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京都大学0048新制・課程博士博士(工学)甲第13089号工博第2831号新制||工||1411(附属図書館)UT51-2007-H362京都大学大学院工学研究科化学工学専攻(主査)教授 田門 肇, 教授 三浦 孝一, 教授 宮原 稔学位規則第4条第1項該当Doctor of EngineeringKyoto UniversityDA

Effects of Nanocrystal Cellulose from Bamboo on the Flexural Strength of Acrylic Resin: In Vitro

The purpose of this study is to evaluate the effects of nanocrystal cellulose (NCC) from bamboo on the flexural strength of heat-cured acrylic resin. A total of 35 specimens (3.3 mm × 10 mm × 64 mm) were prepared and the specimens were divided into five groups of seven specimens each. Group 1 used conventional acrylic resin that was prepared based on the instructions of the manufacturer (0%). The filled NCC from bamboo fiber in four concentrations (0.25, 0.5, 1, and 2% w/w) was used in the four-reinforcing resin workpiece groups. The specimens were loaded until failure occurred on a three-point bending test machine. One-way analysis of variance and Dunnett’s multiple comparison test at a 95% confidence level were used to determine the statistical differences in the flexural strength among the five groups. The results found that the average flexural strength of five specimen groups (0, 0.25, 0.5, 1, and 2% w/w) were 60.11 ± 2.4, 60.75 ± 2.18, 66.50 ± 5.08, 56.04 ± 0.31, and 48.05 ± 2.61 MPa, respectively. The flexural strength of 0.5 mg% w/w NCC-reinforced acrylic resin was significantly higher than the control group (p < 0.01). The reinforced NCC from bamboo fiber to acrylic resin improved the flexural strength properties

Influence of Evaporation Drying on the Porous Properties of Carbon/Carbon Composite Xerogels

Carbon/carbon (C/C) composite xerogels dried by evaporation were prepared in this study to observe the change of their porous properties and their morphology by nitrogen sorption apparatus and a scanning electron microscope. Resorcinol and formaldehyde (RF) sols as a matrix phase and cotton fibers (CF) as a dispersed phase were mixed and gelated to be CF/RF composite hydrogels. The composite hydrogels were exchanged by t-butanol (TBA), dried by evaporation at 50 °C, and carbonized at 1000 °C to become the C/C composite xerogels. The results show that the CF addition does not decrease the mesoporous properties of the C/C composite xerogels. Moreover, the CF addition can alleviate the pore shrinkage, and it can maintain the mesopore structure. The mesopore size and the micropore size of C/C composites are insignificantly changed because the CF addition and the solvent exchange using TBA may suppress the pore shrinkage despite the gas-liquid interface existing during the evaporation drying