543 research outputs found
Depletion of density of states near Fermi energy induced by disorder and electron correlation in alloys
We have performed high resolution photoemission study of substitutionally
disordered alloys Cu-Pt, Cu-Pd, Cu-Ni, and Pd-Pt. The ratios between alloy
spectra and pure metal spectra are found to have dips at the Fermi level when
the residual resistivity is high and when rather strong repulsive
electron-electron interaction is expected. This is in accordance with Altshuler
and Aronov's model which predicts depletion of density of states at the Fermi
level when both disorder and electron correlation are present.Comment: 1 tex file and 4 ps file
Dielectronic Resonance Method for Measuring Isotope Shifts
Longstanding problems in the comparison of very accurate hyperfine-shift
measurements to theory were partly overcome by precise measurements on
few-electron highly-charged ions. Still the agreement between theory and
experiment is unsatisfactory. In this paper, we present a radically new way of
precisely measuring hyperfine shifts, and demonstrate its effectiveness in the
case of the hyperfine shift of and in
. It is based on the precise detection of dielectronic
resonances that occur in electron-ion recombination at very low energy. This
allows us to determine the hyperfine constant to around 0.6 meV accuracy which
is on the order of 10%
Position controlled self-catalyzed growth of GaAs nanowires by molecular beam epitaxy
GaAs nanowires are grown by molecular beam epitaxy using a self-catalyzed,
Ga-assisted growth technique. Position control is achieved by nano-patterning a
SiO2 layer with arrays of holes with a hole diameter of 85 nm and a hole pitch
varying between 200 nm and 2 \mum. Gallium droplets form preferentially at the
etched holes acting as catalyst for the nanowire growth. The nanowires have
hexagonal cross-sections with {110} side facets and crystallize predominantly
in zincblende. The interdistance dependence of the nanowire growth rate
indicates a change of the III/V ratio towards As-rich conditions for large hole
distances inhibiting NW growth.Comment: 9 pages, 4 figure
Resonant Auger spectroscopy at the L2,3 shake-up thresholds as a probe of electron correlation effects in nickel
The excitation energy dependence of the three-hole satellites in the
L3-M4,5M4,5 and L2-M4,5M4,5 Auger spectra of nickel metal has been measured
using synchrotron radiation. The satellite behavior in the non-radiative
emission spectra at the L3 and L2 thresholds is compared and the influence of
the Coster-Kronig channel explored. The three-hole satellite intensity at the
L3 Auger emission line reveals a peak structure at 5 eV above the L3 threshold
attributed to resonant processes at the 2p53d9 shake-up threshold. This is
discussed in connection with the 6-eV feature in the x-ray absorption spectrum.Comment: 8 pages, 4 figures; http://prb.aps.org/abstract/PRB/v58/i7/p3677_
Unexpected selections of Plasmodium falciparum polymorphisms in previously treatment-naĂŻve areas after monthly presumptive administration of three different anti-malarial drugs in Liberia 1976-78.
BACKGROUND: To assess the effect on malaria prevalence, village specific monthly administrations of pyrimethamine, chlorproguanil, chloroquine or placebo were given to children in four previously treatment-naĂŻve Liberian villages, 1976-78. Plasmodium falciparum in vivo resistance developed to pyrimethamine only. Selection of molecular markers of P. falciparum resistance after 2Â years of treatment are reported. METHODS: Blood samples were collected from 191 study children in a survey in 1978. Polymorphisms in pfcrt, pfmdr1, pfdhfr, pfdhps, pfmrp1 and pfnhe1 genes were determined using PCR-based methods. RESULTS: Pfcrt 72-76 CVIET was found in one chloroquine village sample, all remaining samples had pfcrt CVMNK. Pfmdr1 N86 prevalence was 100%. A pfmdr1 T1069ACTâACG synonymous polymorphism was found in 30% of chloroquine village samples and 3% of other samples (PÂ =Â 0.008). Variations in pfnhe1 block I were found in all except the chloroquine treated village (PÂ <Â 0.001). Resistance associated pfdhfr 108N prevalence was 2% in the pyrimethamine village compared to 45-65% elsewhere, including the placebo village (PÂ =Â 0.001). CONCLUSIONS: Chloroquine treatment possibly resulted in the development of pfcrt 72-76 CVIET. Selection of pfmdr1 T1069ACG and a pfnhe1 block 1 genotypes indicates that chloroquine treatment exerted a selective pressure on P. falciparum. Pyrimethamine resistance associated pfdhfr 108N was present prior to the introduction of any drug. Decreased pfdhfr 108N frequency concurrent with development of pyrimethamine resistance suggests a non-pfdhfr polymorphisms mediated resistance mechanism
Correction of non-linearity effects in detectors for electron spectroscopy
Using photoemission intensities and a detection system employed by many
groups in the electron spectroscopy community as an example, we have
quantitatively characterized and corrected detector non-linearity effects over
the full dynamic range of the system. Non-linearity effects are found to be
important whenever measuring relative peak intensities accurately is important,
even in the low-countrate regime. This includes, for example, performing
quantitative analyses for surface contaminants or sample bulk stoichiometries,
where the peak intensities involved can differ by one or two orders of
magnitude, and thus could occupy a significant portion of the detector dynamic
range. Two successful procedures for correcting non-linearity effects are
presented. The first one yields directly the detector efficiency by measuring a
flat-background reference intensity as a function of incident x-ray flux, while
the second one determines the detector response from a least-squares analysis
of broad-scan survey spectra at different incident x-ray fluxes. Although we
have used one spectrometer and detection system as an example, these
methodologies should be useful for many other cases.Comment: 13 pages, 12 figure
Introducing Perennial Grain in Grain Crops Rotation: The Role of Rooting Pattern in Soil Quality Management
The use of the perennial grain intermediate wheatgrass (Thinopyrum intermedium(Host) Barkworth & D.R. Dewey) may have the potential to sustain soil health and fertility through the development of an extensive root system. However, references are scarce to demonstrate its potential influence in a context of a limited perennial grain growth phase, integrated into annual grain crops succession. This study aims at determining how early a perennial crop rooting system differs from that of an annual crop through root development and root traits and microbial indicators. Our results indicate that the two-year-old intermediate wheatgrass promotes a denser and deeper rooting system with proportionally more root biomass and length deeper in the soil profile. From the first growing season, the perennial grain demonstrated a suite of root traits typical of a more resource-conservative strategy, and more belowground-oriented resource allocation. Soil fungal biomass indicators were enhanced. Arbuscular mycorrhizal fungi (AMF) indicators were notably found to be improved at 1 m depth during the second growing season. This study provides evidence that grain-based agriculture can benefit from the potential of deeper and long-lived root systems of intermediate wheatgrass to manage soils. The periodic use of a short-term perennial phase in the crop rotation has the potential to improve soil functioning in the long term
Intramolecular vibronic dynamics in molecular solids: C60
Vibronic coupling in solid C60 has been investigated with a combination of resonant photoemission spectroscopy (RPES) and resonant inelastic x-ray scattering (RIXS). Excitation as a function of energy within the lowest unoccupied molecular orbital resonance yielded strong oscillations in intensity and dispersion in RPES, and a strong inelastic component in RIXS. Reconciling these two observations establishes that vibronic coupling in this core hole excitation leads to predominantly inelastic scattering and localization of the excited vibrations on the molecule on a femtosecond time scale. The coupling extends throughout the widths of the frontier valence bands.
Effect of the GaAsP shell on optical properties of self-catalyzed GaAs nanowires grown on silicon
We realize growth of self-catalyzed core-shell GaAs/GaAsP nanowires (NWs) on
Si substrates using molecular-beam epitaxy. Transmission electron microscopy
(TEM) of single GaAs/GaAsP NWs confirms their high crystal quality and shows
domination of the zinc-blende phase. This is further confirmed in optics of
single NWs, studied using cw and time-resolved photoluminescence (PL). A
detailed comparison with uncapped GaAs NWs emphasizes the effect of the GaAsP
capping in suppressing the non-radiative surface states: significant PL
enhancement in the core-shell structures exceeding 2000 times at 10K is
observed; in uncapped NWs PL is quenched at 60K whereas single core-shell
GaAs/GaAsP NWs exhibit bright emission even at room temperature. From analysis
of the PL temperature dependence in both types of NW we are able to determine
the main carrier escape mechanisms leading to the PL quench
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