Investigation of the effect of microstructural changes on thermal transport in semicrystalline polymer semiconductors

Great progress in the development of new semiconducting polymers over the last two decades alongside improved understanding of electron transport mechanisms have resulted in a dramatic increase in the electron mobility of these materials making them promising candidates for electronic and thermoelectric applications. Heat transport phenomena, on the other hand—which govern thermal conductivity—have not received as much attention up to date. In spite of the simplicity of the principle behind the measurement of thermoelectric properties, the combined uncertainty in thermoelectric figure of merit zT could easily reach 50% with the largest uncertainty coming from thermal conductivity measurements. Such a high measurement uncertainty, often comparable to relative variations in zT encountered when optimizing within a given class of materials, prevents the study of structure-thermal property relationships. Here we present a protocol for the measurement of the thermal conductivity of thin films with reduced measurement uncertainty, which allowed us to investigate the effect of microstructural changes on the thermal conductivity of the conjugated polymer P(NDI2OD-T2). We show that the enhancement of the thermal conductivity upon annealing is much less pronounced than the corresponding increase in the electron mobility that has been reported under the same annealing conditions in the literature. This suggests that semicrystalline conjugated polymers in which thermal transport remains limited by the amorphous domain boundaries in between crystalline grains could be a suitable system for realizing the electron-crystal phonon glass concept and enable higher performance thermoelectric materials.</jats:p

Sampling uncertainty in gridded sea surface temperature products and Advanced Very High Resolution Radiometer (AVHRR) Global Area Coverage (GAC) data

Sea surface temperature (SST) data are often provided as gridded products, typically at resolutions of order 0.05 degrees from satellite observations to reduce data volume at the request of data users and facilitate comparison against other products or models. Sampling uncertainty is introduced in gridded products where the full surface area of the ocean within a grid cell cannot be fully observed because of cloud cover. In this paper we parameterise uncertainties in SST as a function of the percentage of clear-sky pixels available and the SST variability in that subsample. This parameterisation is developed from Advanced Along Track Scanning Radiometer (AATSR) data, but is applicable to all gridded L3U SST products at resolutions of 0.05-0.1 degrees, irrespective of instrument and retrieval algorithm, provided that instrument noise propagated into the SST is accounted for. We also calculate the sampling uncertainty of ~0.04 K in Global Area Coverage (GAC) Advanced Very High Resolution Radiometer (AVHRR) products, using related methods

An Introduction to Statistical Issues and Methods in Metrology for Physical Science and Engineering

This article provides an overview of the interplay between statistics and measurement. Measurement quality affects inference from data collected and analyzed using statistical methods while appropriate data analysis quantifies the quality of measurements. This article brings material on statistics and measurement together in one place as a resource for practitioners. Both frequentist and Bayesian methods are discussed

Experimental assessment of pre-turbo aftertreatment configurations in a single stage turbocharged diesel engine. Part 1: Steady-state operation

Diesel oxidation catalysts and diesel particulate filters are standard aftertreatment systems in Diesel engines which are traditionally placed downstream of the turbine. However, pre-turbo aftertreatment configurations are being approached as a way to improve the aftertreatment performance in terms of light-off and passive regeneration. This exhaust line architecture can also benefit fuel economy. The objective of this work is to analyse experimentally how the pre-turbo aftertreatment placement impacts on the performance of a single stage turbocharged Diesel engine. The work has been divided into two parts focused on steady-state and transient engine operation separately. The first part comprises the analysis of the experimental results corresponding to steady-state operating conditions. The range of operation covers different engine loads and speeds. The engine response with pre-turbo aftertreatment placement is mainly affected by the change in the pumping work caused by the aftertreatment pressure drop reduction and its new location, which avoids the multiplicative effect of the turbine expansion ratio when setting the engine back-pressure. These effects become more significant as the engine load increases benefiting fuel consumption from low to high loads. Concerning aftertreatment performance, the results evidence noticeable benefits in DPF passive regeneration and CO/HC emissions reduction at low engine load.This work has been partially supported by the Vicerrectorado de Investigacion de la Universitat Politenica de Valencia through grant number SP20120340-UPPTE/2012/96 and by the Conselleria de Educacio, Cultura i Esport of the Generalitat Valenciana through grant number GV/2013/043.Luján, JM.; Bermúdez, V.; Piqueras, P.; García Afonso, Ó. (2015). Experimental assessment of pre-turbo aftertreatment configurations in a single stage turbocharged diesel engine. Part 1: Steady-state operation. Energy. 80:599-613. https://doi.org/10.1016/j.energy.2014.05.048S5996138

Surface wear of TiN coated nickel tool during the injection moulding of polymer micro Fresnel lenses

Limited tool life of nickel mould inserts represents an issue for the mass-production of polymer optics with complex micro three-dimensional geometries by injection moulding. TiN coating was applied to a nickel insert for the injection moulding of polycarbonate micro Fresnel lenses. Surface wear was monitored at different intervals during production on different tool locations. 3D micro optical dimensional microscopy, surface replica technique and SEM–EDS were employed to characterize wear of the micro features. Results showed wear decreasing at higher distance from the gate. After 24,500 moulding cycles the measured height reduction of 23μm high ribs was on the order of 400–1000nm

System Vicarious Calibration for Ocean Color Climate Change Applications: Requirements for In Situ Data

System Vicarious Calibration (SVC) ensures a relative radiometric calibration to satellite ocean color sensors that minimizes uncertainties in the water-leaving radiance Lw derived from the top of atmosphere radiance LT. This is achieved through the application of adjustment gain-factors, g-factors, to pre-launch absolute radiometric calibration coefficients of the satellite sensor corrected for temporal changes in radiometric sensitivity. The g-factors are determined by the ratio of simulated to measured spectral LT values where the former are computed using: i. highly accurate in situ Lw reference measurements; and ii. the same atmospheric model and algorithms applied for the atmospheric correction of satellite data. By analyzing basic relations between relative uncertainties of Lw and LT, and g-factors consistently determined for the same satellite missions using different in situ data sources, this work suggests that the creation of ocean color Climate Data Records (CDRs) should ideally rely on: i. one main long-term in situ calibration system (site and radiometry) established and sustained with the objective to maximize accuracy and precision over time of g-factors and thus minimize possible biases among satellite data products from different missions; and additionally ii. unique (i.e., standardized) atmospheric model and algorithms for atmospheric correction to maximize cross-mission consistency of data products at locations different from that supporting SVC. Finally, accounting for results from the study and elements already provided in literature, requirements and recommendations for SVC sites and field radiometers radiometric measurements are streamlined