Characterization of Direct-Push Vadose Zone Sediments from the 241-B and 241-BX Tank Farms

Geochemical tests provide evidence for the transit of a plume of caustic waste solution through the sediment column at the Hanford 241-B and -BX Tank Farms. Direct-push samples recovered from boreholes surrounding Tanks 241-B-110 and 241-BX-102 and related waste transfer lines and diversion boxes included sediments typical of those previously recovered from other localities on the Hanford Site. The Hanford formation sediments are dominantly quartzo-feldspathic sands strewn with lithic fragments, displaying a range of particle size distributions and sorting characteristics. Some moderately well-sorted, fine-grained lithologies are interpreted as lenticular bodies irregularly dispersed in coarser-grained, more poorly sorted sediments. Tier I tests conducted on the vadose zone sediments revealed an inverse correlation between moisture content and sediment size fraction (i.e., there is greater moisture content in finer-grained sediments). The Tier I tests also showed that the pore water solutions were likely sodium-rich, moderately saline, and possessed higher pH values than background (untainted) sediments. These data are characteristic of sediments that have encountered sodium-rich, saline, caustic waste solution, as documented in other reports at other suspect contamination sites around Hanford. Analyses of solutions from 1:1 water extracts reveal relatively balanced cation and anion concentrations, indicating that most of the geochemical species have been accounted for. The water extract data for affected sediments also indicate unusually high concentrations of aluminum, iron, and phosphorus. The relatively high concentrations of aluminum and iron may be the result of dissolution of secondary amorphous phases that precipitated after a reactive plume partially dissolved aluminum- and iron-bearing phases as it migrated through the sediment column. On the other hand, the presence of elevated concentrations of phosphorous may be the tell-tale signature of wastes derived from the bismuth phosphate separation process. Elements typically mobile in the geosphere, such as technetium-99, are present at either low concentrations or are below the analytical detection limit. However, we expect that the mobile elements would be present mainly along a narrow plume front, and if this front had passed deeper into the sediment profile than depths sampled, the retention of these elements would be minor. On the other hand for the direct push sediments from around BX Tank Farm, uranium-238 was detected in nearly all sediment specimens (by acid extract experiments) at concentrations above the natural crustal average (0.763 pCi/g), and we also detected the presence of several anthropogenic radioisotopes, such as cobalt-60, cesium-137, europium-154, and europium-155 (by gamma energy analysis). These data are direct confirmation of contamination of the sediments

Influence of diurnal variation in mesophyll conductance on modelled 13C discrimination: results from a field study

Mesophyll conductance to CO2 (gm) limits carbon assimilation and influences carbon isotope discrimination (Δ) under most environmental conditions. Current work is elucidating the environmental regulation of gm, but the influence of gm on model predictions of Δ remains poorly understood. In this study, field measurements of Δ and gm were obtained using a tunable diode laser spectroscope coupled to portable photosynthesis systems. These data were used to test the importance of gm in predicting Δ using the comprehensive Farquhar model of Δ (Δcomp), where gm was parameterized using three methods based on: (i) mean gm; (ii) the relationship between stomatal conductance (gs) and gm; and (iii) the relationship between time of day (TOD) and gm. Incorporating mean gm, gs-based gm, and TOD-based gm did not consistently improve Δcomp predictions of field-grown juniper compared with the simple model of Δ (Δsimple) that omits fractionation factors associated with gm and decarboxylation. Sensitivity tests suggest that b, the fractionation due to carboxylation, was lower (25‰) than the value commonly used in Δcomp (29‰) and Δsimple (27‰). These results demonstrate the limits of all tested models in predicting observed juniper Δ, largely due to unexplained offsets between predicted and observed values that were not reconciled in sensitivity tests of variability in gm, b, or e, the day respiratory fractionation

Terrestrial very-long-baseline atom interferometry: Workshop summary

This document presents a summary of the 2023 Terrestrial Very-Long-Baseline Atom Interferometry Workshop hosted by CERN. The workshop brought together experts from around the world to discuss the exciting developments in large-scale atom interferometer (AI) prototypes and their potential for detecting ultralight dark matter and gravitational waves. The primary objective of the workshop was to lay the groundwork for an international TVLBAI proto-collaboration. This collaboration aims to unite researchers from different institutions to strategize and secure funding for terrestrial large-scale AI projects. The ultimate goal is to create a roadmap detailing the design and technology choices for one or more kilometer--scale detectors, which will be operational in the mid-2030s. The key sections of this report present the physics case and technical challenges, together with a comprehensive overview of the discussions at the workshop together with the main conclusions.</jats:p