Algal culture studies for CELSS

Microalgae are well-suited as a component of a Closed Environmental Life Support System (CELSS), since they can couple the closely related functions of food production and atmospheric regeneration. The objective was to provide a basis for predicting the response of CELSS algal cultures, and thus the food supply and air regeneration system, to changes in the culture parameters. Scenedesmus growth was measured as a function of light intensity, and the spectral dependence of light absorption by the algae as well as algal respiration in the light were determined as a function of cell concentration. These results were used to test and confirm a mathematical model that describes the productivity of an algal culture in terms of the competing processes of photosynthesis and respiration. The relationship of algal productivity to cell concentration was determined at different carbon dioxide concentrations, temperatures, and light intensities. The maximum productivity achieved by an air-grown culture was found to be within 10% of the computed maximum productivity, indicating that CO2 was very efficiently removed from the gas stream by the algal culture. Measurements of biomass productivity as a function of cell concentration at different light intensities indicated that both the productivity and efficiency of light utilization were greater at higher light intensities

Influence of Precipitation Method on Acid-Base Catalyzed Reactions over Mg-Zr Mixed Oxides

To examine the promotional effect that zirconia has on magnesia in catalysis, mixed oxides were prepared by coprecipitation under controlled-pH conditions or rising-pH conditions. The resulting mixed oxides were characterized by using NH3 and CO2 adsorption microcalorimetry, X-ray diffraction, and scanning electron microscopy. The samples were also tested as catalysts for transesterification of tributyrin with methanol, coupling of acetone, and conversion of ethanol to ethene, ethanal, and butanol. Zirconia promoted the activity of MgO for both transesterification and acetone coupling reactions, presumably by exposing new acid–base pairs at the surface. During ethanol conversion, however, zirconia promoted the dehydration reactions. Characterization and reactivity results suggest that a Mg-Zr sample prepared by controlled-pH precipitation exposes more ZrO2 than a sample prepared by the rising-pH method

Oxidation state of iron in hydrous phono-tephritic melts

The oxidation state of iron in hydrous ultrapotassic (phono-tephritic) melts coexisting with mixed H2O-CO2 fluids was experimentally studied at 1200 and 1250{degree sign}C and pressures from 50 to 500 MPa. The oxygen fugacity (fO2) varied from NNO-2.9 to NNO+2.6 in logfO2, relative to the Ni-NiO oxygen buffer (NNO), as imposed by external redox conditions in experimental vessels and internal variations in water activity from 0.05 to 1 inside the capsules. The iron redox state of the quenched melts was determined by colorimetric wet-chemical analysis. This analytical method was optimized to measure the Fe2+/ΣFe ratio of mg-sized samples within ±0.03 (2σ). The accuracy and precision was tested with international reference materials and with standards analyzed by other methods. The Fe2+/ΣFe ratio of the experimental glasses covered a range of 0.41 to 0.85. A small negative effect of dissolved water on Fe2+/ΣFe at given fO2 was found, consistent with the thermodynamic model of Moretti (2005). No effect of pressure and temperature on the redox state of iron was resolvable in the investigated P-T range. Compared to hydrous ferrobasaltic melts that were studied previously under similar conditions, systematically lower Fe2+/ΣFe ratios were found for the phono-tephritic melts, in particular at low oxygen fugacities. This effect is attributed to the much higher K2O contents of the phono-tephrite (7.5 compared to 0.3 wt%), but the difference in ΣFeO (7.8 wt% in the phono-tephrite and 12.9 wt% in the ferrobasalt) may have an influence as well. Comparison of the experimentally obtained relationship between logfO2 and Fe3+/Fe2+ for the studied hydrous ultrapotassic melts with commonly used empirical and thermodynamic models suggest that these models can be successfully applied to phono-tephritc melts, although such compositions were not implemented in the model calibrations. Furthermore, the new data can be used to improve the models with respect to the effects of compositional variables, such as H2O or K2O, on the redox state of iron in silicate melts

Technical design and commissioning of the KATRIN large-volume air coil system

The KATRIN experiment is a next-generation direct neutrino mass experiment with a sensitivity of 0.2 eV (90% C.L.) to the effective mass of the electron neutrino. It measures the tritium $\beta$-decay spectrum close to its endpoint with a spectrometer based on the MAC-E filter technique. The $\beta$-decay electrons are guided by a magnetic field that operates in the mT range in the central spectrometer volume; it is fine-tuned by a large-volume air coil system surrounding the spectrometer vessel. The purpose of the system is to provide optimal transmission properties for signal electrons and to achieve efficient magnetic shielding against background. In this paper we describe the technical design of the air coil system, including its mechanical and electrical properties. We outline the importance of its versatile operation modes in background investigation and suppression techniques. We compare magnetic field measurements in the inner spectrometer volume during system commissioning with corresponding simulations, which allows to verify the system's functionality in fine-tuning the magnetic field configuration. This is of major importance for a successful neutrino mass measurement at KATRIN.Comment: 32 pages, 16 figure

Public transport capacity provision and its sensitivity to demand estimation

The selection of the appropriate transportation technology to satisfy travel demand has far reaching implications in terms of its ability to either effectively support economic growth and prosperity, or be a drain on public resources. In this regard, ensuring a high level of infrastructure productivity is of great importance. While the applicability of various transit technologies ranging from standard bus services to bus rapid transit and rapid rail transit is widely understood, the scalability of individual modes is an aspect that requires greater definition to ensure that a particular mode can have its capacity enhanced over a period of time in suitable increments that can conveniently and efficiently accommodate growth and fluctuations in demand. Rapid implementation of scalable infrastructure solutions is of particular importance in developing countries. This paper investigates: how scalable road-based transit systems are; how demand estimation accuracy effects the provision of transit capacity; and how much spare capacity should be provided. It is concluded that road-based modes are scalable within families of system configurations, and that in low growth scenarios the infrastructure productivity of high capacity modes is poor. It is argued that, while an accurate demand estimate is important from a revenue estimation perspective, demand accuracy from an infrastructure sizing perspective is less important, as the capacity of one component can be influenced by the capacity of others. It is contended that the amount of spare capacity provided at the outset, or at key upgrade points, depends upon the mode capacity configuration, its capacity increase increment size and the forecast rate of growth, not necessarily the ultimate demand.Paper presented at the 34th Annual Southern African Transport Conference 6-9 July 2015 "Working Together to Deliver - Sakha Sonke", CSIR International Convention Centre, Pretoria, South Africa.The Minister of Transport, South AfricaTransportation Research Board of the US

Chirp mitigation of plasma-accelerated beams using a modulated plasma density

Plasma-based accelerators offer the possibility to drive future compact light sources and high-energy physics applications. Achieving good beam quality, especially a small beam energy spread, is still one of the major challenges. For stable transport, the beam is located in the focusing region of the wakefield which covers only the slope of the accelerating field. This, however, imprints a longitudinal energy correlation (chirp) along the bunch. Here, we propose an alternating focusing scheme in the plasma to mitigate the development of this chirp and thus maintain a small energy spread

Neutrino and antineutrino charge-exchange reactions on 12C

We extend the formalism of weak interaction processes, obtaining new expressions for the transition rates, which greatly facilitate numerical calculations, both for neutrino-nucleus reactions and muon capture. Explicit violation of CVC hypothesis by the Coulomb field, as well as development of a sum rule approach for the inclusive cross sections have been worked out. We have done a thorough study of exclusive (ground state) properties of $^{12}$B and $^{12}$N within the projected quasiparticle random phase approximation (PQRPA). Good agreement with experimental data achieved in this way put in evidence the limitations of standard RPA and the QRPA models, which come from the inability of the RPA in opening the $p_{3/2}$ shell, and from the non-conservation of the number of particles in the QRPA. The inclusive neutrino/antineutrino ($\nu/\tilde{\nu}$) reactions $^{12}$C($\nu,e^-)^{12}$N and $^{12}$C($\tilde{\nu},e^+)^{12}$B are calculated within both the PQRPA, and the relativistic QRPA (RQRPA). It is found that the magnitudes of the resulting cross-sections: i) are close to the sum-rule limit at low energy, but significantly smaller than this limit at high energies both for $\nu$ and $\tilde{\nu}$, ii) they steadily increase when the size of the configuration space is augmented, and particulary for $\nu/\tilde{\nu}$ energies $> 200$ MeV, and iii) converge for sufficiently large configuration space and final state spin. The quasi-elastic $^{12}$C($\nu,\mu^-)^{12}$N cross section recently measured in the MiniBooNE experiment is briefly discussed. We study the decomposition of the inclusive cross-section based on the degree of forbiddenness of different multipoles. A few words are dedicated to the $\nu/\tilde{\nu}$-$^{12}$C charge-exchange reactions related with astrophysical applications.Comment: 21 pages, 13 figures, 1 table, submitted to Physical Review

Weak Long-Ranged Casimir Attraction in Colloidal Crystals

We investigate the influence of geometric confinement on the free energy of an idealized model for charge-stabilized colloidal suspensions. The mean-field Poisson-Boltzmann formulation for this system predicts pure repulsion among macroionic colloidal spheres. Fluctuations in the simple ions' distribution provide a mechanism for the macroions to attract each other at large separations. Although this Casimir interaction is long-ranged, it is too weak to influence colloidal crystals' dynamics.Comment: 5 pages 2 figures ReVTe