Novel Regime of Operation for Superconducting Quantum Interference Filters

A new operating regime of the Superconducting Quantum Interference Filter (SQIF) is investigated. The voltage to magnetic field response function, V(H), is determined by a Fraunhofer dependence of the critical current and magnetic flux focusing effect in Josephson junctions (F-mode). For SQIF-arrays made of high-Tc superconducting bicrystal Josephson junctions the F-mode plays a predominant role in the voltage-field response V(H). The relatively large superconducting loops of the SQIF are used for inductive coupling to the external input circuit. It is shown that the output noise of a SQIF-array measured with a cooled amplifier in the 1-2 GHz range is determined by the slope of the V(H) characteristic. Power gain and saturation power were evaluated using low frequency SQIF parameters. Finally, we consider the influence of the spread in the parameters of Josephson junctions in the SQIF-array on the V(H) characteristic of the whole structure.Comment: 7 pages, 4 figure

Application of quantum-chemical modeling results in experimental investigations of silicone composites

© 2017, Peter the Great St. Petersburg Polytechnic University. The results of direct numerical simulation obtained earlier, within the cluster quantum-chemical approximation, are used in experimental investigations of polydimethylsiloxane composites with shungit. The surface structure of these composites by scanning electron and atomic force microscopy was studied. Correlation of the distribution of micro and nano - dimensional filler in the polymer matrix with the physical mechanical properties of the elastomers was established

A combined theoretical and experimental study of the low temperature properties of BaZrO3

Low temperature properties of BaZrO3 are revealed by combining experimental techniques (X-ray diffraction, neutron scattering and dielectric measurements) with theoretical first-principles-based methods (total energy and linear response calculations within density functional theory, and effective Hamiltonian approaches incorporating/neglecting zero-point phonon vibrations). Unlike most of the perovskite systems, BaZrO3 does not undergo any (long-range-order) structural phase transition and thus remains cubic and paraelectric down to 2 K, even when neglecting zero-point phonon vibrations. On the other hand, these latter pure quantum effects lead to a negligible thermal dependency of the cubic lattice parameter below ~ 40 K. They also affect the dielectricity of BaZrO3 by inducing an overall saturation of the real part of the dielectric response, for temperatures below ~ 40 K. Two fine structures in the real part, as well as in the imaginary part, of dielectric response are further observed around 50-65 K and 15 K, respectively. Microscopic origins (e.g., unavoidable defects and oxygen octahedra rotation occurring at a local scale) of such anomalies are suggested. Finally, possible reasons for the facts that some of these dielectric anomalies have not been previously reported in the better studied KTaO3 and SrTiO3 incipient ferroelectrics are also discussed.Comment: 8 pages, 5 figures, submitted to Physical Review

Frequency and size dependence of ac Josephson effect in Nb/Au/YBCO heterojunctions

Abstract. High frequency dynamics of Nb/Au/YBaCuO heterojunctions on tilted NdGaO 3 substrates have been studied. The both integer and non-integer Shapiro steps have been observed at mm-wave frequencies. Unconventional dependence of the critical current and the amplitudes of Shapiro steps vs. applied microwave power have been registered. Observed behavior deviates from existing theories of Josephson effect for junctions made from conventional or d-wave superconductors. Although the maximal size of the heterojunctions was smaller than the Josephson penetration depth, calculated from an averaged value of the critical current density, the experimental magnetic field dependences I C (H) deviate from the Fraunhofer pattern, pointing on non-uniform distribution of superconducting current density. Experimental results could be speculatively explained by origination of self-induced fractional magnetic vortices, which may take place in a junction where the amplitude and the phase of superconducting current alternate significantly over the junction area. Introducing a new lengthscale, which is much smaller than the Josephson penetration depth, the fractional vortices are considered, modifying the high frequency dynamics, namely the ac Josephson effect. Experimental results have been analyzed taking into account the second harmonic of superconducting current-phase relation and the influence of heterojunction capacitance. Introduction It is known that in metal-oxide superconductors with high critical temperature, for example in YBCO, the d-wave symmetry of superconducting order parameter (D-superconductor) is predominant one in the basal (a-b) plan

Magnetoelectric ordering of BiFeO3 from the perspective of crystal chemistry

In this paper we examine the role of crystal chemistry factors in creating conditions for formation of magnetoelectric ordering in BiFeO3. It is generally accepted that the main reason of the ferroelectric distortion in BiFeO3 is concerned with a stereochemical activity of the Bi lone pair. However, the lone pair is stereochemically active in the paraelectric orthorhombic beta-phase as well. We demonstrate that a crucial role in emerging of phase transitions of the metal-insulator, paraelectric-ferroelectric and magnetic disorder-order types belongs to the change of the degree of the lone pair stereochemical activity - its consecutive increase with the temperature decrease. Using the structural data, we calculated the sign and strength of magnetic couplings in BiFeO3 in the range from 945 C down to 25 C and found the couplings, which undergo the antiferromagnetic-ferromagnetic transition with the temperature decrease and give rise to the antiferromagnetic ordering and its delay in regard to temperature, as compared to the ferroelectric ordering. We discuss the reasons of emerging of the spatially modulated spin structure and its suppression by doping with La3+.Comment: 18 pages, 5 figures, 3 table

Enhanced electric conductivity at ferroelectric vortex cores in BiFeO3

In many large ensembles, the property of the system as a whole cannot be understood from studying the individual entities alone ¿ these ensembles can be made up by neurons in the brain, transport users in traffic networks or data packages in the Internet. The past decade has seen important progress in our fundamental understanding of what such seemingly disparate 'complex systems' have in common; some of these advances are surveyed here

Исследование эластичного наполнителя, получаемого методом высокотемепреатурного сдвигового измельчения

Possibility of using elastic filler which received of the waste of tyres by conditions of high temperatures and deformation is investigated in rubber technology. The presented part of work has been directed on studying of morphological properties elastic filler, abilities to participation in vulcanization process elastomer material, comparison given kind of filler with the products of recycling of the worn out tyres presented in the modern market.В работе рассмотрены вопросы, связанные с изучением основных физико-химических и технических свойств продукта вторичной переработки резины, получаемого методом высокотемпературного сдвигового измельчения (ВСИ), на основе отработанных шин и резинотехнических изделий

The regulatory subunit of PKA-I remains partially structured and undergoes β-aggregation upon thermal denaturation

Background: The regulatory subunit (R) of cAMP-dependent protein kinase (PKA) is a modular flexible protein that responds with large conformational changes to the binding of the effector cAMP. Considering its highly dynamic nature, the protein is rather stable. We studied the thermal denaturation of full-length RIα and a truncated RIα(92-381) that contains the tandem cyclic nucleotide binding (CNB) domains A and B. Methodology/Principal Findings: As revealed by circular dichroism (CD) and differential scanning calorimetry, both RIα proteins contain significant residual structure in the heat-denatured state. As evidenced by CD, the predominantly α-helical spectrum at 25°C with double negative peaks at 209 and 222 nm changes to a spectrum with a single negative peak at 212-216 nm, characteristic of β-structure. A similar α→β transition occurs at higher temperature in the presence of cAMP. Thioflavin T fluorescence and atomic force microscopy studies support the notion that the structural transition is associated with cross-β-intermolecular aggregation and formation of non-fibrillar oligomers. Conclusions/Significance: Thermal denaturation of RIα leads to partial loss of native packing with exposure of aggregation-prone motifs, such as the B' helices in the phosphate-binding cassettes of both CNB domains. The topology of the β-sandwiches in these domains favors inter-molecular β-aggregation, which is suppressed in the ligand-bound states of RIα under physiological conditions. Moreover, our results reveal that the CNB domains persist as structural cores through heat-denaturation. © 2011 Dao et al

Identification and Characterization of Novel Mutations in the Human Gene Encoding the Catalytic Subunit Calpha of Protein Kinase A (PKA)

The genes PRKACA and PRKACB encode the principal catalytic (C) subunits of protein kinase A (PKA) Cα and Cβ, respectively. Cα is expressed in all eukaryotic tissues examined and studies of Cα knockout mice demonstrate a crucial role for Cα in normal physiology. We have sequenced exon 2 through 10 of PRKACA from the genome of 498 Norwegian donors and extracted information about PRKACA mutations from public databases. We identified four interesting nonsynonymous point mutations, Arg45Gln, Ser109Pro, Gly186Val, and Ser263Cys, in the Cα1 splice variant of the kinase. Cα variants harboring the different amino acid mutations were analyzed for kinase activity and regulatory (R) subunit binding. Whereas mutation of residues 45 and 263 did not alter catalytic activity or R subunit binding, mutation of Ser109 significantly reduced kinase activity while R subunit binding was unaltered. Mutation of Cα Gly186 completely abrogated kinase activity and PKA type I but not type II holoenzyme formation. Gly186 is located in the highly conserved DFG motif of Cα and mutation of this residue to Val was predicted to result in loss of binding of ATP and Mg2+, which may explain the kinetic inactivity. We hypothesize that individuals born with mutations of Ser109 or Gly186 may be faced with abnormal development and possibly severe disease