Titan brighter at twilight than in daylight

Investigating the overall brightness of planets (and moons) provides insight into their envelopes and energy budgets [1, 2, 3, 4]. Titan phase curves (a representation of overall brightness vs. Sun-object-observer phase angle) have been published over a limited range of phase angles and spectral passbands [5, 6]. Such information has been key to the study of the stratification, microphysics and aggregate nature of Titan's atmospheric haze [7, 8], and has complemented the spatially-resolved observations first showing that the haze scatters efficiently in the forward direction [7, 9]. Here we present Cassini Imaging Science Subsystem whole-disk brightness measurements of Titan from ultraviolet to near-infrared wavelengths. The observations reveal that Titan's twilight (loosely defined as the view when the phase angle 150deg) outshines its daylight at various wavelengths. From the match between measurements and models, we show that at even larger phase angles the back-illuminated moon will appear much brighter than when fully illuminated. This behavior is unique to Titan in our solar system, and is caused by its extended atmosphere and the efficient forward scattering of sunlight by its atmospheric haze. We infer a solar energy deposition rate (for a solar constant of 14.9 Wm-2) of (2.84+/-0.11)x10^14 W, consistent to within 1-2 standard deviations with Titan's time-varying thermal emission spanning 2007- 2013 [10, 11]. We propose that a forward scattering signature may also occur at large phase angles in the brightness of exoplanets with extended hazy atmospheres, and that this signature has valuable diagnostic potential for atmospheric characterization.Comment: Pre-print of a manuscript published in Nature Astronomy 1, 0114 (2017) DOI: 10.1038/s41550-017-0114, http://www.nature.com/nastronom

An estimate of the chemical composition of Titan's lakes

Hundreds of radar-dark patches interpreted as lakes have been discovered in the north and south polar regions of Titan. We have estimated the composition of these lakes by using the direct abundance measurements from the Gas Chromatograph Mass Spectrometer (GCMS) aboard the Huygens probe and recent photochemical models based on the vertical temperature profile derived by the Huygens Atmospheric Structure Instrument (HASI). Thermodynamic equilibrium is assumed between the atmosphere and the lakes, which are also considered as nonideal solutions. We find that the main constituents of the lakes are ethane (C2H6) (~76-79%), propane (C3H8) (~7-8%), methane (CH4) (~5-10%), hydrogen cyanide (HCN) (~2-3%), butene (C4H8) (~1%), butane (C4H10) (~1%) and acetylene (C2H2) (~1%). The calculated composition of lakes is then substantially different from what has been expected from models elaborated prior to the exploration of Titan by the Cassini-Huygens spacecraft.Comment: 5 pages, 2 figures, accepted in ApJ

Photochemical hazes in sub-Neptunian atmospheres with focus on GJ 1214 b

We study the properties of photochemical hazes in super-Earths/mini-Neptunes atmospheres with particular focus on GJ1214b. We evaluate photochemical haze properties at different metallicities between solar and 10000$\times$solar. Within the four orders of magnitude change in metallicity, we find that the haze precursor mass fluxes change only by a factor of $\sim$3. This small diversity occurs with a non-monotonic manner among the different metallicity cases, reflecting the interaction of the main atmospheric gases with the radiation field. Comparison with relative haze yields at different metallicities from laboratory experiments reveals a qualitative similarity with our theoretical calculations and highlights the contributions of different gas precursors. Our haze simulations demonstrate that higher metallicity results into smaller average particle sizes. Metallicities at and above 100$\times$solar with haze formation yields of $\sim$10$\%$ provide enough haze opacity to satisfy transit observation at visible wavelengths and obscure sufficiently the H$_2$O molecular absorption features between 1.1 $\mu$m and 1.7 $\mu$m. However, only the highest metallicity case considered (10000$\times$solar) brings the simulated spectra into closer agreement with transit depths at 3.6 $\mu$m and 4.5 $\mu$m indicating a high contribution of CO/CO$_2$ in GJ1214b's atmosphere. We also evaluate the impact of aggregate growth in our simulations, in contrast to spherical growth, and find that the two growth modes provide similar transit signatures (for D$_f$=2), but with different particle size distributions. Finally, we conclude that the simulated haze particles should have major implications for the atmospheric thermal structure and for the properties of condensation clouds

Titan's lakes chemical composition: sources of uncertainties and variability

Between 2004 and 2007 the instruments of the CASSINI spacecraft discovered hydrocarbon lakes in the polar regions of Titan. We have developed a lake-atmosphere equilibrium model allowing the determination of the chemical composition of these liquid areas. The model is based on uncertain thermodynamic data and precipitation rates of organic species predicted to be present in the lakes and seas that are subject to spatial and temporal variations. Here we explore and discuss the influence of these uncertainties and variations. The errors and uncertainties relevant to thermodynamic data are simulated via Monte-Carlo simulations. Global Circulation Models (GCM) are also employed in order to investigate the possibility of chemical asymmetry between the south and the north poles, due to differences in precipitation rates. We find that mole fractions of compounds in the liquid phase have a high sensitivity to thermodynamic data used as inputs, in particular molar volumes and enthalpies of vaporization. When we combine all considered uncertainties, the ranges of obtained mole fractions are rather large (up to ~8500%) but the distributions of values are narrow. The relative standard deviations remain between 10% and ~300% depending on the compound considered. Compared to other sources of uncertainties and variability, deviation caused by surface pressure variations are clearly negligible, remaining of the order of a few percent up to ~20%. Moreover no significant difference is found between the composition of lakes located in north and south poles. Because the theory of regular solutions employed here is sensitive to thermodynamic data and is not suitable for polar molecules such as HCN and CH3CN, our work strongly underlines the need for experimental simulations and the improvement of Titan's atmospheric models.Comment: Accepted in Planetary and Space Scienc

Titan Haze

The Titan haze exerts a dominating influence on surface visibility and atmospheric radiative heating at optical and near-infrared wavelengths and our desire to understand surface composition and atmospheric dynamics provides a strong motivation to study the properties of the haze. Prior to the Cassini/Huygens missions the haze was known to be global in extent, with a hemispheric contrast asymmetry, with a complicated structure in the polar vortex region poleward of about 55 deg latitude, and with a distinct layer near 370 km altitude outside of the polar vortex at the time of the Voyager 2 flyby. The haze particles measured by the Pioneer and Voyager spacecraft were both highly polarizing and strongly forward scattering, a combination that seems to require an aggregation of small (several tens of nm radius) primary particles. These same properties were seen in the Cassini orbiter and Huygens Probe data. The most extensive set of optical measurements were made inside the atmosphere by the Descent Imager/Spectral Radiometer (DISR) instrument on the Huygens Probe. At the probe location as determined by the DISR measurements the average haze particle contained about 3000 primary particles whose radius is about 40 nm. Three distinct vertical regions were seen in the DISR data with differing particle properties. Refractive indices of the particles in the main haze layer resemble those reported by Khare et al. between O.3S and about 0.7 micron but are more absorbing than the Khare et al. results between 0.7 micron and the long-wavelength limit of the DISR spectra at 1.6 micron. These and other results are described by Tomasko et al., and a broader summary of results was given by Tomasko and West,. New data continue to stream in from the Cassini spacecraft. New data analyses and new laboratory and model results continue to move the field forward. Titan's 'detached' haze layer suffered a dramatic drop in altitude near equinox in 2009 with implications for the circulation and seasonal change in the stratosphere. The book chapter associated with this talk will also present new material on thermal-infrared data analysis and on new developments in laboratory work and haze microphysical modeling

On the possibility of significant electron depletion due to nanograin charging in the coma of comet 67p/churyumov-gerasimenko near perihelion

We approach the complicated phenomena of gas-dust interactions in a cometary ionosphere, focusing in particular on the possibility of significant depletion in electron number density due to grain charging. Our one-dimensional ionospheric model, accounting for grain charging processes, is applied to the subsolar direction and the diamagnetic cavity of 67P/Churyuomov-Gerasimenko, the target comet for the ESA Rosetta mission, at perihelion (similar to 1.25-1.30 AU). We argue on the one hand that grains with radii &gt;100 nm are unlikely to significantly affect the overall ionospheric particle balance within this environment, at least for cometocentric distances &gt;10 km. On the other hand, if nanograins with radii in the 1-3 nm range are ejected to the coma at a level of similar to 1% with respect to the mass of the sublimated gas, a significant electron depletion is expected up to cometocentric distances of several tens of kilometers. We relate these results to the recent Cassini discoveries of very pronounced electron depletion compared with the positive ion population in the plume of Enceladus, which has been attributed to nanograin charging.</p

EVOLUTION OF THE STRATOSPHERIC TEMPERATURE AND CHEMICAL COMPOSITION OVER ONE TITANIAN YEAR

Since the Voyager 1 (V1) flyby in 1980, Titans exploration from space and the ground has been ongoing for more than a full revolution of Saturn around the Sun (one Titan year or 29.5 Earth years was completed in May 2010). In this study we search for temporal variations affecting Titans atmospheric thermal and chemical structure within that year. We process Cassini CIRS data taken during the Titan flybys from 2006-2013 and compare them to the 1980 V1IRIS spectra (re-analyzed here). We also consider data from Earth-based and -orbiting observatories (such as from the ISO, re-visited). When we compare the CIRS 2010 and the IRIS data we find limited inter-annual variations, below the 25 or35 levels for the lower and middle, or the high latitudes, respectively. A return to the 1980 stratospheric temperatures and abundances is generally achieved from 50degN to 50degS, indicative of the solar radiation being the dominating energy source at 10 AU, as for the Earth, as predicted by GCM and photochemical models. However, some exceptions exist among the most complex hydrocarbons (C4H2 and C3H4), especially in the North. In the Southern latitudes, since 2012, we see a trend for an increase of several trace gases, possibly indicative of a seasonal atmospheric reversal. At the Northern latitudes we found enhanced abundances around the period of the northern spring equinox in mid-2009 (as in Bampasidis et al. 2012), which subsequently decreased (from 2010-2012) returning to values similar to those found in the V1 epoch a Titanian year before