473 research outputs found
4-Methyl-2,6-bis(phosphonomethyl)phenol dihydrate
The 4-methyl-2,6-bis(phosphomethyl)phenol molecule,
which crystallizes with two water molecules per asymmetric
unit, has approximate twofold symmetry and is
involved in extensive three-dimensional hydrogen bonding
in which every available OH group participates.
The principal dimensions include P--O 1.4981 (13)
and 1.5015 (14) ,~, four P--OH distances in the range
1.5395(14) to 1.5688(13) A, P--C 1.7857(17) and
1.7893 (17) ~k, and O...O intramolecular and intermolecular
hydro.gen-bond distances in the range 2.458 (2) to
2.866 (2) A
Cooling rate dependence of the antiferromagnetic domain structure of a single crystalline charge ordered manganite
The low temperature phase of single crystals of NdCaMnO
and GdCaMnO manganites is investigated by squid
magnetometry. NdCaMnO undergoes a charge-ordering
transition at =245K, and a long range CE-type antiferromagnetic state
is established at =145K. The dc-magnetization shows a cooling rate
dependence below , associated with a weak spontaneous moment. The
associated excess magnetization is related to uncompensated spins in the
CE-type antiferromagnetic structure, and to the presence in this state of
fully orbital ordered regions separated by orbital domain walls. The observed
cooling rate dependence is interpreted to be a consequence of the rearrangement
of the orbital domain state induced by the large structural changes occurring
upon cooling.Comment: REVTeX4; 7 pages, 4 figures. Revised 2001/12/0
Selective Spin-State Switch and Metal-Insulator Transition in \boldmath
Ultra-high resolution synchrotron diffraction data for
throw new light on the metal-insulator transition of Co Ba-cobaltites.
An anomalous expansion of CoO octahedra is observed at the phase transition
on heating, while CoO pyramids show the normal shrinking at the closing of
the gap. The insulator-to-metal transition is attributed to a sudden excitation
of some electrons in the octahedra ( state) into the Co band
(final state). The state in the pyramids does
not change and the structural study also rules out a
orbital ordering at .Comment: Phys. Rev. B (to appear
Spin, charge and orbital ordering in ferrimagnetic insulator YBaMnO
The oxygen-deficient (double) perovskite YBaMnO, containing
corner-linked MnO square pyramids, is found to exhibit ferrimagnetic
ordering in its ground state. In the present work we report
generalized-gradient-corrected, relativistic first-principles full-potential
density-functional calculations performed on YBaMnO in the nonmagnetic,
ferromagnetic and ferrimagnetic states. The charge, orbital and spin orderings
are explained with site-, angular momentum- and orbital-projected density of
states, charge-density plots, electronic structure and total energy studies.
YBaMnO is found to stabilize in a G-type ferrimagnetic state in
accordance with experimental results. The experimentally observed insulating
behavior appears only when we include ferrimagnetic ordering in our
calculation. We observed significant optical anisotropy in this material
originating from the combined effect of ferrimagnetic ordering and crystal
field splitting. In order to gain knowledge about the presence of different
valence states for Mn in YBaMnO we have calculated -edge x-ray
absorption near-edge spectra for the Mn and O atoms. The presence of the
different valence states for Mn is clearly established from the x-ray
absorption near-edge spectra, hyperfine field parameters and the magnetic
properties study. Among the experimentally proposed structures, the recently
reported description based on 4/ is found to represent the stable
structure
The MEGAPIE-TEST Project
The goals of the MEGAPIE initiative are to design, build and operate a 1MW heavy liquid metal target. The first step towards the realization of the MEGAPIE target was the feasibility studies, which outlined the entire project. Contextually to the feasibility studies the conceptual design phase started with the establishment of R&D working groups assisting the design and validation of both the target and its ancillary systems. In this framework the EU project MEGAPIE-TEST has been structured in three work packages with tasks concerning the finalization of the engineering design, the components and subsystem testing, the integral test and the first irradiation period. The MEGAPIE-TEST consortium is composed by the 14 partners: FZK, PSI, CEA, ENEA, SCK-CEN, CNRS /IDFE, IN2P3, LMPGM, EMN, ISMRA, UNIV-NANTES, U-PSUDXI, USTL. Currently the engineering design of the target has been finalized, its manufacturing has been launched and the design activities on the ancillary systems were almost completed. R&D activities in the fields of materials, thermal â hydraulics, structural mechanics, neutronic and nuclear assessment and liquid metal technologies were performed in order to assist specific design issues. Some Subsystem and component tests were also performed and the preparation of the integral test is an ongoing activity
Orbital ordering in the manganites: resonant x-ray scattering predictions at the manganese LII and LIII edges
It is proposed that the observation of orbital ordering in manganite materials should be possible at the L II and L III edges of manganese using x-ray resonant scattering. If performed, dipole selection rules would make the measurements much more direct than the disputed observations at the manganese K edge. They would yield specific information about the type and mechanism of the ordering not available at the K edge, as well as permitting the effects of orbital ordering and Jahn-Teller ordering to be detected and distinguished from one another. Predictions are presented based on atomic multiplet calculations, indicating distinctive dependence on energy, as well as on polarization and on the azimuthal angle around the scattering vector
Last Call for RHIC Predictions
This paper contains the individual contributions of all speakers of the
session on 'Last Call for RHIC Predictions' at Quark Matter 99, and a summary
by the convenor.Comment: 56 pages, psfig, epsf, epsfig, graphicx style files required,
Proceedings of the XIV Int. Conf. on Nucleus-Nucleus Collisions, Quark Matter
99, Torino, Italy, May 10 - 15, 1999. Typographical mistakes corrected and
figure numbers change
Measurement of the gamma gamma -> pi+ pi- and gamma gamma -> K+ K- processes at energies of 2.4 - 4.1 GeV
We have measured pi+pi- and K+K- production in two-photon collisions using
87.7 /fb of data collected with the Belle detector at the asymmetric energy
e+e- collider KEKB. The cross sections are measured to high precision in the
two-photon center-of-mass energy (W) range between 2.4 GeV < W < 4.1 GeV and
angular region |cos theta^{*}| < 0.6. The cross section ratio
sigma(gammagamma->K+K-)/sigma(gammagamma->pi+pi-) is measured to be 0.89 +-
0.04(stat) +- 0.15(syst) in the range of 3.0 GeV < W < 4.1 GeV, where the ratio
is energy independent. We observe a sin^{-4} theta^{*} behavior of the cross
section in the same W range. Production of chi_{c0} and chi_{c2} mesons is
observed in both gammagamma -> pi+pi- and gammagamma -> K+K- modes.Comment: 17 pages, 5 figures, submitted to Phys. Lett. B, errors relative to
the two-photon decay width correcte
Large enhancement of deuteron polarization with frequency modulated microwaves
We report a large enhancement of 1.7 in deuteron polarization up to values of
0.6 due to frequency modulation of the polarizing microwaves in a two liters
polarized target using the method of dynamic nuclear polarization. This target
was used during a deep inelastic polarized muon-deuteron scattering experiment
at CERN. Measurements of the electron paramagnetic resonance absorption spectra
show that frequency modulation gives rise to additional microwave absorption in
the spectral wings. Although these results are not understood theoretically,
they may provide a useful testing ground for the deeper understanding of
dynamic nuclear polarization.Comment: 10 pages, including the figures coming in uuencoded compressed tar
files in poltar.uu, which also brings cernart.sty and crna12.sty files neede
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