta_g=12+/-2. This overdensity has total mass of M~8.1x10^(14)M_sun in a volume of 13x15x17 Mpc^3. Simulations indicate that such an overdensity at z~2.9 is a proto-cluster that will collapse in a cluster of total mass M~2.5x10^(15)M_sun at z=0. We compare the properties of the galaxies within the overdensity with a control sample at the same z but outside the overdensity. We did not find any statistically significant difference between the properties (stellar mass, SFR, sSFR, NUV-r, r-K) of the galaxies inside and outside the overdensity. The stacked spectrum of galaxies in the overdensity background shows a significant absorption feature at the wavelength of Lya redshifted at z=2.895 (lambda=4736 A), with a rest frame EW = 4+/- 1.4 A. Stacking only background galaxies without intervening sources at z~2.9 along their line of sight, we find that this absorption feature has a rest frame EW of 10.8+/-3.7 A, with a detection S/N of ~4. These EW values imply a high column density (N(HI)~3-20x10^(19)cm^(-2)), consistent with a scenario where such absorption is due to intervening cold gas streams, falling into the halo potential wells of the proto-cluster galaxies. However, we cannot exclude the hypothesis that this absorption is due to the diffuse gas within the overdensity.Comment: 15 pages, 9 figures, accepted for publication in A&A (revised version after referee's comments and language editing

The Hawk-I UDS and GOODS Survey (HUGS): Survey design and deep K-band number counts

We present the results of a new, ultra-deep, near-infrared imaging survey executed with the Hawk-I imager at the ESO VLT, of which we make all the data public. This survey, named HUGS (Hawk-I UDS and GOODS Survey), provides deep, high-quality imaging in the K and Y bands over the CANDELS UDS and GOODS-South fields. We describe here the survey strategy, the data reduction process, and the data quality. HUGS delivers the deepest and highest quality K-band images ever collected over areas of cosmological interest, and ideally complements the CANDELS data set in terms of image quality and depth. The seeing is exceptional and homogeneous, confined to the range 0.38"-0.43". In the deepest region of the GOODS-S field, (which includes most of the HUDF) the K-band exposure time exceeds 80 hours of integration, yielding a 1-sigma magnitude limit of ~28.0 mag/sqarcsec. In the UDS field the survey matches the shallower depth of the CANDELS images reaching a 1-sigma limit per sq.arcsec of ~27.3mag in the K band and ~28.3mag in the Y-band, We show that the HUGS observations are well matched to the depth of the CANDELS WFC3/IR data, since the majority of even the faintest galaxies detected in the CANDELS H-band images are also detected in HUGS. We present the K-band galaxy number counts produced by combining the HUGS data from the two fields. We show that the slope of the number counts depends sensitively on the assumed distribution of galaxy sizes, with potential impact on the estimated extra-galactic background light (abridged).Comment: Accepted for publication on Astronomy and Astrophysic

Discovering extremely compact and metal-poor, star-forming dwarf galaxies out to z ~ 0.9 in the VIMOS Ultra-Deep Survey

We report the discovery of 31 low-luminosity (-14.5 > M_{AB}(B) > -18.8), extreme emission line galaxies (EELGs) at 0.2 < z < 0.9 identified by their unusually high rest-frame equivalent widths (100 < EW[OIII] < 1700 A) as part of the VIMOS Ultra Deep Survey (VUDS). VIMOS optical spectra of unprecedented sensitivity ($I_{AB}$ ~ 25 mag) along with multiwavelength photometry and HST imaging are used to investigate spectrophotometric properties of this unique sample and explore, for the first time, the very low stellar mass end (M* < 10^8 M$_{\odot}$) of the luminosity-metallicity (LZR) and mass-metallicity (MZR) relations at z < 1. Characterized by their extreme compactness (R50 < 1 kpc), low stellar mass and enhanced specific star formation rates (SFR/M* ~ 10^{-9} - 10^{-7} yr^{-1}), the VUDS EELGs are blue dwarf galaxies likely experiencing the first stages of a vigorous galaxy-wide starburst. Using T_e-sensitive direct and strong-line methods, we find that VUDS EELGs are low-metallicity (7.5 < 12+log(O/H) < 8.3) galaxies with high ionization conditions, including at least three EELGs showing HeII 4686A emission and four EELGs of extremely metal-poor (<10% solar) galaxies. The LZR and MZR followed by EELGs show relatively large scatter, being broadly consistent with the extrapolation toward low luminosity and mass from previous studies at similar redshift. However, we find evidences that galaxies with younger and more vigorous star formation -- as characterized by their larger EWs, ionization and sSFR -- tend to be more metal-poor at a given stellar mass.Comment: Letter in A&A 568, L8 (2014). This replacement matches the published versio

The VIMOS Ultra-Deep Survey (VUDS): fast increase of the fraction of strong Lyman alpha emitters from z=2 to z=6

Aims. The aim of this work is to constrain the evolution of the fraction of Lya emitters among UV selected star forming galaxies at 2<z<6, and to measure the stellar escape fraction of Lya photons over the same redshift range. Methods. We exploit the ultradeep spectroscopic observations collected by the VIMOS Ultra Deep Survey (VUDS) to build an unique, complete and unbiased sample of 4000 spectroscopically confirmed star forming galaxies at 2<z<6. Our galaxy sample UV luminosities brighter than M* at 2<z<6, and luminosities down to one magnitude fainter than M* at 2<z<3.5. Results. We find that 80% of the star forming galaxies in our sample have EW0(Lya)<10A, and correspondingly fesc(Lya)<1%. By comparing these results with literature, we conclude that the bulk of the Lya luminosity at 2<z<6 comes from galaxies that are fainter in the UV than those we sample in this work. The strong Lya emitters constitute, at each redshift, the tail of the distribution of the galaxies with extreme EW0(Lya) and fesc(Lya) . This tail of large EW0 and fesc(Lya) becomes more important as the redshift increases, and causes the fraction of Lya with EW0> 25A to increase from 5% at z=2 to 30% at z=6, with the increase being relatively stronger beyond z=4. We observe no difference, for the narrow range of UV luminosities explored in this work, between the fraction of strong Lya emitters among galaxies fainter or brighter than M*, although the fraction for the FUV faint galaxies evolves faster, at 2<z<3.5, than for the bright ones. We do observe an anticorrelation between E(B-V) and fesc(Lya): generally galaxies with high fesc(Lya) have also small amounts of dust (and viceversa). However, when the dust content is low (E(B-V)<0.05) we observe a very broad range of fesc(Lya), ranging from 10^-3 to 1. This implies that the dust alone is not the only regulator of the amount of escaping Lya photons.Comment: 12 pages, 6 figures, A&A in pres

The VIMOS Ultra Deep Survey: Lyα\alpha Emission and Stellar Populations of Star-Forming Galaxies at 2<z<2.5

The aim of this paper is to investigate spectral and photometric properties of 854 faint ($i_{AB}$<~25 mag) star-forming galaxies (SFGs) at 2<z<2.5 using the VIMOS Ultra-Deep Survey (VUDS) spectroscopic data and deep multi-wavelength photometric data in three extensively studied extragalactic fields (ECDFS, VVDS, COSMOS). These SFGs were targeted for spectroscopy based on their photometric redshifts. The VUDS spectra are used to measure the UV spectral slopes ($\beta$) as well as Ly$\alpha$ equivalent widths (EW). On average, the spectroscopically measured $\beta$ (-1.36$\pm$0.02), is comparable to the photometrically measured $\beta$ (-1.32$\pm$0.02), and has smaller measurement uncertainties. The positive correlation of $\beta$ with the Spectral Energy Distribution (SED)-based measurement of dust extinction, E$_{\rm s}$(B-V), emphasizes the importance of $\beta$ as an alternative dust indicator at high redshifts. To make a proper comparison, we divide these SFGs into three subgroups based on their rest-frame Ly$\alpha$ EW: SFGs with no Ly$\alpha$ emission (SFG$_{\rm N}$; EW$\le$0\AA), SFGs with Ly$\alpha$ emission (SFG$_{\rm L}$; EW$>$0\AA), and Ly$\alpha$ emitters (LAEs; EW$\ge$20\AA). The fraction of LAEs at these redshifts is $\sim$10%, which is consistent with previous observations. We compared best-fit SED-estimated stellar parameters of the SFG$_{\rm N}$, SFG$_{\rm L}$ and LAE samples. For the luminosities probed here ($\sim$L$^*$), we find that galaxies with and without Ly$\alpha$ in emission have small but significant differences in their SED-based properties. We find that LAEs have less dust, and lower star-formation rates (SFR) compared to non-LAEs. We also find that LAEs are less massive compared to non-LAEs, though the difference is smaller and less significant compared to the SFR and E$_{\rm s}$(B-V). [abridged]Comment: Accepted for publication in A&A, 19 pages, 10 figures, 1 tabl

The evolution of clustering length, large-scale bias and host halo mass at 2<z<5 in the VIMOS Ultra Deep Survey (VUDS)

We investigate the evolution of galaxy clustering for galaxies in the redshift range 2.0<$z$<5.0 using the VIMOS Ultra Deep Survey (VUDS). We present the projected (real-space) two-point correlation function $w_p(r_p)$ measured by using 3022 galaxies with robust spectroscopic redshifts in two independent fields (COSMOS and VVDS-02h) covering in total 0.8 deg$^2$. We quantify how the scale dependent clustering amplitude $r_0$ changes with redshift making use of mock samples to evaluate and correct the survey selection function. Using a power-law model $\xi(r) = (r/r_0)^{-\gamma}$ we find that the correlation function for the general population is best fit by a model with a clustering length $r_0$=3.95$^{+0.48}_{-0.54}$ h$^{-1}$Mpc and slope $\gamma$=1.8$^{+0.02}_{-0.06}$ at $z$~2.5, $r_0$=4.35$\pm$0.60 h$^{-1}$Mpc and $\gamma$=1.6$^{+0.12}_{-0.13}$ at $z$~3.5. We use these clustering parameters to derive the large-scale linear galaxy bias $b_L^{PL}$, between galaxies and dark matter. We find $b_L^{PL}$ = 2.68$\pm$0.22 at redshift $z$~3 (assuming $\sigma_8$ = 0.8), significantly higher than found at intermediate and low redshifts. We fit an HOD model to the data and we obtain that the average halo mass at redshift $z$~3 is $M_h$=10$^{11.75\pm0.23}$ h$^{-1}$M$_{\odot}$. From this fit we confirm that the large-scale linear galaxy bias is relatively high at $b_L^{HOD}$ = 2.82$\pm$0.27. Comparing these measurements with similar measurements at lower redshifts we infer that the star-forming population of galaxies at $z$~3 should evolve into the massive and bright ($M_r$<-21.5) galaxy population which typically occupy haloes of mass $\langle M_h\rangle$ = 10$^{13.9}$ h$^{-1}$ $M_{\odot}$ at redshift $z$=0.Comment: 19 pages, 10 figures, submitted to A&