Combined Approach of Mechanochemistry and Electron Crystallography for the Discovery of 1D and 2D Coordination Polymers

Mechanochemical synthesis is an attractive preparative method that combines a green approach with versatility, efficiency, and rapidity of reaction. However, it often yields microcrystalline materials, and their small crystal size is a major hindrance to structure elucidation with conventional single-crystal or powder X-ray diffraction methods. This work presents the novel approach of combining mechanochemistry with electron diffraction techniques to elucidate the crystal structure of metal−organic compounds of zinc(II) and copper(II) with 2,6-pyridinedicarboxylic acid and 4,4′-bipyridine

Extended “orbital molecules” and magnetic phase separation in Bi0.68Ca0.32MnO3

The low-temperature structure of Bi0.68Ca0.32MnO3 has been solved from electron and neutron diffraction data. The quantitative simultaneous refinement indicates an ordering of the Mn cations in a “stripe/chess”-like pattern. The ordering is accompanied by the formation of short Mn—Mn distances and the rearrangement of the Mn—O bonds indicating the development of complex extended “orbital molecules.” The primary order parameter breaks inversion symmetry and allows the generation of a spontaneous electrical polarization as the secondary order parameter. The neutron data at low temperature indicate the coexistence of a pseudo-CE long-range-ordered structure with a strongly reduced moment and short-range ferromagnetic correlations. These results indicate an intricate competition between the charge, orbital, and magnetic degrees of freedom and the Bi3+ stereoactivity in this manganite system

Pressure dependence of magnetism and martensitic properties in Co-doped NiMnGa alloys

NiMnGa alloys display several "giant" effects due to the interplay between magnetic and structural degrees of freedom. A large magnetization difference, between martensitic phases and austenitic phases iso f great importance to obtain higher performances due to the improbe possibilit? of driving structural trasformations by magnetic fields. A deltaM enhancement was recently achieved by adding Co to Mn-rich NiMnGa alloy

Suitability of Porous Inorganic Materials from Industrial Residues and Bioproducts for Use in Horticulture: A Multidisciplinary Approach

This study follows a circular economy approach through the preliminary implementation of a coated porous inorganic material (PIM), studied as sustainable controlled release fertilizer, and its application for lettuce Lactuca sativa L. cultivar Chiara growth. The PIM was made of pumice scraps that partially replaced clay as a natural raw material, spent coffee grounds as a porous agent, bovine bone ash and potassium carbonate to provide phosphorus (P) and potassium (K) nutrients, respectively. A coating made with defatted black soldier fly prepupae biomass was used as a nitrogen (N) source. Most of the ingredients used were industrial residues, with the aim of valorizing the raw waste materials present locally. The suitability of PIMs as a fertilizer was investigated with an interdisciplinary approach, which included the first chemical and physical characterization of the material, the evaluation of its antibacterial properties and of its use in horticulture through lettuce growth tests. As tests were carried out indoors, a specific LED lighting device was used to grow the lettuce. The release of nutrients into the soil was estimated by measuring the main elements in the fertilizers before and after their use in the soil. The first results from this characterization study support PIMs’ suitability for agronomic applications. The use of the PIMs suggested average higher dry weight (49%), fresh weight (112%), and leaf area (48%), compared to those with the use of a standard fertilizer soil, without the release of any dangerous element for the plant in the soil. These results are a promising beginning for the development of further studies already in progress on sustainable controlled-release fertilizers

Do regional aerosols contribute to the riverine export of dissolved black carbon?

The fate of black carbon (BC), a stable form of thermally altered organic carbon produced during biomass and fuel combustion, remains an area of uncertainty in the global carbon cycle. The transfer of photosynthetically derived BC into extremely long‐term oceanic storage is of particular significance and rivers are the key linkage between terrestrial sources and oceanic stores. Significant fluvial fluxes of dissolved BC to oceans result from the slow release of BC from degrading charcoal stocks; however, these fluvial fluxes may also include undetermined contributions of aerosol BC, produced by biomass and fossil fuel combustion, which are deposited in river catchments following atmospheric transport. By investigation of the Paraíba do Sul River catchment in Southeast Brazil we show that aerosol deposits can be substantial contributors to fluvial fluxes of BC. We derived spatial distributions of BC stocks within the catchment associated with soil charcoal and with aerosol from both open biomass burning and fuel combustion. We then modeled the fluvial concentrations of dissolved BC (DBC) in scenarios with varying rates of export from each stock. We analyzed the ability of each scenario to reproduce the variability in DBC concentrations measured in four data sets of river water samples collected between 2010 and 2014 and found that the best performing scenarios included a 5–18% (135–486 Mg DBC year−1) aerosol contribution. Our results suggest that aerosol deposits of BC in river catchments have a shorter residence time in catchments than charcoal BC and, therefore, contribute disproportionately (with respect to stock magnitude) toward fluvial fluxes of BC

Observation of the Gamma-Ray Binary HESS J0632+057 with the H.E.S.S., MAGIC, and VERITAS Telescopes

The results of gamma-ray observations of the binary system HESS J0632 + 057 collected during 450 hr over 15 yr, between 2004 and 2019, are presented. Data taken with the atmospheric Cherenkov telescopes H.E.S.S., MAGIC, and VERITAS at energies above 350 GeV were used together with observations at X-ray energies obtained with Swift-XRT, Chandra, XMM-Newton, NuSTAR, and Suzaku. Some of these observations were accompanied by measurements of the Hα emission line. A significant detection of the modulation of the very high-energy gamma-ray fluxes with a period of 316.7 4.4 days is reported, consistent with the period of 317.3 0.7 days obtained with a refined analysis of X-ray data. The analysis of data from four orbital cycles with dense observational coverage reveals short-timescale variability, with flux-decay timescales of less than 20 days at very high energies. Flux variations observed over a timescale of several years indicate orbit-to-orbit variability. The analysis confirms the previously reported correlation of X-ray and gamma-ray emission from the system at very high significance, but cannot find any correlation of optical Hα parameters with fluxes at X-ray or gamma-ray energies in simultaneous observations. The key finding is that the emission of HESS J0632 + 057 in the X-ray and gamma-ray energy bands is highly variable on different timescales. The ratio of gamma-ray to X-ray flux shows the equality or even dominance of the gamma-ray energy range. This wealth of new data is interpreted taking into account the insufficient knowledge of the ephemeris of the system, and discussed in the context of results reported on other gamma-ray binary systems

MAGIC and H.E.S.S. detect VHE gamma rays from the blazar OT081 for the first time: a deep multiwavelength study

https://pos.sissa.it/395/815/pdfPublished versio

MAGIC and Fermi-LAT gamma-ray results on unassociated HAWC sources

The HAWC Collaboration released the 2HWC catalogue of TeV sources, in which 19 show no association with any known high-energy (HE; E greater than or similar to 10 GeV) or very-high-energy (VHE; E greater than or similar to 300 GeV) sources. This catalogue motivated follow-up studies by both the Major Atmospheric Gamma-ray Imaging Cherenkov (MAGIC) and Fermi-LAT (Large Area Telescope) observatories with the aim of investigating gamma-ray emission over a broad energy band. In this paper, we report the results from the first joint work between High Altitude Water Cherenkov (HAWC), MAGIC, and Fermi-LAT on three unassociated HAWC sources: 2HWC J2006+341, 2HWC J1907+084*, and 2HWC J1852+013*. Although no significant detection was found in the HE and VHE regimes, this investigation shows that a minimum 1 degrees extension (at 95 per cent confidence level) and harder spectrum in the GeV than the one extrapolated from HAWC results are required in the case of 2HWC J1852+013*, whilst a simply minimum extension of 0.16 degrees (at 95 per cent confidence level) can already explain the scenario proposed by HAWC for the remaining sources. Moreover, the hypothesis that these sources are pulsar wind nebulae is also investigated in detail