Nano-photocatalysts in microfluidics, energy conversion and environmental applications

Extensive studies have been carried out on photocatalytic materials in recent years as photocatalytic reactions offer a promising solution for solar energy conversion and environmental remediation. Currently available commercial photocatalysts still lack efficiency and thus are economically not viable for replacing traditional sources of energy. This article focuses on recent developments in novel nano-photocatalyst materials to enhance photocatalytic activity. Recent reports on optofluidic systems, new synthesis of photocatalytic composite materials and motile photocatalysts are discussed in this article.Postprint (published version

Primary signet-ring cell carcinoma of the urinary bladder

Primary signet-ring cell carcinoma of the urinary bladder is a rare tumor. The overall incidence is approximately 0.12-0.6% of all urinary bladder malignancies. The majority of the patients present in an advanced stage with a uniformly grim prognosis. As signet-ring cell carcinomas are more common in the gastrointestinal tract, a possibility of metastasis needs to be considered. Here we report, a 42-year-old patient who presented with hematuria and was diagnosed with a urinary bladder tumor. The patient was managed with partial cystectomy and pelvic lymph node dissection. The histopathological examination confirmed primary signet-ring cell carcinoma of the urinary bladder

Determining unstable game states to aid the identification of perturbations in football

Alternative approaches to the reductionist method for analysing football are needed to better understand factors typically not considered, for example off the ball runs by teammates. The dynamical systems approach, where the complex relationships between players is emphasised, predicts that goal scoring opportunities are preceded by instability in the balance between the two teams’ behaviours. The aim was to create operational definitions for determining unstable game states to facilitate the identification of perturbations, that is the causes of instability. Validity tests involving four English Premier League (EPL) football coaches and two performance analysts and subsequent reliability tests established five unstable game states; penalty box possession, counter attack, ratio of attacking to defending players, successful cross and successful shot. Eighteen EPL matches were analysed to present exemplar statistics for three teams of different standard (based on final league position) suggesting that teams create unstable situations differently, likely due to individual player characteristics, with home advantage and opposition strength effects, suggesting this may be a component of what constitutes a performance indicator for a team. Future studies need to consider individual player actions that create instability as well as provide objective measures that substantiate findings

The attacking process in football: a taxonomy for classifying how teams create goal scoring opportunities using a case study of Crystal Palace FC

Purpose: Whilst some studies have comprehensively described the different features associated with the attacking process in football they have not produced a methodology of practical use for performance enhancement. This study presents a framework of comprehensive and meaningful metrics to objectively describe the attacking process so that useful performance profiles can be produced. Methods: The attacking process was categorized into three independent situations, no advantage (stable), advantage, and unstable (potential goal scoring opportunity) situations. Operational definitions for each situation enhanced their reliability and validity. English Premier League football matches (n = 38) played by Crystal Palace Football Club in the 2017/2018 season were analyzed as an exemplar. Results: Crystal Palace FC created a median of 53.5 advantage situations (IQR = 16.8) and 23 unstable situations (IQR = 8.8) per match. They frequently utilized wide areas (Median = 21.5, IQR = 9.8) to progress, but only 26.6% resulted in unstable situations (Median = 6.0, IQR = 3.8), the lowest rate compared to the other advantage situations. Conclusion: This classification framework, when used with contextual factors in a multi-factorial manner, including individual player contributions, will provide practically useful information for applied practice. This approach will help close the so called theory-practice gap and enable academic rigor to inform practical problems

Investigating Poor Performance Regions of Black Boxes: LIME-based Exploration in Sepsis Detection

Interpreting machine learning models remains a challenge, hindering their adoption in clinical settings. This paper proposes leveraging Local Interpretable Model-Agnostic Explanations (LIME) to provide interpretable descriptions of black box classification models in high-stakes sepsis detection. By analyzing misclassified instances, significant features contributing to suboptimal performance are identified. The analysis reveals regions where the classifier performs poorly, allowing the calculation of error rates within these regions. This knowledge is crucial for cautious decision-making in sepsis detection and other critical applications. The proposed approach is demonstrated using the eICU dataset, effectively identifying and visualizing regions where the classifier underperforms. By enhancing interpretability, our method promotes the adoption of machine learning models in clinical practice, empowering informed decision-making and mitigating risks in critical scenarios.Comment: Accepted at the 1st World Conference on eXplainable Artificial Intelligence - Late-breaking work, Demos and Doctoral Consortium, 202

Determining unstable game states to aid the identification of perturbations in football

Alternative approaches to the reductionist method for analysing football are needed to better understand factors typically not considered, for example off the ball runs by teammates. The dynamical systems approach, where the complex relationships between players is emphasised, predicts that goal scoring opportunities are preceded by instability in the balance between the two teams’ behaviours. The aim was to create operational definitions for determining unstable game states to facilitate the identification of perturbations, that is the causes of instability. Validity tests involving four English Premier League (EPL) football coaches and two performance analysts and subsequent reliability tests established five unstable game states; penalty box possession, counter attack, ratio of attacking to defending players, successful cross and successful shot. Eighteen EPL matches were analysed to present exemplar statistics for three teams of different standard (based on final league position) suggesting that teams create unstable situations differently, likely due to individual player characteristics, with home advantage and opposition strength effects, suggesting this may be a component of what constitutes a performance indicator for a team. Future studies need to consider individual player actions that create instability as well as provide objective measures that substantiate findings

Nano-photocatalysts in microfluidics, energy conversion and environmental applications

Extensive studies have been carried out on photocatalytic materials in recent years as photocatalytic reactions offer a promising solution for solar energy conversion and environmental remediation. Currently available commercial photocatalysts still lack efficiency and thus are economically not viable for replacing traditional sources of energy. This article focuses on recent developments in novel nano-photocatalyst materials to enhance photocatalytic activity. Recent reports on optofluidic systems, new synthesis of photocatalytic composite materials and motile photocatalysts are discussed in this article.11148Ysciescopu

Evaluating goal threat in football using player and ball locations

Goal scoring in football is relatively low but vitally important, hence research has considered how goals are created and scored with measures such as expected goals prevalent. The dynamical systems theoretical perspective, considers a collective system, such as football, as existing in two states, stable (no substantive advantage for either team) or unstable (advantage present). Hence, goal scoring events occur when the system has become unstable, with a “perturbation” the event causing the system state change. Here, a “goal threat” value was calculated every second (scaled from 0 to 100) using the XY coordinates of players and the ball, weighted in relation to proximity to the goal (a potential proxy for the degree of system instability). Video recordings and synchronised Amisco 2D representations of goals (n=64) scored in Swansea City AFC English Premier League 2012/2013 matches (n=20) were analysed using Dartfish v10 Pro software. Each goal was analysed from when the play was judged to be stable (no obvious goal scoring opportunity), or the start of possession, until the goal had been scored. Goals were not always preceded by high goal threat values (maximum goal threat values ranged from 13.4 to 99.0). The authors independently subjectively determined that perturbations occurred up to 7 seconds from when the goal threat value increased by at least 40%. Thus, perturbations were not directly related to goal scoring opportunities. This novel method provides a useful, quantifiable, and simple measure of goal threat that may also aid audience engagement and measure defensive effectiveness