100 research outputs found
Assessing seasonality in the surface urban heat island of London
AbstractThis paper assesses the seasonality of the urban heat island (UHI) effect in the Greater London area (United Kingdom). Combining satellite-based observations and urban boundary layer climate modeling with the UrbClim model, the authors are able to address the seasonality of UHI intensity, on the basis of both land surface temperature (LST) and 2-m air temperature, for four individual times of the day (0130, 1030, 1330, and 2230 local time) and the daily means derived from them. An objective of this paper is to investigate whether the UHI intensities that are based on both quantities exhibit a similar hysteresis-like trajectory that is observed for LST when plotting the UHI intensity against the background temperature. The results show that the UrbClim model can satisfactorily reproduce both the observed urban–rural LSTs and 2-m air temperatures as well as their differences and the hysteresis in the surface UHI. The hysteresis-like seasonality is largely absent in both the observed and modeled 2-m air temperatures, however. A sensitivity simulation of the UHI intensity to incoming solar radiation suggests that the hysteresis of the LST can mainly be attributed to the seasonal variation in incoming solar radiation.</jats:p
Advantages of using a fast urban boundary layer model as compared to a full mesoscale model to simulate the urban heat island of Barcelona
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A new method to assess fine-scale outdoor thermal comfort for urban agglomerations
In urban areas, high air temperatures and heat stress levels greatly affect human thermal comfort and public health, with climate change further increasing the mortality risks. This study presents a high resolution (100 m) modelling method, including detailed offline radiation calculations, that is able to efficiently calculate outdoor heat stress for entire urban agglomerations for a time period spanning several months. A dedicated measurement campaign was set up to evaluate model performance, yielding satisfactory results. As an example, the modelling tool was used to assess the effectiveness of green areas and water surfaces to cool air temperatures and wet bulb globe temperatures during a typical hot day in the city of Ghent (Belgium), since the use of vegetation and water bodies are shown to be promising in mitigating the adverse effects of urban heat islands and improving thermal comfort. The results show that air temperature reduction is most profound over water surfaces during the afternoon, while open rural areas are coolest during the night. Radiation shading from trees, and to a lesser extent, from buildings, is found to be most effective in reducing wet bulb globe temperatures and improving thermal comfort during the warmest moments of the day
Unveiling the radiative local density of optical states of a plasmonic nanocavity by STM
Atomically-sharp tips in close proximity of metal surfaces create plasmonic nanocavities supporting both radiative (bright) and non-radiative (dark) localized surface plasmon modes. Disentangling their respective contributions to the total density of optical states remains a challenge. Electroluminescence due to tunnelling through the tip-substrate gap could allow the identification of the radiative component, but this information is inherently convoluted with that of the electronic structure of the system. In this work, we present a fully experimental procedure to eliminate the electronic-structure factors from the scanning tunnelling microscope luminescence spectra by confronting them with spectroscopic information extracted from elastic current measurements. Comparison against electromagnetic calculations demonstrates that this procedure allows the characterization of the meV shifts experienced by the nanocavity plasmonic modes under atomic-scale gap size changes. Therefore, the method gives access to the frequency-dependent radiative Purcell enhancement that a microscopic light emitter would undergo when placed at such nanocavityWe acknowledge financial support from the Spanish Ministry for Economy and Competitiveness (grants FIS2015-72482-EXP, FIS2015-64951-R, FIS2016-78591-C3-1-R, PGC2018-098613—B-C21, PGC2018-096047-B-I00, RTI2018-099737-B-I00 and MAT2014-53432-C5-5-R), the regional government of Comunidad de Madrid (grant S2018/NMT-4321), Universidad Autónoma de Madrid (UAM/48 and UAM/134) and IMDEA Nanoscience. Both IMDEA Nanoscience and IFIMAC acknowledge support from the Severo Ochoa and Maria de Maeztu Programmes for Centres and Units of Excellence in R&D (MINECO, Grants SEV-2016-0686 and MDM-2014-0377). We also acknowledge support by the QuantERA program of the European Union with funding by the Spanish AEI through project PCI2018-09314
Electronic temperature and two-electron processes in overbias plasmonic emission from tunnel junctions
The accurate determination of electronic temperatures in metallic
nanostructures is essential for many technological applications, like
plasmon-enhanced catalysis or lithographic nanofabrication procedures. In this
Letter we demonstrate that the electronic temperature can be accurately
measured by the shape of the tunnel electroluminescence emission edge in tunnel
plasmonic nanocavities, which follows a universal thermal distribution with the
bias voltage as the chemical potential of the photon population. A significant
deviation between electronic and lattice temperatures is found below 30 K for
tunnel currents larger than 15 nA. This deviation is rationalized as the result
of a two-electron process in which the second electron excites plasmon modes
with an energy distribution that reflects the higher temperature following the
first tunneling event. These results dispel a long-standing controversy on the
nature of overbias emission in tunnel junctions and adds a new method for the
determination of electronic temperatures and quasiparticle dynamics
Applications of Models and Tools for Mesoscale and Microscale Thermal Analysis in Mid-Latitude Climate Regions—A Review
Urban analysis at different spatial scales (micro- and mesoscale) of local climate conditions is required to test typical artificial urban boundaries and related climate hazards such as high temperatures in built environments. The multitude of finishing materials and sheltering objects within built environments produce distinct patterns of different climate conditions, particularly during the daytime. The combination of high temperatures and intense solar radiation strongly perturb the environment by increasing the thermal heat stress at the pedestrian level. Therefore, it is becoming common practice to use numerical models and tools that enable multiple design and planning alternatives to be quantitatively and qualitatively tested to inform urban planners and decision-makers. These models and tools can be used to compare the relationships between the micro-climatic environment, the subjective thermal assessment, and the social behaviour, which can reveal the attractiveness and effectiveness of new urban spaces and lead to more sustainable and liveable public spaces. This review article presents the applications of selected environmental numerical models and tools to predict human thermal stress at the mesoscale (e.g., satellite thermal images and UrbClim) and the microscale (e.g., mobile measurements, ENVI-met, and UrbClim HR) focusing on case study cities in mid-latitude climate regions framed in two European research projects.The work leading to these results has received funding from the European Community’s Seventh Framework Programme under Grant Agreement No. 308497, Project RAMSES—Reconciling Adaptation, Mitigation, and Sustainable Development for Cities (2012–2017)
and from the European Union’s H2020 Research and Innovation Programme under Grant Agreement No. 73004
(PUCS/Climate-fit.city).
The APC was funded by the Research Group of Building and Technology, De partment of Civil and Environmental Engineering, Norwegian University of Science and Technolog
Influence of climate change on summer cooling costs and heat stress in urban office buildings
Indoor climatic conditions are strongly influenced by outdoor meteorological conditions. It is thus expected that the combined effect of climate change and the urban heat island effect negatively influences working conditions in urban office buildings. Since office buildings are particularly vulnerable to overheating because of the profound internal heat gains, this is all the more relevant. The overheating in office buildings leads to elevated cooling costs or, because additional work breaks are required by legislation in some countries, productivity losses. We have developed a methodology incorporating urban climate modelling and building energy simulations to assess cooling costs and lost working hours in office buildings, both for current-day and future climate, extending towards the end of the twenty-first century. The methodology is tailored to additionally assess the impact and benefits of adaptation measures, and it is designed to be transferable from one city to another. Results for a prototype building located in three different European cities (Antwerp, Bilbao and London) illustrate the challenge in keeping Western-European office buildings comfortable until the end of the twenty-first century without adaptation measures, and the beneficial effect of adequate adjustments. The results further illustrate the large decreases in cooling costs (up to 30%) caused by the introduction of (external) shading and increased night-time ventilation in actively cooled buildings, and the improvements in working conditions in free-running buildings caused by moving workers to cooler locations and splitting workdays in morning and evening shifts
Heat and health in Antwerp under climate change: Projected impacts and implications for prevention
<p><b>BACKGROUND: </b>Excessive summer heat is a serious environmental health problem in several European cities. Heat-related mortality and morbidity is likely to increase under climate change scenarios without adequate prevention based on locally relevant evidence.</p>
<p><b>METHODS: </b>We modelled the urban climate of Antwerp for the summer season during the period 1986-2015, and projected summer daily temperatures for two periods, one in the near (2026-2045) and one in the far future (2081-2100), under the Representative Concentration Pathway (RCP) 8.5. We then analysed the relationship between temperature and mortality, as well as with hospital admissions for the period 2009-2013, and estimated the projected mortality in the near future and far future periods under changing climate and population, assuming alternatively no acclimatization and acclimatization based on a constant threshold percentile temperature.</p>
<p><b>RESULTS: </b>During the sample period 2009-2013 we observed an increase in daily mortality from a maximum daily temperature of 26°C, or the 89th percentile of the maximum daily temperature series. The annual average heat-related mortality in this period was 13.4 persons (95% CI: 3.8-23.4). No effect of heat was observed in the case of hospital admissions due to cardiorespiratory causes. Under a no acclimatization scenario, annual average heat-related mortality is multiplied by a factor of 1.7 in the near future (24.1deaths/year CI 95%: 6.78-41.94) and by a factor of 4.5 in the far future (60.38deaths/year CI 95%: 17.00-105.11). Under a heat acclimatization scenario, mortality does not increase significantly in the near or in the far future.</p>
<p><b>CONCLUSION: </b>These results highlight the importance of a long-term perspective in the public health prevention of heat exposure, particularly in the context of a changing climate, and the calibration of existing prevention activities in light of locally relevant evidence.</p></p
Nanotube-like electronic states in [5,5]-C90 fullertube molecules
Fullertubes, that is, fullerenes consisting of a carbon nanotube moiety capped by hemifullerene ends, are emerging carbon nanomaterials whose properties show both fullerene and carbon nanotube (CNT) traits. Albeit it may be expected that their electronic states show a certain resemblance to those of the extended nanotube, such a correlation has not yet been found or described. Here it shows a scanning tunneling microscopy (STM) and spectroscopy (STS) characterization of the adsorption, self-assembly, and electronic structure of 2D arrays of [5,5]-C90 fullertube molecules on two different noble metal surfaces, Ag(111) and Au(111). The results demonstrate that the shape of the molecular orbitals of the adsorbed fullertubes corresponds closely to those expected for isolated species on the grounds of density functional theory calculations. Moreover, a comparison between the electronic density profiles in the bands of the extended [5,5]-CNT and in the molecules reveals that some of the frontier orbitals of the fullertube molecules can be described as the result of the quantum confinement imposed by the hemifullerene caps to the delocalized band states in the extended CNT. The results thus provide a conceptual framework for the rational design of custom fullertube molecules and can potentially become a cornerstone in the understanding of these new carbon nanoformsPID2020-113142RB-C21, PLEC2021-007906, PID2021-128011NB-I00, PID2020-114653RB-I00, S2018/NMT-4321, S2018/NMT-4367, Y2020/NMT6469, CEX2020-001039-S, CEX2018-000805-
Experimental Station for Generation, Processing and Diagnostics of Nanoparticles of Astrophysical Interest
Europhysics Sectional Conference on the Atomic and Molecular Physics of Ionized Gases. ESCAMPIG XXIV.Glasgow July 17-21 (2018). .--file:///C:/Users/BIBLIO~1/AppData/Local/Temp/CONGRESOS_Y_CONFERENCIAS752874-1.pd
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