The acheulean handaxe: More like a bird's song than a beatles' tune?

The goal of this paper is to provoke debate about the nature of an iconic artifact— the Acheulean handaxe. Specifically, we want to initiate a conversation about whether or not they are cultural objects. The vast majority of archeologists assume that the behaviors involved in the production of handaxes were acquired by social learning and that handaxes are therefore cultural. We will argue that this assumption is not warranted on the basis of the available evidence and that an alternative hypothesis should be given serious consideration. This alternative hypothesis is that the form of Acheulean handaxes was at least partly under genetic control

Real and perceived barriers to steel reuse across the UK construction value chain

© 2017 Elsevier B.V. Although steel reuse has been identified as an effective method to reduce the carbon and energy impact of construction, its occurrence is shrinking in the UK. This can be partly explained by the many barriers which have been identified in the literature, but a detailed analysis of how these barriers affect different parts of the supply chain is still lacking. We show that there is a contrast between perceived higher costs and time required to employ reused steel and the assessments of realised projects. Using a novel ranking method inspired from the field of information retrieval (tf-idf), we have analysed interviews of actors across the supply chain to determine the acuteness of the perception of each barrier. We show that demolition contractors, stockists, and fabricators face specific barriers which each need to be addressed at their level. This is in contrast with more generic barriers present throughout the value chain which we show are probably more perception than reality. Finally, we suggest how supply chain integration could facilitate reuse and make it economically viable at scale

Options to make steel reuse profitable: An analysis of cost and risk distribution across the UK construction value chain

Although steel reuse has been identified as an effective method to reduce the carbon and energy impact of construction, it is in effect only a marginal practice. A detailed analysis of the costs and risks of reuse in practice in the uk is lacking. We found that although there is a sufficient spread between the price of steel scrap and new steel, this difference cannot be captured by the demolition contractors. Rather, reused steel is somewhat more expensive than new elements, except in certain circumstances such as when the reused elements are available from a nearby site, or when testing elements can be avoided. Further, we show that neither the costs of steel reuse, nor the risks, nor its benefits are spread equitably throughout the construction industry supply chain: most of the substantial and capital-intensive changes required for the widespread adoption of steel reuse are concentrated on steelwork contractors and stockists. Based on this analysis, we suggest helping the emergence of a specialised stockist.This research was supported by Innovate UK, project ‘Supply Chain Integration for structural steel reuse’, ref. 132106; EPSRC Material demand reduction: NMZL/112, RG82144, EPSRC reference: EP/N02351X/1

Synthesis and reductive chemistry of bimetallic and trimetallic rare-earth metallocene hydrides with (C5H4SiMe3)1− ligands

The reductive chemistry of [Cp\u272Ln(μ–H)(THF)x]y [Ln = Y, Dy, Tb; Cp\u27 = (C5H4SiMe3)1−; x = 2, 0 and y = 2, 3] was examined to determine if these hydrides would be viable precursors for 4fn5d1 Ln2+ ions that could form 5d1-5d1 metal–metal bonded complexes. The hydrides were prepared by reaction of the chlorides, [Cp\u272Ln(μ–Cl)]2, 1-Ln, with allylmagnesium chloride to form the allyl complexes, [Cp\u272Y(η3–C3H5)(THF)], 2-Ln, which were hydrogenolyzed. The solvent-free reaction of solid 2-Ln with 60 psi of H2 gas in a Fischer-Porter apparatus produced, in the Y case, the trimetallic species, [Cp\u272Y(μ–H)]3, 3-Y, and in the Dy and Tb cases, the bimetallic complexes [Cp\u272Ln(μ–H)(THF)]2, 4-Ln (Ln = Dy, Tb). The latter complexes could be converted to 3-Dy and 3-Tb by heating under vacuum. Isopiestic data indicate that 3-Y solvates to 4-Y in THF. Reductions of 4-Y, 4-Dy, and 4-Tb with KC8 in the presence of a chelate such as 2.2.2-cryptand or 18-crown-6 all gave reaction products with intense dark colors characteristic of Ln2+ ions. In the yttrium case, with either chelating agent, the dark green product gives a rhombic EPR spectrum (g1 = 2.01, g2 = 1.99, g3 = 1.98, A = 24.1 G) at 77 K. However, the only crystallographically-characterizable products obtainable from these solutions were Ln3+polyhydride anion complexes of composition, [K(chelate)]{[Cp\u272Ln(μ–H)]3(μ–H)}

Budgetten blijven belangrijk

Contains fulltext : 135818.pdf (publisher's version ) (Open Access)Budgettering is voor veel bedrijven een wezenlijk onderdeel van het management accounting systeem. Budgettering kent van oudsher een aantal traditionele problemen zoals budgetary slack. Er is in de literatuur de laatste jaren ook een aantal problemen gesignaleerd met betrekking tot budgettering in een turbulente omgeving. Na bespreking van deze problemen, gaat dit artikel in op een empirisch onderzoek onder 52 academisch geschoolde fi nanciële functionarissen. Er wordt onder meer geconcludeerd dat bij toenemende turbulentie inderdaad meer problemen ontstaan met budgetten. Een onverwachte uitkomst was de verwerping van de hypothese dat hoe turbulenter de omgeving, hoe minder nadruk komt te liggen op het behalen van budgettaire doelen. Budgetten zijn en blijven blijkbaar belangrijk, ook in een turbulente omgeving. Een opvallende bevinding is verder dat de methode van rolling forecasts in bijna zestig procent van de bedrijven gebruikt wordt in aanvulling op het traditionele budget.9 p