64 research outputs found

    Street Art in the Context of the Historical Avant-garde

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    The objective of this study is to determine a role of historical avant-garde in forming a phenomenon of the modern culture as street-art. This study was carried out using a comparative, social and historical approaches. The revelation of connections and differences between practices of street-art and avant-garde was carried out according to following parameters such as a place of action, a specific character of the art process, its result (work), addressee/reference group, a social component. A number of peculiarities of street art, the origin of which is inspired by historical avant-garde. First of all, it is an urban art characterizing by maximum democratization and a social direction of art, removing art borders and a problem of the work of art quality. At the same time the identity of street art with avant-garde is discourteous. Street art does not possess this attributive feature as utopia, it is realistic oriented to “here and now”. Avant-garde idea of building a new world and a new man using art means is changed for less ambitious social practices directed to setting up the interaction with different reference groups. Radicalism of avant-garde lay not so much in the political sphere as aesthetic one. Radicalism of street art is connected with politicization. The novelties in the sphere of art forms of street art are not significant, they are connected with using new technologies. The results of this study showed that although street art is not avant-garde of the modern art but it is founded by the cultural field occurring due to historical avant-garde.   Keywords: avant-garde, relational art, social practice, street art, urbanis

    In system photoelectron spectroscopy study of tin oxide layers produced from tetrakis dimethylamino tin by plasma enhanced atomic layer deposition

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    Tin oxide SnO2 layers were deposited using plasma enhanced atomic layer deposition with tetrakis dimethylamino tin precursor and oxygen plasma. The deposited layers were analyzed by spectral ellipsometry, conductivity measurements, and in system photoelectron spectroscopy. Within a deposition temperature range of 90 210 amp; 8201; C, the resistivity of the SnO2 layers decreases by 5 orders of magnitude with increasing deposition temperature. At the same time, the refractive index at 632.8 amp; 8201;nm increases from 1.7 to 1.9. These changes in bulk layer properties are connected to results from photoelectron spectroscopy. It is found that decreasing carbon and nitrogen contaminations in the tin oxide layers lead to decreasing optical band gaps and increasing refractive index. Additionally, for the deposited SnO2 layers, a shoulder in the O 1s core level spectrum is observed that decreases with the deposition temperature and thus is proposed to be related to hydroxyl group

    Endothelial function, regulation of angiogenesis and embryonic central hemodynamics in ART-conceived pregnancies

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    This study was undertaken to compare the concentrations of pro- and anti-angiogenic growth factors, nitric oxide (NO) stable metabolites in maternal serum and embryonic left ventricular (LV) isovolumic relaxation time (IRT, ms) during the first trimester in two groups of women: with pregnancy conceived by assisted reproductive technologies (ART, nј39) and normally conceived (control group, nј68) pregnancy. The concentration of vasoconstrictor endothelin 1 was 45.5 times more in ART than in control group. On the contrary, the concentrations of NO stable metabolites in ART were 1.9 times less than in control women. The assessment of angiogenic suppressors in ART women demonstrates the decrease in s-endoglin concentration was 1.6 times and in soluble receptor to vascular endothelial growth factor concentration was 2.0 times in comparison with control group. There was a significant increase in LV IRT in ART embryos in comparison to control ones. These data suggest significant changes in pro-antiangiogenic factors balance and increase in vascular impedance in ART-conceived embryos

    Rapid scalable processing of tin oxide transport layers for perovskite solar cells

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    The development of scalable deposition methods for perovskite solar cell materials is critical to enable the commercialization of this nascent technology. Herein, we investigate the use and processing of nanoparticle SnO2 films as electron transport layers in perovskite solar cells and develop deposition methods for ultrasonic spray coating and slot-die coating, leading to photovoltaic device efficiencies over 19%. The effects of postprocessing treatments (thermal annealing, UV ozone, and O2 plasma) are then probed using structural and spectroscopic techniques to characterize the nature of the np-SnO2/perovskite interface. We show that a brief “hot air flow” method can be used to replace extended thermal annealing, confirming that this approach is compatible with high-throughput processing. Our results highlight the importance of interface management to minimize nonradiative losses and provide a deeper understanding of the processing requirements for large-area deposition of nanoparticle metal oxides

    Photonic gas sensors exploiting directly the optical properties of hybrid carbon nanotube localized surface plasmon structures

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    We investigate the modification of the optical properties of carbon nanotubes (CNTs) resulting from a chemical reaction triggered by the presence of a specific compound (gaseous carbon dioxide (CO2)) and show this mechanism has important consequences for chemical sensing. CNTs have attracted significant research interest because they can be functionalized for a particular chemical, yielding a specific physical response which suggests many potential applications in the fields of nanotechnology and sensing. So far, however, utilizing their optical properties for this purpose has proven to be challenging. We demonstrate the use of localized surface plasmons generated on a nanostructured thin film, resembling a large array of nano-wires, to detect changes in the optical properties of the CNTs. Chemical selectivity is demonstrated using CO2 in gaseous form at room temperature. The demonstrated methodology results additionally in a new, electrically passive, optical sensing configuration that opens up the possibilities of using CNTs as sensors in hazardous/explosive environments

    Interface Molecular engineering for laminated monolithic perovskite/silicon tandem solar cells with 80.4% fill factor

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    A multipurpose interconnection layer based on poly(3,4‐ethylenedioxythiophene) doped with poly(styrene sulfonate) (PEDOT:PSS), and d‐sorbitol for monolithic perovskite/silicon tandem solar cells is introduced. The interconnection of independently processed silicon and perovskite subcells is a simple add‐on lamination step, alleviating common fabrication complexities of tandem devices. It is demonstrated experimentally and theoretically that PEDOT:PSS is an ideal building block for manipulating the mechanical and electrical functionality of the charge recombination layer by controlling the microstructure on the nano‐ and mesoscale. It is elucidated that the optimal functionality of the recombination layer relies on a gradient in the d‐sorbitol dopant distribution that modulates the orientation of PEDOT across the PEDOT:PSS film. Using this modified PEDOT:PSS composite, a monolithic two‐terminal perovskite/silicon tandem solar cell with a steady‐state efficiency of 21.0%, a fill factor of 80.4%, and negligible open circuit voltage losses compared to single‐junction devices is shown. The versatility of this approach is further validated by presenting a laminated two‐terminal monolithic perovskite/organic tandem solar cell with 11.7% power conversion efficiency. It is envisioned that this lamination concept can be applied for the pairing of multiple photovoltaic and other thin film technologies, creating a universal platform that facilitates mass production of tandem devices with high efficiency

    Nonspecific synaptic plasticity improves the recognition of sparse patterns degraded by local noise

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    Safaryan, K. et al. Nonspecific synaptic plasticity improves the recognition of sparse patterns degraded by local noise. Sci. Rep. 7, 46550; doi: 10.1038/srep46550 (2017). This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ © The Author(s) 2017.Many forms of synaptic plasticity require the local production of volatile or rapidly diffusing substances such as nitric oxide. The nonspecific plasticity these neuromodulators may induce at neighboring non-active synapses is thought to be detrimental for the specificity of memory storage. We show here that memory retrieval may benefit from this non-specific plasticity when the applied sparse binary input patterns are degraded by local noise. Simulations of a biophysically realistic model of a cerebellar Purkinje cell in a pattern recognition task show that, in the absence of noise, leakage of plasticity to adjacent synapses degrades the recognition of sparse static patterns. However, above a local noise level of 20 %, the model with nonspecific plasticity outperforms the standard, specific model. The gain in performance is greatest when the spatial distribution of noise in the input matches the range of diffusion-induced plasticity. Hence non-specific plasticity may offer a benefit in noisy environments or when the pressure to generalize is strong.Peer reviewe

    Heterosynaptic plasticity in the neocortex

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    Ongoing learning continuously shapes the distribution of neurons’ synaptic weights in a system with plastic synapses. Plasticity may change the weights of synapses that were active during the induction—homosynaptic changes, but also may change synapses not active during the induction—heterosynaptic changes. Here we will argue, that heterosynaptic and homosynaptic plasticity are complementary processes, and that heterosynaptic plasticity might accompany homosynaptic plasticity induced by typical pairing protocols. Synapses are not uniform in their susceptibility for plastic changes, but have predispositions to undergo potentiation or depression, or not to change. Predisposition is one of the factors determining the direction and magnitude of homo- and heterosynaptic changes. Heterosynaptic changes which take place according to predispositions for plasticity may provide a useful mechanism(s) for homeostasis of neurons’ synaptic weights and extending the lifetime of memory traces during ongoing learning in neuronal networks
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