645 research outputs found
Reconstruction of {\AA}ngstr{\o}m resolution exit-waves by the application of drift-corrected phase-shifting off-axis electron holography
Phase-shifting electron holography is an excellent method to reveal electron
wave phase information with very high phase sensitivity over a large range of
spatial frequencies. It circumvents the limiting trade-off between fringe
spacing and visibility of standard off-axis holography. Previous
implementations have been limited by the independent drift of biprism and
sample. We demonstrate here an advanced drift correction scheme for the
hologram series that allow to obtain reliable phase information at the 1 {\AA}
information limit of the used Titan 80-300 kV environmental transmission
electron microscope using a single biprism at moderate voltage of 250 V. The
obtained phase and amplitude information is validated at a thin Pt sample by
use of multislice image simulation with the frozen lattice approximation and
shows excellent agreement. The presented method drastically reduces the
hardware requirements and thus allows to achieve high resolution in off-axis
holography in various instruments including those for in-situ applications. A
software implementation for the acquisition, calibration and reconstruction is
provided
Nanofabrication of spin-transfer torque devices by a PMMA mask one step process: GMR versus single layer devices
We present a method to prepare magnetic spin torque devices of low specific
resistance in a one step lithography process. The quality of the pillar devices
is demonstrated for a standard magnetic double layer device. For single layer
devices, we found hysteretic switching and a more complex dynamical excitation
pattern in higher fields. A simple model to explain the resistance spikes is
presented.Comment: 22 pages, 6 figures, submitted to J. Appl. Phy
Tailoring the Absorption Properties of Black Silicon
AbstractSamples of crystalline silicon for use as solar cell material are structured and hyperdoped with sulfur by irradiation with femtosecond laser pulses under a sulfur hexafluoride atmosphere. The sulfur creates energy levels in the silicon band gap, allowing light absorption in the infrared wavelength regime, which offers the potential of a significant efficiency increase. This Black Silicon is a potential candidate for impurity or intermediate band photovoltaics. In this paper we determine the laser processed sulfur energy levels by deep-level transient spectroscopy (DLTS). We present how the number of laser pulses per sample spot influence the sulfur energy levels and hence the DLTS spectra. Further we show that changing the laser pulse by splitting it with a Michelson interferometer setup results in altered absorption which is most likely due to altered sulfur energy levels. This contribution focuses on the possibility of controlling the sulfur in Black Silicon through manipulating the laser pulse shape. As a first step samples of microstructured silicon are fabricated with doubled laser pulses at two different laser pulse distances and the absorption spectra by integrating sphere measurements are compared
Optimization of nanopores generated by chemical etching of swift-ion irradiated LiNbO3.
The morphology of the nanopores obtained by chemical etching on ion-beam irradiated LiNbO3 has been investigated for a variety of ions (F, Br, Kr, Cu, Pb), energies (up to 2300 MeV), and stopping powers (up to 35 keV/nm) in the electronic energy loss regime. The role of etching time and etching agent on the pore morphology, diameter, depth, and shape has also been studied. The transversal and depth profiles of the pore have been found to be quite sensitive to both, irradiation and etching parameters. Moreover, two etching regimes with different morphologies and etching rates have been identified
Canopy uptake dominates nighttime carbonyl sulfide fluxes in a boreal forest
Nighttime vegetative uptake of carbonyl sulfide (COS) can exist due to the incomplete closure of stomata and the light independence of the enzyme carbonic anhydrase, which complicates the use of COS as a tracer for gross primary productivity (GPP). In this study we derived nighttime COS fluxes in a boreal forest (the SMEAR II station in Hyytiälä, Finland; 61°51′ N, 24°17′ E; 181 m a.s.l.) from June to November 2015 using two different methods: eddy-covariance (EC) measurements (FCOS-EC) and the radon-tracer method (FCOS-Rn). The total nighttime COS fluxes averaged over the whole measurement period were −6.8 ± 2.2 and −7.9 ± 3.8 pmol m−2 s−1 for FCOS-Rn and FCOS-EC, respectively, which is 33–38 % of the average daytime fluxes and 21 % of the total daily COS uptake. The correlation of 222Rn (of which the source is the soil) with COS (average R2  =  0.58) was lower than with CO2 (0.70), suggesting that the main sink of COS is not located at the ground. These observations are supported by soil chamber measurements that show that soil contributes to only 34–40 % of the total nighttime COS uptake. We found a decrease in COS uptake with decreasing nighttime stomatal conductance and increasing vapor-pressure deficit and air temperature, driven by stomatal closure in response to a warm and dry period in August. We also discuss the effect that canopy layer mixing can have on the radon-tracer method and the sensitivity of (FCOS-EC) to atmospheric turbulence. Our results suggest that the nighttime uptake of COS is mainly driven by the tree foliage and is significant in a boreal forest, such that it needs to be taken into account when using COS as a tracer for GPP
Direct imaging of the structural change generated by dielectric breakdown in MgO based magnetic tunnel junctions
MgO based magnetic tunnel junctions are prepared to investigate the
dielectric breakdown of the tunnel barrier. The breakdown is directly
visualized by transmission electron microscopy measurements. The broken tunnel
junctions are prepared for the microscopy measurements by focussed ion beam out
of the junctions characterized by transport investigations. Consequently, a
direct comparison of transport behavior and structure of the intact and broken
junctions is obtained. Compared to earlier findings in Alumina based junctions,
the MgO barrier shows much more microscopic pinholes after breakdown. This can
be explained within a simple model assuming a relationship between the current
density at the breakdown and the rate of pinhole formation
Towards standardized processing of eddy covariance flux measurements of carbonyl sulfide
Carbonyl sulfide (COS) flux measurements with the eddy covariance (EC) technique are becoming popular for estimating gross primary productivity. To compare COS flux measurements across sites, we need standardized protocols for data processing. In this study, we analyze how various data processing steps affect the calculated COS flux and how they differ from carbon dioxide (CO2) flux processing steps, and we provide a method for gap-filling COS fluxes. Different methods for determining the time lag between COS mixing ratio and the vertical wind velocity (w) resulted in a maximum of 15.9 % difference in the median COS flux over the whole measurement period. Due to limited COS measurement precision, small COS fluxes (below approximately 3 pmol m(-2) s(-1)) could not be detected when the time lag was determined from maximizing the covariance between COS and w. The difference between two high-frequency spectral corrections was 2.7 % in COS flux calculations, whereas omitting the high-frequency spectral correction resulted in a 14.2 % lower median flux, and different detrending methods caused a spread of 6.2 %. Relative total uncertainty was more than 5 times higher for low COS fluxes (lower than +/- 3 pmol m(-2) s(-1)) than for low CO2 fluxes (lower than +/- 1.5 mu mol m(-2) s(-1)), indicating a low signal-to-noise ratio of COS fluxes. Due to similarities in ecosystem COS and CO2 exchange, we recommend applying storage change flux correction and friction velocity filtering as usual in EC flux processing, but due to the low signal-to-noise ratio of COS fluxes, we recommend using CO2 data for time lag and high-frequency corrections of COS fluxes due to the higher signal-to-noise ratio of CO2 measurements.Peer reviewe
High regional climate sensitivity over continental China constrained by glacial-recent changes in temperature and the hydrological cycle
The East Asian monsoon is one of Earth’s most significant climatic phenomena, and numerous paleoclimate archives have revealed that it exhibits variations on orbital and suborbital time scales. Quantitative constraints on the climate changes associated with these past variations are limited, yet are needed to constrain sensitivity of the region to changes in greenhouse gas levels. Here, we show central China is a region that experienced a much larger temperature change since the Last Glacial Maximum than typically simulated by climate models. We applied clumped isotope thermometry to carbonates from the central Chinese Loess Plateau to reconstruct temperature and water isotope shifts from the Last Glacial Maximum to present. We find a summertime temperature change of 6–7 °C that is reproduced by climate model simulations presented here. Proxy data reveal evidence for a shift to lighter isotopic composition of meteoric waters in glacial times, which is also captured by our model. Analysis of model outputs suggests that glacial cooling over continental China is significantly amplified by the influence of stationary waves, which, in turn, are enhanced by continental ice sheets. These results not only support high regional climate sensitivity in Central China but highlight the fundamental role of planetary-scale atmospheric dynamics in the sensitivity of regional climates to continental glaciation, changing greenhouse gas levels, and insolation
Leaf water δ18O reflects water vapour exchange and uptake by C3 and CAM epiphytic bromeliads in Panama
The distributions of CAM and C3 epiphytic bromeliads across an altitudinal gradient in western Panama were identified from carbon isotope (δ13C) signals, and epiphyte water balance was investigated via oxygen isotopes (δ18O) across wet and dry seasons. There were significant seasonal differences in leaf water (δ18Olw), precipitation, stored 'tank' water and water vapour. Values of δ18Olw were evaporatively enriched at low altitude in the dry season for the C3 epiphytes, associated with low relative humidity (RH) during the day. Crassulacean acid metabolism (CAM) δ18Olw values were relatively depleted, consistent with water vapour uptake during gas exchange under high RH at night. At high altitude, cloudforest locations, C3 δ18Olw also reflected water vapour uptake by day. A mesocosm experiment with Tillandsia fasciculata (CAM) and Werauhia sanguinolenta (C3) was combined with simulations using a non-steady-state oxygen isotope leaf water model. For both C3 and CAM bromeliads, δ18Olw became progressively depleted under saturating water vapour by day and night, although evaporative enrichment was restored in the C3 W. sanguinolenta under low humidity by day. Source water in the overlapping leaf base 'tank' was also modified by evaporative δ18O exchanges. The results demonstrate how stable isotopes in leaf water provide insights for atmospheric water vapour exchanges for both C3 and CAM systems
Seebeck Effect in Magnetic Tunnel Junctions
Creating temperature gradients in magnetic nanostructures has resulted in a
new research direction, i.e., the combination of magneto- and thermoelectric
effects. Here, we demonstrate the observation of one important effect of this
class: the magneto-Seebeck effect. It is observed when a magnetic configuration
changes the charge based Seebeck coefficient. In particular, the Seebeck
coefficient changes during the transition from a parallel to an antiparallel
magnetic configuration in a tunnel junction. In that respect, it is the analog
to the tunneling magnetoresistance. The Seebeck coefficients in parallel and
antiparallel configuration are in the order of the voltages known from the
charge-Seebeck effect. The size and sign of the effect can be controlled by the
composition of the electrodes' atomic layers adjacent to the barrier and the
temperature. Experimentally, we realized 8.8 % magneto-Seebeck effect, which
results from a voltage change of about -8.7 {\mu}V/K from the antiparallel to
the parallel direction close to the predicted value of -12.1 {\mu}V/K.Comment: 16 pages, 7 figures, 2 table
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