550 research outputs found

    THE TEMPERATURE COEFFICIENTS OF SOME PHOTOCHEMICAL REACTIONS

    Full text link

    Vera Kistiakowsky edited transcript, 1976 April–September

    Get PDF
    For more information about this item, visit https://archivesspace.mit.edu/repositories/2/archival_objects/29822

    Discovery of Tantalum, Rhenium, Osmium, and Iridium Isotopes

    Full text link
    Currently, thirty-eight tantalum, thirty-eight rhenium, thirty-nine osmium, and thirty-eight iridium, isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.Comment: To be published in At. Data Nucl. Data Table

    Backward pion-nucleon scattering

    Get PDF
    A global analysis of the world data on differential cross sections and polarization asymmetries of backward pion-nucleon scattering for invariant collision energies above 3 GeV is performed in a Regge model. Including the NαN_\alpha, NγN_\gamma, Δδ\Delta_\delta and Δβ\Delta_\beta trajectories, we reproduce both angular distributions and polarization data for small values of the Mandelstam variable uu, in contrast to previous analyses. The model amplitude is used to obtain evidence for baryon resonances with mass below 3 GeV. Our analysis suggests a G39G_{39} resonance with a mass of 2.83 GeV as member of the Δβ\Delta_{\beta} trajectory from the corresponding Chew-Frautschi plot.Comment: 12 pages, 16 figure

    MASH-II: More Planetary Nebulae from the AAO/UKST H\alpha Survey

    Full text link
    We present a supplement to the Macquarie/AAO/Strasbourg Hα\alpha planetary nebulae (PNe) catalogue (MASH), which we denote MASH-II. The supplement consists of over 300 true, likely and possible new Galactic PNe found after re-examination of the entire AAO/UKST Hα\alpha survey of the southern Galactic Plane in digital form. We have spectroscopically confirmed over 240 of these new candidates as bona-fide PNe and we include other high quality candidates awaiting spectroscopic confirmation as possible PNe. These latest discoveries largely comprise two distinct groups: small, star-like or moderately resolved PNe at one end and mostly large, extremely low surface brightness PNe at the other. Neither group were easy to discover from simple visual scrutiny of the original survey exposures as for MASH but were relatively straightforward to uncover from the digital images via application of semi-automated discovery techniques. We suspect the few PNe still hidden in the Hα\alpha survey will lie outside our search criteria or be difficult to find.Comment: 10 pages, 8 figures. Accepted for publication in MNRAS. Catalogue will be available from vizie

    On the curvature in logarithmic plots of rate coefficients for chemical reactions

    Get PDF
    In terms of the reduced potential energy barrier ζ = ΔuTS/kT, the rate coefficients for chemical reactions are usually expressed as proportional to e-ζ. The coupling between vibrational modes of the medium to the reaction coordinate leads to a proportionality of the regularized gamma function of Euler Q(a,ζ) = Γ(a,ζ)/Γ(a), with a being the number of modes coupled to the reaction coordinate. In this work, the experimental rate coefficients at various temperatures for several chemical reactions were fitted to the theoretical expression in terms of Q(a,ζ) to determine the extent of its validity and generality. The new expression affords lower deviations from the experimental points in 29 cases out of 38 and it accounts for the curvature in the logarithmic plots of rate coefficients versus inverse temperature. In the absence of tunneling, conventional theories predict the curvature of these plots to be identically zero

    Photodissociation of ClNO in the 2 1A' state: computational and experimental NO product state distributions.

    No full text
    Ultrafast photodissociation of the 2 (1)A' state of ClNO, which has an absorption spectrum peaking at 335 nm, is studied by computational and experimental methods. New potential-energy surfaces are calculated for the 1 and 2 (1)A' states at the multireference configuration interaction (MRCI) level. Wavepacket dynamics simulations performed both exactly and by using the multiconfiguration time-dependent Hartree method yield essentially identical results. Transition dipole moments at a range of geometries are included in these calculations to correctly model the excitation. Vibrational and rotational state distributions of the NO product are obtained both computationally by analysing the quantum flux on the 2 (1)A' surface and experimentally by use of 3D resonant multiphoton ionisation (REMPI), a variant of the velocity map imaging technique. The nascent NO is found to be only marginally vibrationally excited, with 91% formed in v=0. The calculated NO rotational distribution peaks in the j=45-55 region, which compares favourably to experiment
    corecore