346 research outputs found
Electrode Polarization Effects in Broadband Dielectric Spectroscopy
In the present work, we provide broadband dielectric spectra showing strong
electrode polarization effects for various materials, belonging to very
different material classes. This includes both ionic and electronic conductors
as, e.g., salt solutions, ionic liquids, human blood, and
colossal-dielectric-constant materials. These data are intended to provide a
broad data base enabling a critical test of the validity of phenomenological
and microscopic models for electrode polarization. In the present work, the
results are analyzed using a simple phenomenological equivalent-circuit
description, involving a distributed parallel RC circuit element for the
modeling of the weakly conducting regions close to the electrodes. Excellent
fits of the experimental data are achieved in this way, demonstrating the
universal applicability of this approach. In the investigated ionically
conducting materials, we find the universal appearance of a second dispersion
region due to electrode polarization, which is only revealed if measuring down
to sufficiently low frequencies. This indicates the presence of a second
charge-transport process in ionic conductors with blocking electrodes.Comment: 9 pages, 6 figures, experimental data are provided in electronic form
(see "Data Conservancy"
Matrix theory of gravitation
A new classical theory of gravitation within the framework of general
relativity is presented. It is based on a matrix formulation of
four-dimensional Riemann-spaces and uses no artificial fields or adjustable
parameters. The geometrical stress-energy tensor is derived from a matrix-trace
Lagrangian, which is not equivalent to the curvature scalar R. To enable a
direct comparison with the Einstein-theory a tetrad formalism is utilized,
which shows similarities to teleparallel gravitation theories, but uses complex
tetrads. Matrix theory might solve a 27-year-old, fundamental problem of those
theories (sec. 4.1). For the standard test cases (PPN scheme,
Schwarzschild-solution) no differences to the Einstein-theory are found.
However, the matrix theory exhibits novel, interesting vacuum solutions.Comment: 24 page
Linear optical properties of one-dimensional Frenkel exciton systems with intersite energy correlations
We analyze the effects of intersite energy correlations on the linear optical
properties of one-dimensional disordered Frenkel exciton systems. The
absorption line width and the factor of radiative rate enhancement are studied
as a function of the correlation length of the disorder. The absorption line
width monotonously approaches the seeding degree of disorder on increasing the
correlation length. On the contrary, the factor of radiative rate enhancement
shows a non-monotonous trend, indicating a complicated scenario of the exciton
localization in correlated systems. The concept of coherently bound molecules
is exploited to explain the numerical results, showing good agreement with
theory. Some recent experiments are discussed in the light of the present
theory.Comment: 18 pages, 3 figues, REVTeX, to appear in Physical Review
Celadonite and smectite formation in the ĂšrkĂşt Mn-carbonate ore deposit (Hungary)
Synsedimentary and early diagenetic oxygen levels are estimated by evaluating celadonitesmectite formation in marine Jurassic black shale-hosted manganese-carbonates. Celadonite formed under suboxic-dysaerobic conditions, Al-rich Fe-smectite formed at suboxic-anaerobic conditions, and nontronite formed at anoxic-anaerobic conditions during sedimentary burial. A genetic pathway by direct precipitation from solution is proposed for the enormous mass of celadonite, based on mineral and textural evidence. Lamination of the manganese ore is independent of clay-mineral composition and was given by a series of mineralized microbial Ferich biomats
Exploring the effects of colouring graph diagrams on people of various backgrounds
Colour is one of the primary aesthetic elements of a visualization. It is often used successfully to encode information such as the importance of a particular part of the diagram or the relationship between two parts. Even so, there are few investigations into the human reading of colour coding on diagrams from the scientific community. In this paper we report on an experiment with graph diagrams comparing a black and white composition with two other colour treatments. We drew our subjects from engineering, art, visual design, physical education, tourism, psychology and social science disciplines. We found that colouring the nodes of interest reduced the time taken to find the shortest path between the two nodes for all subjects. Engineers, tourism and social scientists proved significantly faster with artist/designers just below the overall average speed. From this study, we contribute that adding particular colour treatments to diagrams increases legibility. In addition, preliminary work investigating colour treatments and schemes indicates potential for future gains. © 2014 Springer-Verlag
Active Brownian Particles. From Individual to Collective Stochastic Dynamics
We review theoretical models of individual motility as well as collective
dynamics and pattern formation of active particles. We focus on simple models
of active dynamics with a particular emphasis on nonlinear and stochastic
dynamics of such self-propelled entities in the framework of statistical
mechanics. Examples of such active units in complex physico-chemical and
biological systems are chemically powered nano-rods, localized patterns in
reaction-diffusion system, motile cells or macroscopic animals. Based on the
description of individual motion of point-like active particles by stochastic
differential equations, we discuss different velocity-dependent friction
functions, the impact of various types of fluctuations and calculate
characteristic observables such as stationary velocity distributions or
diffusion coefficients. Finally, we consider not only the free and confined
individual active dynamics but also different types of interaction between
active particles. The resulting collective dynamical behavior of large
assemblies and aggregates of active units is discussed and an overview over
some recent results on spatiotemporal pattern formation in such systems is
given.Comment: 161 pages, Review, Eur Phys J Special-Topics, accepte
A Search for Selectrons and Squarks at HERA
Data from electron-proton collisions at a center-of-mass energy of 300 GeV
are used for a search for selectrons and squarks within the framework of the
minimal supersymmetric model. The decays of selectrons and squarks into the
lightest supersymmetric particle lead to final states with an electron and
hadrons accompanied by large missing energy and transverse momentum. No signal
is found and new bounds on the existence of these particles are derived. At 95%
confidence level the excluded region extends to 65 GeV for selectron and squark
masses, and to 40 GeV for the mass of the lightest supersymmetric particle.Comment: 13 pages, latex, 6 Figure
Aqueous batteries as grid scale energy storage solutions
Energy storage technologies are required to make full use of renewable energy sources, and electrochemical
cells offer a great deal flexibility in the design of energy systems. For large scale electrochemical
storage to be viable, the materials employed and device production methods need to be low cost, devices
should be long lasting and safety during operation is of utmost importance. Energy and power densities
are of lesser concern. For these reasons, battery chemistries that make use of aqueous electrolytes are
favorable candidates where large quantities of energy need to be stored. Herein we describe several
different aqueous based battery chemistries and identify some of the research challenges currently
hindering their wider adoption. Lead acid batteries represent a mature technology that currently dominates
the battery market, however there remain challenges that may prevent their future use at the
large scale. Nickel–iron batteries have received a resurgence of interest of late and are known for their
long cycle lives and robust nature however improvements in efficiency are needed in order to make them
competitive. Other technologies that use aqueous electrolytes and have the potential to be useful in
future large-scale applications are briefly introduced. Recent investigations in to the design of nickel–iron
cells are reported with it being shown that electrolyte decomposition can be virtually eliminated by
employing relatively large concentrations of iron sulfide in the electrode mixture, however this is at the
expense of capacity and cycle life
Non-crossing dependencies: Least effort, not grammar
The use of null hypotheses (in a statistical sense) is common in hard sciences but not in theoretical linguistics. Here the null hypothesis that the low frequency of syntactic dependency crossings is expected by an arbitrary ordering of words is rejected. It is shown that this would require star dependency structures, which are both unrealistic and too restrictive. The hypothesis of the limited resources of the human brain is revisited. Stronger null hypotheses taking into account actual dependency lengths for the likelihood of crossings are presented. Those hypotheses suggests that crossings are likely to reduce when dependencies are shortened. A hypothesis based on pressure to reduce dependency lengths is more parsimonious than a principle of minimization of crossings or a grammatical ban that is totally dissociated from the general and non-linguistic principle of economy.Postprint (author's final draft
The Unitary Gas and its Symmetry Properties
The physics of atomic quantum gases is currently taking advantage of a
powerful tool, the possibility to fully adjust the interaction strength between
atoms using a magnetically controlled Feshbach resonance. For fermions with two
internal states, formally two opposite spin states, this allows to prepare long
lived strongly interacting three-dimensional gases and to study the BEC-BCS
crossover. Of particular interest along the BEC-BCS crossover is the so-called
unitary gas, where the atomic interaction potential between the opposite spin
states has virtually an infinite scattering length and a zero range. This
unitary gas is the main subject of the present chapter: It has fascinating
symmetry properties, from a simple scaling invariance, to a more subtle
dynamical symmetry in an isotropic harmonic trap, which is linked to a
separability of the N-body problem in hyperspherical coordinates. Other
analytical results, valid over the whole BEC-BCS crossover, are presented,
establishing a connection between three recently measured quantities, the tail
of the momentum distribution, the short range part of the pair distribution
function and the mean number of closed channel molecules.Comment: 63 pages, 8 figures. Contribution to the Springer Lecture Notes in
Physics "BEC-BCS Crossover and the Unitary Fermi gas" edited by Wilhelm
Zwerger. Revised version correcting a few typo
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