162 research outputs found

    The Rosenberg Self-Esteem Scale: Translation and Validation in University Students

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    El propósito de esta investigación ha sido traducir al español y analizar las propiedades psicométricas de la escala de autoestima de Rosenberg (RSES) en una muestra de estudiantes universitarios. El análisis factorial confirmatorio confirmó que el modelo que mejor se ajusta a los datos tanto en la muestra total como en las submuestras de hombres y mujeres tiene una estructura unifactorial con efectos de método en los ítems formulados en positivo. Los resultados indican correlaciones positivas y fuertes entre la autoestima y cinco dimensiones del autoconcepto. Además, la escala ha mostrado niveles satisfactorios de consistencia interna y estabilidad temporal tras un periodo de cuatro semanas. Finalmente, se han obtenido diferencias de género significativas. Estos resultados apoyan el uso de la RSES para evaluar la autoestima en el contexto educativo universitario.The aim of this study was to translate into Spanish and to validate the Rosenberg Self-Esteem Scale (RSES), completed by 420 university students. Confirmatory factor analysis revealed that the model that best fit the data, both in the total sample and in the male and female subsamples, was the one-factor structure with method effects associated with positively worded items. The results indicated high, positive correlations between self-esteem and the five dimensions of selfconcept. The scale showed satisfactory levels of internal consistency and temporal stability over a four-week period. Lastly, gender differences were obtained. These findings support the use of the RSES for the assessment of self-esteem in higher education

    Electronic properties of Naphthalimide derivatives

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    Molecular systems have proven to be efficient active materials in electronics, making then suitable substitutes of the inorganic semiconductors used nowadays in electronic devices. For this reason, organic electronics has emerged as a research field with great potential and interest. In this project we have studied, both experimentally and theoretically, two ladder-type compounds functionalized with naphthalimides (Figure 1). The two molecular systems have been implemented in organic field effect transistors (OFETs), to assess their potential as active materials in organic electronics. Both compounds show p-type type mobility, moreover, NDI-TP-Ph-TP material also displays low n-type mobility, presenting a certain ambipolar character. The nature and stability of the charged species involved in the charge transport process have also been studied by spectroelectrochemical experiments.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

    Electronic Properties of Naphthalimide-based Ladder-type Systems

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    The tuneable electronic and structural properties of organic semiconductors together with their flexibility, light weight, high solution processing and low costs in comparison with inorganic semiconductors are some of the key points for the current interest in the development of π-conjugated small molecules and polymers for a variety of applications. In this project, a combined experimental and theoretical study of two ladder-type compounds functionalized with naphthalimides1 (Figure 1) is performed with the aim to explore the impact of the structure on the optical and charge-transport properties. Compound NDI-TP-Ph-TP has an imidazole group as a spacer ring and NIP-TP-Ph-TP has a spacer ring of pyrazine type. The two molecular systems have been implemented in organic field effect transistors2 (OFETs), to assess their potential as active materials in organic electronics. Both compounds show p-type mobility, moreover, NDI-TP-Ph-TP material also displays low n-type mobility, presenting a certain ambipolar character.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

    Strong enhancement of superconductivity at high pressures within the charge-density-wave states of 2H-TaS 2 and 2H-TaSe 2

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    We present measurements of the superconducting and charge density wave critical temperatures (Tc and TCDW) as a function of pressure in the transition metal dichalchogenides 2H-TaSe2 and 2H-TaS2. Resistance and susceptibility measurements show that Tc increases from temperatures below 1 K up to 8.5 K at 9.5 GPa in 2H-TaS2 and 8.2 K at 23 GPa in 2H-TaSe2. We observe a kink in the pressure dependence of TCDW at about 4 GPa that we attribute to the lock-in transition from incommensurate CDW to commensurate CDW. Above this pressure, the commensurate TCDW slowly decreases coexisting with superconductivity within our full pressure range.Comment: Published in Phys. Rev B 93, 184512 (2016

    Tunable electroactive oligothiophene-naphthalimide semiconductors via end-capped engineering: cumulative effects beyond the linker

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    Aiming to obtain novel functional semiconducting materials for their use in organic electronics, the combination of strong donor moieties with electron-withdrawing units is one of the most useful strategies to obtain ambipolar semiconductors with tunable properties. Nowadays most of the efforts headed to efficient materials are based on small changes in the alkyl pendant chains or by replacing single atoms. However, a precise design of new functional materials is still challenging. For this reason, in this work we present a new synthetic approach for achieving redox amphoteric organic semiconductors by tuning their opto-electrochemical properties via rational chemical modifications. All these materials present low-lying LUMO levels, lower than −4.00 eV with broad absorption up to 800 nm in the UV-Vis-NIR spectra. In addition, they have been characterized by DFT, absorption and Raman vibrational spectroscopies, while their charge stabilization abilities are studied by means of spectroelectrochemical techniques. The results point out to a quite complex electronic scenario that goes beyond the expected cumulative effects of the independent molecular units constituting the final molecular assembly.Funding for open access charge: Universidad de Málaga / CBU

    Colapso gravitacional radiativo esféricamente simétrico en relatividad general: introducción del factor de flujo, el factor de Eddington y la influencia de la relación de clausura entre ellos sobre la evolución del sistema

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    The H–J–Rs’ method [Phys. Rev. D22, 2305 (1980)] is extended to include the Eddington’s variable factor, the radiation flux factor and a closure relationship between them in order to show its influence on the behavior of density, pressure, fluid velocity and energy radiation flux, among others, of an object under gravitational collapse within the framework of general relativity. The post-quasistatic approximation of Herrera et al [Phys. Rev. D65, 104004 (2002)] along with the Tolman VI equation of state and the Lorentz–Eddington, Bowers–Wilson and Maximum Packing relationships were used to find that the choice of different closure relationships does not affect the global behavior of the system but only the instantaneous values of the different physical quantities.  Se extiende el método H–J–R [Phys. Rev. D22, 2305 (1980)] utilizando el factor variable de Eddington y el factor de flujo de radiación, y se presenta la influencia de la elección de la relación entre ellos sobre el comportamiento en el tiempo de la densidad, presión, velocidad del fluido y flujo de radiación, entre otras, de un objeto en fase de colapso gravitacional radiativo en el marco de la relatividad general. Para tal fin, se ha utilizado la aproximación poscuasiestática de Herrera et al [Phys. Rev. D65, 104004 (2002)] con la ecuación de estado Tolman VI y las relaciones de clausura de Lorentz–Eddington, Bowers–Wilson y Maximum Packing, encontrando que la elección de una relación de clausura particular no afecta el comportamiento General del colapso, pero sí afecta los valores instantáneos de las diferentes magnitudes físicas.         &nbsp

    Bimodal Expansion of the Lymphatic Vessels Is Regulated by the Sequential Expression of IL-7 and Lymphotoxin α1β2 in Newly Formed Tertiary Lymphoid Structures.

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    Lymphangiogenesis associated with tertiary lymphoid structure (TLS) has been reported in numerous studies. However, the kinetics and dynamic changes occurring to the lymphatic vascular network during TLS development have not been studied. Using a viral-induced, resolving model of TLS formation in the salivary glands of adult mice we demonstrate that the expansion of the lymphatic vascular network is tightly regulated. Lymphatic vessel expansion occurs in two distinct phases. The first wave of expansion is dependent on IL-7. The second phase, responsible for leukocyte exit from the glands, is regulated by lymphotoxin (LT)βR signaling. These findings, while highlighting the tight regulation of the lymphatic response to inflammation, suggest that targeting the LTα1β2/LTβR pathway in TLS-associated pathologies might impair a natural proresolving mechanism for lymphocyte exit from the tissues and account for the failure of therapeutic strategies that target these molecules in diseases such as rheumatoid arthritis
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