Enhanced shelf-life of the formulated biocontrol agent Bacillus amyloliquefaciens CPA-8 combining diverse packaging strategies and storage conditions

Two effective biocontrol products (named as BA3 and BA4) based on Bacillus amyloliquefaciens CPA-8 have been reported as a potential alternative to chemical applications against brown rot caused by Monilinia spp. on stone fruit. To have practical use, this study aimed to describe the best packaging strategies (bags or flasks, atmosphere, and temperature of storage) to not only guarantee efficacy but also stability and ease of application of the products to be handled through the normal channels of distribution and storage. In terms of the viability neither the BA3 nor the BA4 product has been compromised after twelve months of storage. However, storage at 4 °C affected the stability and visual aspect of both CPA-8 formulations, mainly associated not only to the increase of RH but also aw. Moreover, it should be pointed out that flasks did not conserve refrigerated BA3 samples in a suitable way, since RH and aw increased noticeably making their visual properties unsightly after 10 months of cold storage. At that time, the BA4 products were better preserved at 4 °C when packaged in flasks. Finally, this study also demonstrated that the most suitable packaging conditions for long-term storability (stored at 22 °C) did not show any negative effect in the biocontrol efficacy of CPA-8 in nectarines artificially infected with M. fructicola and provide suitable product delivery and field application. In conclusion, these results contribute to the final stage of development of these two CPA-8 products, practically ready for registration, thus contributing to the environmental-friendly management of postharvest diseases in stone fruit.info:eu-repo/semantics/acceptedVersio

Using radium isotopes to characterize water ages and coastal mixing rates: A sensitivity analysis

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W., 2006, PAPERS SUMMER UNDERG, P51 Taniguchi M, 2003, BIOGEOCHEMISTRY, V66, P35, DOI 10.1023/B:BIOG.0000006090.25949.8d Taylor J. R., 1997, INTRO ERROR ANAL, P160 Turner IL, 1997, J COASTAL RES, V13, P46 Weinstein Y., 2006, RADIOACT ENV, V8, P360, DOI DOI 10.1016/S1569-4860(05)08029-0 Windom HL, 2006, MAR CHEM, V102, P252, DOI 10.1016/j.marchem.2006.06.016 Knee, Karen L. Garcia-Solsona, Ester Garcia-Orellana, Jordi Boehm, Alexandria B. Paytan, Adina 4 AMER SOC LIMNOLOGY OCEANOGRAPHY WACO LIMNOL OCEANOGR-METHNumerous studies have used naturally occurring Ra isotopes (Ra-223, Ra-224, Ra-226, and Ra-228, with half-lives of 11.4 d, 3.7 d, 1600 y, and 5.8 y, respectively) to quantify water mass ages, coastal ocean mixing rates, and submarine groundwater discharge (SGD). 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Uncertainties in eddy diffusion coefficients estimated based on cross-shore gradients in short-lived Ra isotope activity were greater when fewer points were used to determine the linear trend, when the coefficient of determination (R-2) was low, and when Ra-224, rather than Ra-223, was used. By exploring the uncertainties associated with Ra-derived water ages and eddy diffusion coefficients, this study will enable researchers to apply these methods more effectively and to reduce uncertainty

Optimizing both catalyst preparation and catalytic behaviour for the oxidative dehydrogenation of ethane of Ni-Sn-O catalysts

[EN] Bulk Ni-Sn-O catalysts have been synthesized, tested in the oxidative dehydrogenation of ethane and characterized by several physicochemical techniques. The catalysts have been prepared by evaporation of the corresponding salts using several additives in the synthesis gel, i.e. ammonium hydroxide, nitric acid, glyoxylic acid or oxalic acid, in the synthesis gel. The catalysts were finally calcined at 500 degrees C in air. Important changes in the catalytic behaviour have been observed depending on the additive. In fact, an important improvement in the catalytic performance is observed especially when some additives, such as glyoxylic or oxalic acid, are used. Thus the productivity to ethylene multiplies by 6 compared to the reference Ni-Sn-O catalyst if appropriate templates are used, and this is the result of an improvement in both the catalytic activity and the selectivity to ethylene. This improved performance has been explained in terms of the decrease of the crystallite size (and the increase in the surface area of catalyst) as well as the modification of the lattice parameter of nickel oxide.The authors would like to acknowledge the DGICYT in Spain (CTQ2015-68951-C3-1-R and CTQ2012-37925-C03-2) for financial support. We also thank the University of Valencia and SCSIE-UV for assistanceSolsona Espriu, BE.; López Nieto, JM.; Agouram, S.; Soriano Rodríguez, MD.; Dejoz, A.; Vázquez, MI.; Concepción Heydorn, P. (2016). Optimizing both catalyst preparation and catalytic behaviour for the oxidative dehydrogenation of ethane of Ni-Sn-O catalysts. Topics in Catalysis. 59(17-18):1564-1572. https://doi.org/10.1007/s11244-016-0674-zS156415725917-18Heracleous E, Lee AF, Wilson K, Lemonidou AA (2005) J Catal 231:159–171Heracleous E, Lemonidou AA (2006) J Catal 237:162–174Savova B, Loridant S, Filkova D, Millet JMM (2010) Appl Catal A 390:148–157Heracleous E, Lemonidou AA (2010) J Catal 270:67–75Solsona B, Nieto JML, Concepcion P, Dejoz A, Ivars F, Vazquez MI (2011) J Catal 280:28–39Skoufa Z, Heracleous E, Lemonidou AA (2012) Catal Today 192:169–176Zhu H, Ould-Chikh S, Anjum DH, Sun M, Biausque G, Basset JM, Caps V (2012) J Catal 285:292–303Skoufa Z, Heracleous E, Lemonidou AA (2012) Chem Eng Sci 84:48–56Zhu H, Rosenfeld DC, Anjum DH, Caps V, Basset JM (2015) ChemSusChem 8:1254–1263Heracleous E, Lemonidou AA (2015) J Catal 322:118–129Solsona B, Concepcion P, Demicol B, Hernandez S, Delgado JJ, Calvino JJ, Nieto JML (2012) J Catal 295:104–114Nieto JML, Solsona B, Grasselli RK, Concepción P (2014) Top Catal 57:1248–1255Popescu I, Skoufa Z, Heracleous E, Lemonidou AA, Marcu IC (2015) PCCP 17:8138–8147Zhang X, Gong Y, Yu G, Xie Y (2002) J Mol Catal A 180:293–298Popescu I, Skoufa Z, Heracleous E, Lemonidou A, Marcu I-C (2015) Phys Chem Chem Phys 17:8138–8147Nakamura KI, Miyake T, Konishi T, Suzuki T (2006) J Mol Catal A 260:144–151Solsona B, Dejoz AM, Vazquez MI, Ivars F, Nieto JML (2009) Top Catal 52:751–757Bortolozzi JP, Gutierrez LB, Ulla MA (2013) Appl Catal A 452:179–188Takeguchi T, Furukawa S, Inoue M (2001) J Catal 202:14–24Richardson JT, Turk B, Twigg MV (1996) Appl Catal 148:97–112Biju V, Khadar MA (2002) J Nanopart Res 4:247–253Van Veenendaal MA, Sawatzky GA (1993) Phys Rev Lett 70:2459–2462Vedrine JC, Hollinger G, Duc TM (1978) J Phys Chem 82:1515–1520Salagre P, Fierro JLG, Medina F, Sueiras JE (1996) J Mol Catal A 106:125–13

Groundwater and nutrient discharge through karstic coastal springs (Castelló, Spain)

Altres ajuts: Support from the Fulbright Commission for a post-doctoral fellowship to J.G-O. (ref 2007-0516) is gratefully acknowledged. Support for the research of PM was received through the prize ICREA Academia, funded by the Generalitat de Catalunya.Discharge of groundwater and associated chemical compounds into coastal karstic regions, which are abundant in the Mediterranean basin, is envisaged to be significant. In this study, we evaluate the groundwater discharge and its nutrient load to the open karstic site of Badum (Castelló, East Spain). Salinity profiles evidenced that groundwater discharge from coastal brackish springs causes a buoyant fresher layer, as identified with thermal infrared images. Chemical tracers (radium isotopes, dissolved inorganic silicate and seawater major elements) have been used to determine a brackish groundwater proportion in coastal waters of 36% in October 2006 and 44% in June 2007. Based on a radium-derived residence time of 2.7 days in October 2006 and 2.0 days in June 2007, total SGD fluxes have been estimated in 71 500 and 187 000m³ d⁻¹, respectively, with fresh-SGD contributions representing 71% and 85%. The calculated SGD-associated nutrient fluxes, most likely of natural origin, were 1500 and 8300 μmolm⁻² d⁻¹ of DIN and 19 and 40 μmolm⁻² d⁻¹ of DIP in October 2006 and June 2007, respectively. These inputs may actually lead to or enhance P limitation, thereby altering the structure of biological communities in the area

Coparentalitat i custòdia compartida a Catalunya

L’article aborda la problemàtica de la custòdia compartida legal dels fills menors d’edat en el postdivorci dins d’un context de creixent diversitat de les pràctiques parentals. S’hi presenta el marc sociojurídic actual existent a Espanya i a Catalunya entorn de la figura jurídica i la pràctica de la custòdia compartida. A més, s’hi analitzen les dades de sentències judicials de nul·litats, separacions i divorcis en referència al període 2007-2012 procedents de l’INE sobre Catalunya i uns altres territoris de l’Estat espanyol. En els resultats, hi destaca l’especificitat de Catalunya en el context de l’Estat espanyol, amb nivells més alts de divorci, consens entre els cònjuges i custòdia compartida. Concloem que el formidable increment de la custòdia compartida es podria explicar per l’adaptació de la pràctica judicial a nous models de coparentalitat en el predivorci. S’hi planteja la necessitat d’avançar en la recerca qualitativa per conèixer l’impacte real de la custòdia compartida en la vida quotidiana dels nens i els seus progenitors, perquè interpretem que, en la pràctica, aquesta figura jurídica conté i amaga acords ben diversos i crea escenaris molt complexos en el postdivorci.</p

Relationship between bulk phase, near surface and outermost atomic layer of VPO catalysts and their catalytic performance in the oxidative dehydrogenation of ethane

A set of vanadium phosphorous oxide (VPO) catalysts, mainly consisting of (VO)₂P₂O₇, VO(PO₃)₂ or VOPO₄∙2H₂O bulk crystalline phases, has been investigated for the oxidative dehydrogenation (ODH) of ethane to ethylene, a key potential reaction for a sustainable industrial and socioeconomic development. The catalytic performance on these VPO catalysts has been explained on the basis of the main crystalline phases and the corresponding suface features found by XPS and LEISS at 400 ˚C, i.e. within the temperature range used for ODH reaction. The catalysts based on (VO)₂P₂O₇ phase presented the highest catalytic activity and productivity to ethylene. Nevertheless, the catalysts consisting of VO(PO₃)₂ structure showed higher selectivity to ethylene, reaching 90% selectivity at ca. 10% ethane conversion. To the best of our knowledge, this is the highest selectivity reported on a vanadium phosphorous oxide at similar conversions for the ethane ODH. In general, catalysts consisting of crystalline phases with vanadium present as V⁴⁺, i.e. (VO)₂P₂O₇ and VO(PO₃)₂, were found to be significantly more selective to ethylene than those containing V⁵⁺ phases. The surface analysis by XPS showed an inverse correlation between the mean oxidation state of vanadium near surface and the selectivity to ethylene. The lower averaged oxidation states of vanadium appear to be favoured by the presence of V³⁺ species near the surface, which was only found in the catalysts containing V⁴⁺ phases. Among those catalysts the one based on VO(PO₃)₂ phase shows the highest selectivity, which could be related to the most isolated scenario of V species (the lowest V content relative to P) found at the outermost surface by low energy ion scattering spectroscopy (LEISS), a "true" surface technique only sensitive to the outermost atomic layer

Submarine groundwater discharge: A significant source of dissolved trace metals to the North Western Mediterranean Sea

Versión del edito

Support effects on NiO-based catalysts for the oxidative dehydrogenation (ODH) of ethane

[EN] We report on the effect of NiO-support interactions on the chemical nature of Ni species in a series of supported NiO catalysts for the ODH of ethane. SiO2, TiO2-anatase, a high surface area TiO2 and a porous clay hetero-structure (PCH) with TiO2 and SiO2 pillars were used as supports, which led to a selectivity to ethylene in the range 30-90% over supported NiO catalysts. The catalysts were characterized by means of XRD, N-2-Adsorption, H-2-TPR, XPS and in situ (under H-2 reductive atmosphere) and ex situ XAS spectroscopy. The catalytic performance of supported materials is discussed in terms of their reducibility and specific reduction kinetics, but also taking into account the specific chemical nature of Ni species on each catalyst. The influence of the particle size and the presence of Ni and O vacancies on the catalytic performance in the ODH of ethane is inferred.Authors would like to thank the DGICYT in Spain CTQ2015-68951-C3-1-R, CTQ2015-68951-C3-3-R, CTQ2012-37925-C03-2 and ENE2017-88818-C2-1-R. Also authors want to acknowledge the ALBA Synchrotron Light Source (Project ID: 2015021258 at CLAESS beamline). Authors from ITQ thank Project SEV-2016-0683 for financial support. D. D. also thanks MINECO and Severo Ochoa Excellence Program for his fellowship (SVP-2014-068669). Authors from UV thank the University of Valencia (UV-INV-AE16-484416 project) and MINECO (MAT2017-84118-C2-1-R project) for funding.Delgado-Muñoz, D.; Sanchís, R.; Cecilia, JA.; Rodríguez-Castellón, E.; Caballero, A.; Solsona, B.; López Nieto, JM. (2019). Support effects on NiO-based catalysts for the oxidative dehydrogenation (ODH) of ethane. Catalysis Today. 333:10-16. https://doi.org/10.1016/j.cattod.2018.07.010S101633