666 research outputs found
Selectivity of hydrogen chemisorption on clean and lead modified palladium particles; a TPD and photoemission study
This work describes hydrogen chemisorption on clean and lead modified palladium particles obtained from decomposition of PdO. TPD is used as a chemical probe to test the surface properties of several states of metallic palladium relevant in practical selective hydrogenation catalysts. These states differ in oxygen content and the presence of a lead modifier. XPS and UPS data serve as a basis for identifying the surface properties. TPD spectra show a very broad low temperature peak-likely bulk hydride decomposition-and a sharp TPD peak between 330 and 380 K. This latter can be devided into three rather poorly separated subpeaks; addition of Pb does not shift peak maxima but decreases the central subpeak and eliminates the high temperature peak completely. This points to the interaction of Pb with specific surface sites rather than to bulk alloy formation. The enhancement of selectivity in hydrogenation obtained from lead modification is considered as a geometric site blocking effect rather than to arise from a bulk modification of the valence electronic structure of palladium metal
Protein Pattern Formation
Protein pattern formation is essential for the spatial organization of many
intracellular processes like cell division, flagellum positioning, and
chemotaxis. A prominent example of intracellular patterns are the oscillatory
pole-to-pole oscillations of Min proteins in \textit{E. coli} whose biological
function is to ensure precise cell division. Cell polarization, a prerequisite
for processes such as stem cell differentiation and cell polarity in yeast, is
also mediated by a diffusion-reaction process. More generally, these functional
modules of cells serve as model systems for self-organization, one of the core
principles of life. Under which conditions spatio-temporal patterns emerge, and
how these patterns are regulated by biochemical and geometrical factors are
major aspects of current research. Here we review recent theoretical and
experimental advances in the field of intracellular pattern formation, focusing
on general design principles and fundamental physical mechanisms.Comment: 17 pages, 14 figures, review articl
Quasi Harmonic Lattice Dynamics and Molecular Dynamics calculations for the Lennard-Jones solids
We present Molecular Dynamics (MD), Quasi Harmonic Lattice Dynamics (QHLD)
and Energy Minimization (EM) calculations for the crystal structure of Ne, Ar,
Kr and Xe as a function of pressure and temperature. New Lennard-Jones (LJ)
parameters are obtained for Ne, Kr and Xe to reproduce the experimental
pressure dependence of the density. We employ a simple method which combines
results of QHLD and MD calculations to achieve densities in good agreement with
experiment from 0 K to melting. Melting is discussed in connection with
intrinsic instability of the solid as given by the QHLD approximation. (See
http://www.fci.unibo.it/~valle for related papers)Comment: 7 pages, 5 figures, REVte
Imaging Jupiter's radiation belts down to 127 MHz with LOFAR
Context. Observing Jupiter's synchrotron emission from the Earth remains
today the sole method to scrutinize the distribution and dynamical behavior of
the ultra energetic electrons magnetically trapped around the planet (because
in-situ particle data are limited in the inner magnetosphere). Aims. We perform
the first resolved and low-frequency imaging of the synchrotron emission with
LOFAR at 127 MHz. The radiation comes from low energy electrons (~1-30 MeV)
which map a broad region of Jupiter's inner magnetosphere. Methods (see article
for complete abstract) Results. The first resolved images of Jupiter's
radiation belts at 127-172 MHz are obtained along with total integrated flux
densities. They are compared with previous observations at higher frequencies
and show a larger extent of the synchrotron emission source (>=4 ). The
asymmetry and the dynamic of east-west emission peaks are measured and the
presence of a hot spot at lambda_III=230 {\deg} 25 {\deg}. Spectral flux
density measurements are on the low side of previous (unresolved) ones,
suggesting a low-frequency turnover and/or time variations of the emission
spectrum. Conclusions. LOFAR is a powerful and flexible planetary imager. The
observations at 127 MHz depict an extended emission up to ~4-5 planetary radii.
The similarities with high frequency results reinforce the conclusion that: i)
the magnetic field morphology primarily shapes the brightness distribution of
the emission and ii) the radiating electrons are likely radially and
latitudinally distributed inside about 2 . Nonetheless, the larger extent
of the brightness combined with the overall lower flux density, yields new
information on Jupiter's electron distribution, that may shed light on the
origin and mode of transport of these particles.Comment: 10 pages, 12 figures, accepted for publication in A&A (27/11/2015) -
abstract edited because of limited character
Optimized Trigger for Ultra-High-Energy Cosmic-Ray and Neutrino Observations with the Low Frequency Radio Array
When an ultra-high energy neutrino or cosmic ray strikes the Lunar surface a
radio-frequency pulse is emitted. We plan to use the LOFAR radio telescope to
detect these pulses. In this work we propose an efficient trigger
implementation for LOFAR optimized for the observation of short radio pulses.Comment: Submitted to Nuclear Instruments and Methods in Physics Research
Section
Star Formation in the Central 400 pc of the Milky Way: Evidence for a Population of Massive YSOs
The central kpc of the Milky Way might be expected to differ significantly
from the rest of the Galaxy with regard to gas dynamics and the formation of
YSOs. We probe this possibility with mid-infrared observations obtained with
IRAC and MIPS on Spitzer and with MSX. We use color-color diagrams and SED fits
to explore the nature of YSO candidates (including objects with 4.5 micron
excesses possibly due to molecular emission). There is an asymmetry in the
distribution of the candidate YSOs, which tend to be found at negative Galactic
longitudes; this behavior contrasts with that of the molecular gas,
approximately 2/3 of which is at positive longitudes. The small scale height of
these objects suggests that they are within the Galactic center region and are
dynamically young. They lie between two layers of infrared dark clouds and may
have originated from these clouds. We identify new sites for this recent star
formation. The methanol masers appear to be associated with young, embedded
YSOs characterized by 4.5 micron excesses. We use the SEDs of these sources to
estimate their physical characteristics. Within the central 400x50 pc
(|l|<1.3\degr and |b|<10') the star formation rate based on the identification
of Stage I evolutionary phase of YSO candidates is about 0.14 solar mass/yr. We
suggest that a recent burst of star formation took place within the last 10^5
years. This suggestion is also consistent with estimates of star formation
rates within the last ~10^7 years showing a peak around 10^5 years ago. Lastly,
we find that the Schmidt-Kennicutt Law applies well in the central 400 pc of
the Galaxy. This implies that star formation does not appear to be dramatically
affected by the extreme physical conditions in the Galactic center region.Comment: 96 pages, ten tables, 35 figures, ApJ (in press), replaced by a
revised versio
Chromosome Driven Spatial Patterning of Proteins in Bacteria
The spatial patterning of proteins in bacteria plays an important role in many processes, from cell division to chemotaxis. In the asymmetrically dividing bacteria Caulobacter crescentus, a scaffolding protein, PopZ, localizes to both poles and aids the differential patterning of proteins between mother and daughter cells during division. Polar patterning of misfolded proteins in Escherechia coli has also been shown, and likely plays an important role in cellular ageing. Recent experiments on both of the above systems suggest that the presence of chromosome free regions along with protein multimerization may be a mechanism for driving the polar localization of proteins. We have developed a simple physical model for protein localization using only these two driving mechanisms. Our model reproduces all the observed patterns of PopZ and misfolded protein localization - from diffuse, unipolar, and bipolar patterns and can also account for the observed patterns in a variety of mutants. The model also suggests new experiments to further test the role of the chromosome in driving protein patterning, and whether such a mechanism is responsible for helping to drive the differentiation of the cell poles
The distribution of water in the high-mass star-forming region NGC 6334I
We present observations of twelve rotational transitions of H2O-16, H2O-18,
and H2O-17 toward the massive star-forming region NGC 6334 I, carried out with
Herschel/HIFI as part of the guaranteed time key program Chemical HErschel
Surveys of Star forming regions (CHESS). We analyze these observations to
obtain insights into physical processes in this region.
We identify three main gas components (hot core, cold foreground, and
outflow) in NGC 6334 I and derive the physical conditions in these components.
The hot core, identified by the emission in highly excited lines, shows a
high excitation temperature of 200 K, whereas water in the foreground component
is predominantly in the ortho- and para- ground states. The abundance of water
varies between 4 10^-5 (outflow) and 10^-8 (cold foreground gas). This
variation is most likely due to the freeze-out of water molecules onto dust
grains. The H2O-18/H2O-17 abundance ratio is 3.2, which is consistent with the
O-18/O-17 ratio determined from CO isotopologues. The ortho/para ratio in water
appears to be relatively low 1.6(1) in the cold, quiescent gas, but close to
the equilibrium value of three in the warmer outflow material (2.5(0.8)).Comment: 7 pages, 3 figures, accepted by A&
Genomics and biochemical analyses reveal a metabolon key to β-L-ODAP biosynthesis in Lathyrus sativus
Grass pea (Lathyrus sativus L.) is a rich source of protein cultivated as an insurance crop in Ethiopia, Eritrea, India, Bangladesh, and Nepal. Its resilience to both drought and flooding makes it a promising crop for ensuring food security in a changing climate. The lack of genetic resources and the crop’s association with the disease neurolathyrism have limited the cultivation of grass pea. Here, we present an annotated, long read-based assembly of the 6.5 Gbp L. sativus genome. Using this genome sequence, we have elucidated the biosynthetic pathway leading to the formation of the neurotoxin, β-L-oxalyl-2,3-diaminopropionic acid (β-L-ODAP). The final reaction of the pathway depends on an interaction between L. sativus acyl-activating enzyme 3 (LsAAE3) and a BAHD-acyltransferase (LsBOS) that form a metabolon activated by CoA to produce β-L-ODAP. This provides valuable insight into the best approaches for developing varieties which produce substantially less toxi
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