Photoinduced dynamics in protonated aromatic amino acid

UV photoinduced fragmentation of protonated aromatics amino acids have emerged the last few years, coming from a situation where nothing was known to what we think a good understanding of the optical properties. We will mainly focus this review on the tryptophan case. Three groups have mostly done spectroscopic studies and one has mainly been involved in dynamics studies of the excited states in the femtosecond/picosecond range and also in the fragmentation kinetics from nanosecond to millisecond. All these data, along with high level ab initio calculations, have shed light on the role of the different electronic states of the protonated molecules upon the fragmentation mechanisms

Estimation de la cartographie du coefficient d'échange convectif par thermographie infrarouge

Le coefficient d'échange convectif est un paramètre pertinent lorsqu'il s'agit de modéliser le comportement thermique d'un système physique. Dans ce texte, à partir de deux modèles thermiques écrits et discrétisés à l'échelle du pixel nous avons construit deux fonctionnelles qui relient variables observables en occurrence les champs de températures mesurés par une caméra infrarouge et les variables à estimer (coefficient d'échange convectif et/ou diffusivité thermique). Les cartographies du coefficient d'échange convectif sont obtenus en minimisant ces deux fonctionnelles. Ici, les résultats que donnent ces deux modèles sont présentés et confrontés. Nous montrons que lorsque les effets de refroidissement sont prépondérants, la diffusion de la chaleur dans le système physique peut être négligée dans l'estimation du coefficient d'échange convectif. Les valeurs de corrélations linéaires entre le champ de température et sa dérivée temporelle montrent que ces deux grandeurs sont relativement bien corrélées

Scoring Message Stream Anomalies in Railway Communication Systems

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Updated Operational Reliability from Degradation Indicators and Adaptive Maintenance Strategy

This chapter is dedicated to the reliability and maintenance of assets that are characterized by a degradation process. The item state is related to a degradation mechanism that represents the unit-to-unit variability and time-varying dynamics of systems. The maintenance scheduling has to be updated considering the degradation history of each item. The research method relies on the updating process of the reliability of a specific asset. Given a degradation process and costs for preventive/corrective maintenance actions, an optimal inspection time is obtained. At this time, the degradation level is measured and a prediction of the degradation is conducted to obtain the next inspection time. A decision criterion is established to decide whether the maintenance action should take place at the current time or postpone. Consequently, there is an optimal number of inspections that allows to extend the useful life of an asset before performing the preventive maintenance action. A numerical case study involving a non-stationary Wiener-based degradation process is proposed as an illustration of the methodology. The results showed that the expected cost per unit of time considering the adaptive maintenance strategy is lower than the expected cost per unit of time obtained for other maintenance policies

Scoring Message Stream Anomalies in Railway Communication Systems

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Auxin fluxes in the root apex co-regulate gravitropism and lateral root initiation

International audienceRoot architecture plays an important role in water and nutrient acquisition and in the ability of the plant to adapt to the soil. Lateral root development is the main determinant of the shape of the root system and is controlled by external factors such as nutrient concentration. Here it is shown that lateral root initiation and root gravitropism, two processes that are regulated by auxin, are co-regulated in Arabidopsis. A mathematical model was generated that can predict the effects of gravistimulations on lateral root initiation density and suggests that lateral root initiation is controlled by an inhibitory fields mechanism. Moreover, gene transactivation experiments suggest a mechanism involving a single auxin transport route for both responses. Finally, co-regulation may offer a selective advantage by optimizing soil exploration as supported by a simple quantitative analysis

Modeling auxin fluxes and Arabidopsis root ramification at different scales

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Single-photon absorption of isolated collagen mimetic peptides and triple-helix models in the VUV-X energy range

Cartilage and tendons owe their special mechanical properties to the fibrous collagen structure. These strong fibrils are aggregates of a sub-unit consisting of three collagen proteins wound around each other in a triple helix. Even though collagen is the most abundant protein in the human body, the response of this protein complex to ionizing radiation has never been studied. In this work, we probe the direct effects of VUV and soft X-ray photons on isolated models of the collagen triple helix, by coupling a tandem mass spectrometer to a synchrotron beamline. Single-photon absorption is found to induce electronic excitation, ionization and conversion into internal energy leading to inter- and intra-molecular fragmentation, mainly due to Gly-Pro peptide bond cleavages. Our results indicate that increasing the photon energy from 14 to 22 eV reduces fragmentation. We explain this surprising behavior by a smooth transition from excitation to ionization occurring with increasing photon energy. Moreover, our data support the assumption of a stabilization of the triple helix models by proline hydroxylation via intra-complex stereoelectronic effects, instead of the influence of solvent

Herschel Observations of the T Cha Transition Disk: Constraining the Outer Disk Properties

T Cha is a nearby (d similar to 100 pc) transition disk known to have an optically thin gap separating optically thick inner and outer disk components. Huelamo et al. recently reported the presence of a low-mass object candidate within the gap of the T Cha disk, giving credence to the suspected planetary origin of this gap. Here we present the Herschel photometry (70, 160, 250, 350, and 500 mu m) of T Cha from the "Dust, Ice, and Gas in Time" Key Program, which bridges the wavelength range between existing Spitzer and millimeter data and provide important constraints on the outer disk properties of this extraordinary system. We model the entire optical to millimeter wavelength spectral energy distribution (SED) of T Cha (19 data points between 0.36 and 3300 mu m without any major gaps in wavelength coverage). T Cha shows a steep spectral slope in the far-IR, which we find clearly favors models with outer disks containing little or no dust beyond similar to 40 AU. The full SED can be modeled equally well with either an outer disk that is very compact (only a few AU wide) or a much larger one that has a very steep surface density profile. That is, T Cha's outer disk seems to be either very small or very tenuous. Both scenarios suggest a highly unusual outer disk and have important but different implications for the nature of T Cha. Spatially resolved images are needed to distinguish between the two scenarios.DIGIT Herschel Open Time Key ProgramNASAAlexander von Humboldt FoundationEuropean CommissionAgence Nationale pour la Recherche of France PERG06-GA-2009-256513, ANR-07-BLAN-0221, ANR-2010-JCJC-0504-01CNRS/INSU, FranceAstronom