Aesthetic Quality Properties of Carbonate Breccias Associated with Textural and Compositional Factors: Marrón Emperador Ornamental Stone (Upper Cretaceous, Southeast Spain)

The aesthetic properties of ornamental stones, including colour, texture, and the presence or absence of discontinuities, are influential in their use and marketing. This is particularly critical in brecciated rocks such as the Marrón Emperador (ME) ornamental stone, a dark brown breccia dolostone (Upper Cretaceous, southeast Spain). ME shows a high chromatic and textural variability, which is one of its most appreciated commercial features. Through a petrographic, mineralogical, geochemical and colourimetric study of samples obtained from quarries, outcrops and/or drilling cores, several quality categories have been established, as well as the relationship between the aesthetic properties of ME ornamental stone with its compositional and textural factors. Three main types of breccia constitute the ME exploitable lithotect: crackle and mosaic packbreccias, and rubble floatbreccias. Breccia clasts are mainly composed of hypidiotopic-idiotopic medium- to coarsely-crystalline dolosparites, microcrystalline dolosparites and dolomicrites. Results show that diagenetic processes are mainly responsible for the colour of ME dolostones, revealing that the Sr content is a key factor. The darker brown dolomites always show a higher Sr content, where other typical chromophore elements in dolomites, such as Fe and Mn, do not present this correlation. This study provides evidence for the complexity of processes and factors that are responsible for aesthetic quality features in ornamental stones

Supersymmetric Quantum Mechanics, multiphoton algebras and coherent states

The multiphoton algebras for one-dimensional Hamiltonians with infinite discrete spectrum, and for their associated kth-order SUSY partners are studied. In both cases, such an algebra is generated by the multiphoton annihilation and creation operators, as well as by Hamiltonians which are functions of an appropriate number operator. The algebras obtained turn out to be polynomial deformations of the corresponding single-photon algebra previously studied. The Barut-Girardello coherent states, which are eigenstates of the annihilation operator, are obtained and their uncertainty relations are explored by means of the associated quadratures.Comment: Last version of the paper, 6 figure

Ultra-ductile and low friction epoxy matrix composites

We present the results of an effective reinforcement of epoxy resin matrix with fullerene carbon soot. The optimal carbon soot addition of 1 wt. % results in a toughness improvement of almost 20 times. The optimized soot-epoxy composites also show an increase in tensile elongation of more than 13 %, thus indicating a change of the failure mechanism in tension from brittle to ductile. Additionally, the coefficient of friction is reduced from its 0.91 value in plain epoxy resin to 0.15 in the optimized composite. In the optimized composite, the lateral forces during nanoscratching decrease as much as 80 % with enhancement of the elastic modulus and hardness by 43 % and 94%, respectively. The optimized epoxy resin fullerene soot composite can be a strong candidate for coating applications where toughness, low friction, ductility and light weight are important.Comment: 24 pages, 7 Figures, 1 Table in Polymer Testing (2015

Experimenting with RC and RL series circuits using smartphones as function generators and oscilloscopes

Simple, portable and low-cost experiments as RC and RL series circuits are proposed as examples to experiment with DC circuits. Very common elements are used: few electronics components (resistors, capacitors, coils and connecting wires) and two martphones. We consider the charging and discharging of a capacitor in the RC circuit and also that of coil in the RL circuit. Using a smartphone as a oscilloscope we observe voltages variations which are the transient response to a square signal generated in the second smartphones. These voltage variations are directly related to the electrostatic or magnetic energy stored in the circuits. The experimental data have been collected with the smartphone used as an oscilloscope. This approach which avoids the use of expensive signal generators, oscilloscopes, or any specialized hardware can be performed in less-favored contexts and even as a home assignment.Comment: 7 pages, 7 fig

Fatigue Study of the Pre-Corroded 6082-T6 Aluminum Alloy in Saline Atmosphere

[Abstract] This work studies the influence of the saline atmospheric corrosion on the fatigue strength of 6061-T6 aluminum alloy. For this purpose, this alloy was subjected to tests in a salt spray corrosion chamber at different exposure times (1, 2, and 3 months) according to ASTM B117 standard. The morphological study of the pits was carried out by confocal microscopy. Subsequently, fatigue tests were performed at variable stresses whose maximum stress (Smax) was between 30% and 95% of the yield strength (S0) in order to keep them within the zone of elastic behavior of the material. Data were analyzed using the Basquin equation and the maximum likelihood function method. The results show a similar decrease in the conventional fatigue limit (2 × 106 cycles) after one month (98 MPa) and two months (91 MPa) of corrosion. After three months of corrosion, the material showed a very important reduction in the fatigue limit (68 MPa) with respect to the uncorroded material (131 MPa). The data of Se/S0 (fatigue limit/yield strength) versus the ratio Pm/Dm (pit average depth/pit diameter at zero depth) can be fitted to a logarithmic curve

Langerin-Heparin Interaction: Two Binding Sites for Small and Large Ligands as revealed by a combination of NMR Spectroscopy and Cross-Linking Mapping Experiments

Langerin is a C-type lectin present on Langerhans cells that mediates capture of pathogens in a carbohydrate-dependent manner, leading to subsequent internalization and elimination in the cellular organelles called Birbeck granules. This mechanism mediated by langerin was shown to constitute a natural barrier for HIV-1 particle transmission. Besides interacting specifically with high mannose and fucosylated neutral carbohydrate structures, langerin has the ability to bind sulfated carbohydrate ligands as 6-sulfated galactosides in the Ca2+ dependent binding site. Very recently langerin was demonstrated to interact with sulfated glycosaminoglycans (GAGs), in a Ca2+ independent way, resulting in the proposal of a new binding site for GAGs. Based on those results, we have conducted a structural study of the interactions of small heparin (HEP) like oligosaccharides with langerin in solution. Heparin-bead cross-linking experiments, an approach specifically designed to identify HEP/HS binding sites in proteins were first carried out and experimentally validated the previously proposed model for the interaction of Lg ECD with 6 kDa HEP. High-resolution NMR studies of a set of 8 synthetic HEP-like trisaccharides harboring different sulfation patterns demonstrated that all of them bound to langerin in a Ca2+ dependent way. The binding epitopes were determined by STD NMR and the bound conformations by transferred NOESY experiments. These experimental data were combined with docking and molecular dynamics and resulted in the proposal of a binding mode characterized by the coordination of calcium by the two equatorial hydroxyl groups OH3 and OH4 at the non-reducing end. The binding also includes the carboxylate group at the adjacent iduronate residue. Such epitope is shared by all the 8 ligands, explaining the absence of any impact on binding from their differences in substitution pattern. Finally, in contrast to the small trisaccharides, we demonstrated that a longer HEP-like hexasaccharide, bearing an additional O-sulfate group at the non-reducing end, which precludes binding to the Ca2+ site, interacts with langerin in the previously identified Ca2+ independent binding site

Catalogue of exoplanets accessible in reflected starlight to the Nancy Grace Roman Space Telescope. A population study and prospects for phase-curve measurements

Reflected starlight measurements will open a new path in the characterization of directly imaged exoplanets. However, we still lack a population study of known targets amenable to this technique. Here, we investigate which of the about 4300 exoplanets confirmed to date are accessible to the Roman Space Telescope's coronagraph (CGI) in reflected starlight at reference wavelengths $\lambda$=575, 730 and 825 nm. We carry out a population study and also address the prospects for phase-curve measurements. We used the NASA Exoplanet Archive as a reference for planet and star properties, and explored the impact of their uncertainties on the exoplanet's detectability by applying statistical arguments. We define a planet as Roman-accessible on the basis of the instrument inner and outer working angles and its minimum planet-to-star constrast (IWA, OWA, $C_{min}$). We adopt for these technical specifications three plausible configurations labeled as pessimistic, intermediate and optimistic. Our key outputs for each exoplanet are its probability of being Roman-accessible ($P_{access}$), the range of observable phase angles, the evolution of its equilibrium temperature, the number of days per orbit that it is accessible and its transit probability. In the optimistic scenario, we find 26 Roman-accessible exoplanets with $P_{access}$>25% and host stars brighter than $V$=7 mag. This population is biased towards planets more massive than Jupiter but also includes the super-Earths tau Cet e and f which orbit near their star's habitable zone. A total of 13 planets are part of multiplanet systems, 3 of them with known transiting companions, offering opportunities for contemporaneous characterization. The intermediate and pessimistic scenarios yield 10 and 3 Roman-accessible exoplanets, respectively. We find that inclination estimates (e.g. with astrometry) are key for refining the detectability prospects.Comment: Accepted for publication in A&A. 34 pages, 12 Tables, 24 Figure

Temporal Griffiths Phases

Disorder is an unavoidable ingredient of real systems. Spatial disorder generates Griffiths phases (GPs) which, in analogy to critical points, are characterized by a slow relaxation of the order parameter and divergences of quantities such as the susceptibility. However, these singularities appear in an extended region of the parameter space and not just at a (critical) point, i.e. there is generic scale invariance. Here, we study the effects of temporal disorder, focusing on systems with absorbing states. We show that for dimensions $d \geq 2$ there are Temporal Griffiths phases (TGPs) characterized by generic power-law spatial scaling and generic divergences of the susceptibility. TGPs turn out to be a counterpart of GPs, but with space and time playing reversed roles. TGPs constitute a unifying concept, shedding light on the non-trivial effects of temporal disorder.Comment: 4 pages, 3 figures; Accepted in PR

Computational study of coronoid carbazole based Macrocycles: influence of isomerism.

Carbazole (Cz) units have been recognized as crucial conjugated cores in organic electronics due to their good electro- and photoactive properties, such as high hole-transporting mobilities, when compared to other heterocycles. On the other hand, conjugated macrocycles should be useful building blocks for the construction of 2D porous surface networks or 3D inclusion complexes among other supramolecular structures.2 One of the most interesting features of conjugated cyclic oligomers is that their electronic, structural, and optical properties can be tuned as a function of their interior and exterior domains. Therefore, a systematic study of conjugated macrocycles with well-defined diameters is of crucial importance to establish the structure-property relationships of these materials. For that purpose, we carried out a purely theoretical study of coronoid molecules based on three different indolocarbazoles (ICz) structural isomers (see Figure 1) as indolo[2,3-a]carbazole (23a-4MC), indolo[2,3-b]carbazole (23b-4MC) and indolo[3,2-b]carbazole (32b-4MC), which contain four indolecarbazole units (4MC). This work aims to identify new macrostructures with interesting electronic properties as well as to display the usefulness of the theoretical tools to advance knowledge in the organic electronics field. Overall, this investigation contributes to elucidating the electronic properties of coronoid macrocycles, guiding experimental chemists to produce new molecules with desirable properties.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

Platinum nanoparticles stabilized by N-heterocyclic thiones. Synthesis and catalytic activity in mono- and di-hydroboration of alkynes

N-Heterocyclic Thiones (NHT) proved to be efficient ligands for the stabilization of small platinum nanoparticles (1.3-1.7 nm), synthesized by decomposition of [Pt(dba)2], under a H2 atmosphere, in the presence of variable sub-stoichiometric amounts of the NHT. Full characterization by means of TEM, HR-TEM, NMR, ICP, TGA and XPS have been carried out, providing information about the nature of the metal nanoparticles and the interaction of the NHT ligands to the metal surface. Importantly, DFT calculations indicate that some NHT ligands interact with the metal through the C[double bond, length as m-dash]C double bond of the imidazole fragment in addition to the sulfur atom, thus providing additional stabilization to the nanoparticles. According to XPS, TGA and ICP techniques, the surface coverage by the ligand increases by decreasing the size of the substituents on the nitrogen atom. The platinum nanoparticles have been used as catalyst in the hydroboration of alkynes. The most active system is that with a less covered surface area lacking an interaction of the ligand by means of the C[double bond, length as m-dash]C double bond. This catalyst hydroborates alkynes with excellent selectivities towards the monoborylated anti-Markovnikov product (vinyl-boronate) when one equiv. of borane is used. Very interestingly, aliphatic alkynes undergo a second hydroborylation process leading to the corresponding 1,1- and 1,2-diboroylated species with good selectivities towards the former.España MINECO (Projects CTQ2016-76267-P, CTQ2016-80814-R and CTQ2016- 81797-REDC)España Junta de Andalucía Project FQM-212