Anisotropic excitonic effects in the energy loss function of hexagonal boron nitride

We demonstrate that the valence energy-loss function of hexagonal boron nitride (hBN) displays a strong anisotropy in shape, excitation energy and dispersion for momentum transfer q parallel or perpendicular to the hBN layers. This is manifested by e.g. an energy shift of 0.7 eV that cannot be captured by single-particle approaches and is a demonstration of a strong anisotropy in the two-body electron-hole interaction. Furthermore, for in-plane directions of q we observe a splitting of the -plasmon in the M direction that is absent in the K direction and this can be traced back to band-structure effects.Comment: 10 pages, 4 figure

Changement de sujet, empathie et changement de point de vue : étude de cas en traduction littéraire

L’article se propose d’étudier le lien entre empathie et changement de point de vue à travers le changement de sujet grammatical en traduction littéraire finnois-français-finnois. L’analyse se concentre sur trois exemples de représentation écrite du discours direct où le sujet change entre le texte source et son texte cible. La première partie de cet article définit les notions de point de vue et d’empathie en se basant sur la littérature existante dans trois domaines distincts : la traductologie, la narratologie et la linguistique. Elle montre en outre pourquoi le sujet grammatical représente un objet d’étude privilégié pour mettre au jour le changement de point de vue. L’analyse du changement de sujet en traduction faite en deuxième partie de l’article s’appuie sur ces trois approches. La troisième partie fait le lien entre le changement de point de vue observé dans les exemples analysés et la notion d’empathisation. L’analyse de ce lien montre la complexité des rapports entre point de vue et empathie lorsque l’objet d’étude est la traduction de textes littéraires.Peer reviewe

K -shell diagram and hypersatellite spectra of 4d transition elements

The K-shell diagram (K alpha(1,2) and K beta(1,3)) and hypersatellite (HS) (K-h alpha(1,2)) spectra of Y, Zr, Mo, and Pd have been measured with high energy-resolution using photoexcitation by 90 keV synchrotron radiation. Comparison of the measured and ab initio calculated HS spectra demonstrates the importance of quantum electrodynamical (QED) effects for the HS spectra. Phenomenological fits of the measured spectra by Voigt functions yield accurate values for the shift of the HS from the diagram lines, the splitting of the HS lines, and their intensity ratio. Good agreement with theory was found for all quantities except for the intensity ratio, which is dominated by the intermediacy of the coupling of the angular momenta. The observed deviations imply that our current understanding of the variation of the coupling scheme from LS to jj across the periodic table may require some revision.The K-shell diagram (K alpha(1,2) and K beta(1,3)) and hypersatellite (HS) (K-h alpha(1,2)) spectra of Y, Zr, Mo, and Pd have been measured with high energy-resolution using photoexcitation by 90 keV synchrotron radiation. Comparison of the measured and ab initio calculated HS spectra demonstrates the importance of quantum electrodynamical (QED) effects for the HS spectra. Phenomenological fits of the measured spectra by Voigt functions yield accurate values for the shift of the HS from the diagram lines, the splitting of the HS lines, and their intensity ratio. Good agreement with theory was found for all quantities except for the intensity ratio, which is dominated by the intermediacy of the coupling of the angular momenta. The observed deviations imply that our current understanding of the variation of the coupling scheme from LS to jj across the periodic table may require some revision.The K-shell diagram (K alpha(1,2) and K beta(1,3)) and hypersatellite (HS) (K-h alpha(1,2)) spectra of Y, Zr, Mo, and Pd have been measured with high energy-resolution using photoexcitation by 90 keV synchrotron radiation. Comparison of the measured and ab initio calculated HS spectra demonstrates the importance of quantum electrodynamical (QED) effects for the HS spectra. Phenomenological fits of the measured spectra by Voigt functions yield accurate values for the shift of the HS from the diagram lines, the splitting of the HS lines, and their intensity ratio. Good agreement with theory was found for all quantities except for the intensity ratio, which is dominated by the intermediacy of the coupling of the angular momenta. The observed deviations imply that our current understanding of the variation of the coupling scheme from LS to jj across the periodic table may require some revision.Peer reviewe

Direct observation of the momentum distribution and renormalization factor in lithium

We have measured the momentum distribution and renormalization factor Z(kF) in liquid and solid lithium by high-resolution Compton scattering. High-resolution data over a wide momentum range exhibit a clear feature of the renormalization and a sharp drop of momentum densities at the Fermi momentum k(F). These results are compared with those computed by quantum Monte Carlo simulation performed both on a disordered crystal and a liquid exhibiting very good agreement. Asymptotic behavior of the experimental and theoretical momentum distributions are examined to estimate Z(kF). The experimentally obtained Z(kF) = 0.43(-0.01)(+0.11) for liquid Li and 0.54(-0.02)(+0.11) for solid Li are in good agreement with theoretical results of 0.54 +/- 0.01 and 0.64 +/- 0.01, respectively.Peer reviewe

Comparing seven methods for state-of-health time series prediction for the lithium-ion battery packs of forklifts

A key aspect for the forklifts is the state-of-health (SoH) assessment to ensure the safety and the reliability of uninterrupted power source. Forecasting the battery SoH well is imperative to enable preventive maintenance and hence to reduce the costs. This paper demonstrates the capabilities of gradient boosting regression for predicting the SoH timeseries under circumstances when there is little prior information available about the batteries. We compared the gradient boosting method with light gradient boosting, extra trees, extreme gradient boosting, random forests, long short-term memory networks and with combined convolutional neural network and long short-term memory networks methods. We used multiple predictors and lagged target signal decomposition results as additional predictors and compared the yielded prediction results with different sets of predictors for each method. For this work, we are in possession of a unique data set of 45 lithium-ion battery packs with large variation in the data. The best model that we derived was validated by a novel walk-forward algorithm that also calculates point-wise confidence intervals for the predictions; we yielded reasonable predictions and confidence intervals for the predictions. Furthermore, we verified this model against five other lithium-ion battery packs; the best model generalised to greater extent to this set of battery packs. The results about the final model suggest that we were able to enhance the results in respect to previously developed models. Moreover, we further validated the model for extracting cycle counts presented in our previous work with data from new forklifts; their battery packs completed around 3000 cycles in a 10-year service period, which corresponds to the cycle life for commercial Nickel–Cobalt–Manganese (NMC) cells

Li 1s core exciton in LiH studied by x-ray Raman scattering spectroscopy

The Li 1s core excitation spectra in LiH was studied by means of x-ray Raman scattering (XRS) spectroscopy in a wide range of momentum transfers q. The analysis of the near-edge region of the measured spectra in combination with q-dependent ab initio calculations of XRS spectra based on the Bethe-Salpeter equation (BSE) reveals that the prominent peak at the excitation onset arises from two main contributions, namely a pre-edge peak associated to a p-type core exciton and strong transitions to empty states near the bottom of the conduction band, which is in contrast to previous experimental studies that attributed that feature to a single excitonic peak. The p-like angular symmetry of the core exciton is supported by BSE calculations of the relative contributions to the XRS spectra from monopole and dipole transitions and by the observed decrease of its normalised intensity for increasing momentum transfers. Higher energy spectral features in the measured XRS spectra are well reproduced by BSE, as well as by real-space multiple-scattering calculations.Peer reviewe

Cyclic variations of the heliospheric tilt angle and cosmic ray modulation,

Abstract Using data on cosmic ray modulation parameter since 1951, we have estimated the evolution of the heliospheric current sheet tilt angle for the period 1951-1975, i.e., 25 years before regular observations of the tilt angle. This estimate is based on our recent empirical model relating cosmic ray intensity with global heliospheric parameters. We propose a simple model to describe the cyclic evolution of the tilt angle with the solar cycle. This model agrees with available observational data. Using this model, we have estimated the cosmic ray intensity since 1710. This estimate is consistent with the results based on cosmogenic isotopes ( 14 C and 10 Be)