Contaminación de suelos y aguas subterraneas por vertidos industriales

In the industrialised countries, soil and groundwater contamination caused by uncontrolled spills of industrial wastes is one of the most critical environmental problem, because its removal is expensive and difficult to carry out, and the effects persist during many years. In Spain this problem is especially notorious due to an inadequate management policy derived from the absence of coordination between the different involved sectors. The treatment installations are inot enough, so it has produced spillings in streams and soils or its storage in uncontrolled landfillings.The experiences and guidelines of the Environmental Protection Agency from United States have served to the industrialised countries to evaluate this kind of contamination. This methodology is based on its identification and delimitation in soil and groundwater. After the design of a monitoring and control program it can be established the correcting measures. For this reason it is important to know the transfer processes of pollutants between the saturated and not saturated medium, for this reason it is essential the use of geochemical and geophysical methods and their combination with hydrogeological methods.In Spain, this kind of studies is only carried out recently. A case history is the contamination of the alluvial aquifer of the Besos river (Barcelona) by Cr-VI and other heavy metals and organic microcontaminants

A detailed stream sediment Geochemical survey in the Canoves St. Pere de Vilamajor area (Montseny massif. NE Spain)

Se ha realizado una prospección geoquímica táctica de sedimentos aluviales en el Brea de Cánoves-St. Pere de Vilamajor (Macizo del Montseny, Barcelona), como consecuencia de una exploración geoquimica estratégica de sedimentos aluviales previa, en la que se localizó un Brea anómala en Pb, Zn, Cu, As, Cd, Ni, y Co. El Brea estudiada tiene 35 km2 y esta constituida por materiales sedimentarios y volcánicos del Paleozoica, metamorfizados en mayor o menor grado e intruidos por el granito de Vallfornés, y materiales detríticos terciarios. Las muestras, recogidas con una densidad de 7 por Km2 fueron, an alizadas mediante espectrofotometria de absorción atómica para el Pb, Zn, Cu, Ni, Co, As, Cd y Ag, con analisis adicionales para el Sn y W con fluorescencia de rayos X. La interpretación estadistica de los resultados mediante técnicas univariables y multivariables permitió localizar y delimitar los sectores mas anórnalos. Posteriores reconocimientos geológicos de detalle permitieron descubrir un nuevo tipo de mineralización estratiforme relacionado con los niveles volcano-sedimentarios del Ordovícico superior hasta el momento desconocido en las Cadenas Costero Catalanas, asi como sus removilizaciones debido al emplazamiento del granito de Vallfornés, que originaron mineralizaciones de tipo skarn y filonianas

Programa de cálculo de las constantes ópticas de materiales opacos en Fortran IV

Cuando se desea calcular las constantes ópticas n, k a partir de las medidas de reflectancia en aire y aceite de inmersión, es necesario manejar gran cantidad de datos experimentales, sobre todo si se pretende construir las curvas de dispersión de estas constantes desde los 400 nm a los 1.100 nm, efectuando series de 100 lecturas cada 10 nm. Para manejar esta gran cantidad de datos se propone el programa denominadaIRCA escrito en FORTRAN IV para utilizar con computadoras IBM modelos 1130 o 360

Proceso automático para la medida de las reflectancias. 1.- Descripción preliminar

To calculated the physical constant, n, k, from the reflectance measurements in two different media of known refractive indices, it is necessary to apply a stadistic criterion that represents to obtein a great numher of experimental data. The preliniinary description of the method used shows how et is simplified the calculation of the values of n, k, from the experimental data of reflectance

Dyonic Membranes

We present dyonic multi-membrane solutions of the N=2 D=8 supergravity theory that serves as the effective field theory of the $T^2$-compactified type II superstring theory. The `electric' charge is fractional for generic asymptotic values of an axion field, as for D=4 dyons. These membrane solutions are supersymmetric, saturate a Bogomolnyi bound, fill out orbits of an $Sl(2;\Z)$ subgroup of the type II D=8 T-duality group, and are non-singular when considered as solutions of $T^3$-compactified D=11 supergravity. On $K_3$ compactification to D=4, the conjectured type II/heterotic equivalence allows the $Sl(2;\Z)$ group to be reinterpreted as the S-duality group of the toroidally compactified heterotic string and the dyonic membranes wrapped around homology two-cycles of $K_3$ as S-duals of perturbative heterotic string states.Comment: Phyzzx. 27 pp. Additional para. added to introductio

Load assessment and analysis of impacts in multibody systems

The evaluation of contact forces during an impact requires the use of continuous force-based methods. An accurate prediction of the impact force demands the identification of the contact parameters on a case-by-case basis. In this paper, the preimpact effective kinetic energy (Formula presented.) is put forward as an indicator of the intensity of the impact force along the contact normal direction. This represents a part of the total kinetic energy of the system that is associated with the subspace of constrained motion defined by the impact constraints at the moment of contact onset. Its value depends only on the mechanical parameters and the configuration of the system. We illustrate in this paper that this indicator can be used to characterize the impact force intensity. The suitability of this indicator is confirmed by numerical simulations and experimentsPostprint (author's final draft

Steric and Electronic Effects on the Structure and Photophysical Properties of Hg(II) Complexes

Since many factors influence the coordination around a metal center, steric and electronic effects of the ligands mainly determine the connectivity and, thus, the final arrangement. This is emphasized on Hg(II) centers, which have a zero point stabilization energy and, thus, a flexible coordination environment. Therefore, the unrestricted Hg(II) geometry facilitates the predominance of the ligands during the structural inception. Herein, we synthesized and characterized a series of six Hg(II) complexes with general formula (Hg(Pip)2(dPy)) (Pip = piperonylate, dPy = 3- phenylpyridine (3-phpy) (1), 4-phenylpyridine (4-phpy) (2), 2,2′- bipyridine (2,2′-bipy) (3), 1,10-phenanthroline (1,10-phen) (4), 2,2′:6′,2′-terpyridine (terpy) (5), or di(2-picolyl)amine (dpa) (6)). The elucidation of their crystal structures revealed the arrangement of three monomers (3, 5, and 6), one dimer (4), and two coordination polymers (1 and 2) depending on the steric requirements of the dPy and predominance of the ligands. Besides, the study of their photophysical properties in solution supported by TD-DFT calculations enabled us to understand their electronic effects and the influence of the structural arrangement on them

Axisymmetric core collapse simulations using characteristic numerical relativity

We present results from axisymmetric stellar core collapse simulations in general relativity. Our hydrodynamics code has proved robust and accurate enough to allow for a detailed analysis of the global dynamics of the collapse. Contrary to traditional approaches based on the 3+1 formulation of the gravitational field equations, our framework uses a foliation based on a family of outgoing light cones, emanating from a regular center, and terminating at future null infinity. Such a coordinate system is well adapted to the study of interesting dynamical spacetimes in relativistic astrophysics such as stellar core collapse and neutron star formation. Perhaps most importantly this procedure allows for the unambiguous extraction of gravitational waves at future null infinity without any approximation, along with the commonly used quadrupole formalism for the gravitational wave extraction. Our results concerning the gravitational wave signals show noticeable disagreement when those are extracted by computing the Bondi news at future null infinity on the one hand and by using the quadrupole formula on the other hand. We have strong indication that for our setup the quadrupole formula on the null cone does not lead to physical gravitational wave signals. The Bondi gravitational wave signals extracted at infinity show typical oscillation frequencies of about 0.5 kHz.Comment: 17 pages, 18 figures, submitted to Phys. Rev.

Gravitational lensing by p-branes

The scattering of R-R gauge bosons off of Dirichlet p-branes is computed to leading order in the string coupling. The results are qualitatively similar to those found in the scattering of massless NS-NS bosons: all p-branes with p >= 0 exhibit stringy properties, in particular the Regge behavior. Both the R-R and NS-NS scattering amplitudes agree in the limit of small momentum transfer with scattering off the extremal R-R charged p-brane solutions found in the low-energy supergravities. We interpret this as evidence that Dirichlet-branes are an exact world-sheet description of the extremal p-branes. The -1-brane (D-instanton) is a special object which, unlike all other Dirichlet-branes, exhibits point-like behavior. We find the R-R charged instanton solution to type IIB supergravity and confirm that the field theoretic scattering off of this solution miraculously reproduces the full stringy calculation. As an aside, we include a discussion of the entropy of non-extremal black holes in ten dimensions, produced by exciting the 0-brane. We show that, for large black holes, the entropy grows linearly with the black hole mass.Comment: LaTeX, 18 pages, 1 figure, uses psfig.sty, available from http://xxx.lanl.gov/ftp/hep-th/papers/macros/psfig.sty Final version to appear in Nuclear Physics

Equatorial circular orbits in the Kerr-de Sitter spacetimes

Equatorial motion of test particles in the Kerr-de Sitter spacetimes is considered. Circular orbits are determined, their properties are discussed for both the black-hole and naked-singularity spacetimes, and their relevance for thin accretion discs is established.Comment: 24 pages, 19 figures, REVTeX