443 research outputs found
Synthesis of Mesoporous TiO2 Template-Free and Photocatalytic Activity for Azo Dye Degradation
Nanoporous titanium dioxide was prepared by sol-gel technique. To control the surface area, pore size and pore volume of the prepared TiO2, a catalyzed hydrolysis was carried out using different concentrations of silicotungstic acid (SWA) as a template. A fixed molar ratio of H2O/Ti was used. The prepared TiO2 was calcined at 400 or 600oC. Samples were characterized by nitrogen physic-sorption, X-ray powder diffraction (XRD), selected scattered electron diffraction, Raman spectroscopic analysis, Fourier Transform spectroscopy (FTIR), Thermo gravimetric analysis (TGA), Differential scanning calorimetry (DSC), scanning and transmission electron microscopy (SEM and TEM). The photocatalytic activity of the prepared samples was evaluated by the degradation of alizarin yellow under UV light. The results showed that the crystallinity increases as the concentration of SWA decreases. The presence of SWA during the precipitation of TiO2 prevents the formation of rutile phase and suppresses the crystal growth. The results showed also that the surface area increases as the concentration of SWA decreases. The samples prepared using 0.05M SWA and calcined at 600 oC showed a higher activity. Keywords: mesoporous TiO2, photocatalytic degradation, alizarin yellow, azodye
Activity of 50 Long-Period Comets Beyond 5.2 AU
Remote investigations of the ancient solar system matter has been
traditionally carried out through the observations of long-period (LP) comets
that are less affected by solar irradiation than the short-period counterparts
orbiting much closer to the Sun. Here we summarize the results of our
decade-long survey of the distant activity of LP comets. We found that the most
important separation in the dataset is based on the dynamical nature of the
objects. Dynamically new comets are characterized by a higher level of activity
on average: the most active new comets in our sample can be characterized by
afrho values >3--4 higher than that of our most active returning comets. New
comets develop more symmetric comae, suggesting a generally isotropic outflow.
Contrary to this, the coma of recurrent comets can be less symmetrical,
ocassionally exhibiting negative slope parameters, suggesting sudden variations
in matter production. The morphological appearance of the observed comets is
rather diverse. A surprisingly large fraction of the comets have long, teniouos
tails, but the presence of impressive tails does not show a clear correlation
with the brightness of the comets.Comment: 21 pages, 4 figures, accepted for publication in A
Exploring the circumstellar environment of the young eruptive star V2492 Cyg
Context. V2492 Cyg is a young eruptive star that went into outburst in 2010.
The near-infrared color changes observed since the outburst peak suggest that
the source belongs to a newly defined sub-class of young eruptive stars, where
time-dependent accretion and variable line-of-sight extinction play a combined
role in the flux changes.
Aims. In order to learn about the origin of the light variations and to
explore the circumstellar and interstellar environment of V2492 Cyg, we
monitored the source at ten different wavelengths, between 0.55 \mu m and 2.2
\mu m from the ground and between 3.6 \mu m and 160 \mu m from space.
Methods. We analyze the light curves and study the color-color diagrams via
comparison with the standard reddening path. We examine the structure of the
molecular cloud hosting V2492 Cyg by computing temperature and optical depth
maps from the far-infrared data.
Results. We find that the shapes of the light curves at different wavelengths
are strictly self-similar and that the observed variability is related to a
single physical process, most likely variable extinction. We suggest that the
central source is episodically occulted by a dense dust cloud in the inner
disk, and, based on the invariability of the far-infrared fluxes, we propose
that it is a long-lived rather than a transient structure. In some respects,
V2492 Cyg can be regarded as a young, embedded analog of UX Orionis-type stars.
Conclusions. The example of V2492 Cyg demonstrates that the light variations
of young eruptive stars are not exclusively related to changing accretion. The
variability provided information on an azimuthally asymmetric structural
element in the inner disk. Such an asymmetric density distribution in the
terrestrial zone may also have consequences for the initial conditions of
planet formation.Comment: 9 pages, 7 figures, 2 online tables, accepted for publication in A&
Multi-wavelength study of the low-luminosity outbursting young star HBC 722
HBC 722 (V2493 Cyg) is a young eruptive star in outburst since 2010. It is an
FU Orionis-type object with an atypically low outburst luminosity. Because it
was well characterized in the pre-outburst phase, HBC 722 is one of the few
FUors where we can learn about the physical changes and processes associated
with the eruption. We monitored the source in the BVRIJHKs bands from the
ground, and at 3.6 and 4.5 m from space with the Spitzer Space Telescope.
We analyzed the light curves and the spectral energy distribution by fitting a
series of steady accretion disk models at many epochs. We also analyzed the
spectral properties of the source based on new optical and infrared spectra. We
also mapped HBC 722 and its surroundings at millimeter wavelengths. From the
light curve analysis we concluded that the first peak of the outburst in 2010
September was due to an abrupt increase of the accretion rate in the innermost
part of the system. This was followed by a long term process, when the
brightening was mainly due to a gradual increase of the accretion rate and the
emitting area. Our new observations show that the source is currently in a
constant plateau phase. We found that around the peak the continuum was bluer
and the H profile changed significantly between 2012 and 2013. The
source was not detected in the millimeter continuum, but we discovered a
flattened molecular gas structure with a diameter of 1700 au and mass of 0.3
M centered on HBC 722. While the first brightness peak could be
interpreted as a rapid fall of piled-up material from the inner disk onto the
star, the later monotonic flux rise suggests the outward expansion of a hot
component according to the theory of Bell & Lin (1994). Our study of HBC 722
demonstrated that accretion-related outbursts can occur in young stellar
objects even with very low mass disks, in the late Class II phase.Comment: 11 pages, 7 figures, 3 online tables. Accepted for publication in the
A&
Implantation of a colorectal stent as a therapeutic approach in the treatment of esophageal leakage
BACKGROUND: While the mortality of esophageal surgery has decreased due to technological advancements, there is still a complication rate of about 30%. One of the main complications is the anastomotic leakage associated with a significant rate of morbidity and mortality. To close the leakage the efficacy of self-expanding stents (SES) has been shown in different studies. However, the high rate of stent migration limits the use of commercial available stents. In our case we were faced with the problem that the diameter of all available stents was too small to attach tightly to the mucosal wall of the esophagogastric anastomosis. CASE PRESENTATION: We used, for the first time to our knowledge, a metal stent designed for colorectal application in an extensive anastomotic leak after esophageal resection in a patient with an esophageal cancer. After primary surgery with subtotal esohagectomy the anastomotic leak was stented endoscopically with a Polyflex self-expanding covered plastic stent after no response to intensive conventional management. Even though the stent was placed correctly, the diameter of the Polyflex stent was too small to attach onto the wall of the esophagogastric anastomosis. Again surgery was performed with a thoracal resection of the esophageal remnant and a hand made anastomosis. Unfortunately, again an anastomotic leak was detected soon after. To close the leak we decided to use a covered colorectal stent (Hanarostent) with an inner diameter of 30 mm. Sixteen weeks later the stent was extracted and complete mucosal healing of the esophageal leak was observed. CONCLUSION: The stent implantation with a large wide diameter offers a good chance to close more extensive leaks and prevent stent migration
Testing SNe Ia distance measurement methods with SN 2011fe
The nearby, bright, almost completely unreddened Type Ia supernova 2011fe in
M101 provides a unique opportunity to test both the precision and the accuracy
of the extragalactic distances derived from SNe Ia light curve fitters. We
apply the current, public versions of the independent light curve fitting codes
MLCS2k2 and SALT2 to compute the distance modulus of SN 2011fe from
high-precision, multi-color (BVRI) light curves. The results from the two
fitting codes confirm that 2011fe is a "normal" (not peculiar) and only
slightly reddened SN Ia. New unreddened distance moduli are derived as 29.21
+/- 0.07 mag (D ~ 6.95 +/- 0.23$ Mpc, MLCS2k2), and 29.05 +/- 0.07 mag (6.46
+/- 0.21 Mpc, SALT2). Despite the very good fitting quality achieved with both
light curve fitters, the resulting distance moduli are inconsistent by 2 sigma.
Both are marginally consistent (at ~1 sigma) with the HST Key Project distance
modulus for M101. The SALT2 distance is in good agreement with the recently
revised Cepheid- and TRGB-distance to M101. Averaging all SN- and Cepheid-based
estimates, the absolute distance to M101 is ~6.6 +/- 0.5 Mpc.Comment: 8 pages, 7 figures, accepted for publication in A&
Extensive Spectroscopy and Photometry of the Type IIP Supernova 2013ej
We present extensive optical (, , and open CCD) and
near-infrared () photometry for the very nearby Type IIP SN ~2013ej
extending from +1 to +461 days after shock breakout, estimated to be MJD
. Substantial time series ultraviolet and optical spectroscopy
obtained from +8 to +135 days are also presented. Considering well-observed SNe
IIP from the literature, we derive bolometric calibrations from
and unfiltered measurements that potentially reach 2\% precision with a
color-dependent correction. We observe moderately strong Si II
as early as +8 days. The photospheric velocity () is
determined by modeling the spectra in the vicinity of Fe II
whenever observed, and interpolating at photometric epochs based on a
semianalytic method. This gives km s at +50
days. We also observe spectral homogeneity of ultraviolet spectra at +10--12
days for SNe IIP, while variations are evident a week after explosion. Using
the expanding photosphere method, from combined analysis of SN 2013ej and SN
2002ap, we estimate the distance to the host galaxy to be
Mpc, consistent with distance estimates from other methods. Photometric and
spectroscopic analysis during the plateau phase, which we estimated to be
days long, yields an explosion energy of
ergs, a final pre-explosion progenitor mass of ~M and a
radius of ~R. We observe a broken exponential profile beyond
+120 days, with a break point at + days. Measurements beyond this
break time yield a Ni mass of ~M.Comment: 29 pages, 23 figures, 15 tables, Published in The Astrophisical
Journa
Deep Neuromuscular Blockade Improves Laparoscopic Surgical Conditions:A Randomized, Controlled Study
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