Thermal Stability of Self-Assembled Monolayers of n-Hexanethiol on Au(111)-(1 × 1) and Au(001)-(1 × 1)

Thermal desorption in an ultrahigh vacuum of n-hexanethiol (C6T) self-assembled monolayers (SAMs) prepared from ethanolic solutions on Au(111) and Au(001) unreconstructed surfaces was investigated by X-ray photoelectron spectroscopy. The SAMs desorption was performed from room temperature (RT) to 380 K. We report that the hexanethiolate surface saturation coverage is bigger (∼0.4 ML) for the SAM on Au(001) than on Au(111) (∼0.33 ML). We identified a greater stability for C6T SAMs on Au(001). Large amounts of physisorbed species were found on preferred oriented (111) polycrystalline Au at the low coverage regime at RT, while the SAM on the Au(001) single crystal at this conditions desorbs at a steady pace. At 340 K, both SAMs remain stable at the coverage expected for the lying-down phases that maximizes the van der Waals interactions. We observe that at higher temperatures the carbon alpha-sulfur bond breaks, producing free S on both gold surfaces.Fil: Cristina, Lucila Josefina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; ArgentinaFil: Ruano Sandoval, Gustavo Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; ArgentinaFil: Salvarezza, Roberto Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Ferron, Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Física del Litoral. Universidad Nacional del Litoral. Instituto de Física del Litoral; Argentina. Universidad Nacional del Litoral. Facultad de Ingeniería Química. Departamento de Materiales; Argentin

Preface to the special section on algorithms and architectures for real-time control

Rapid developments in microelectronics and computer science continue to fuel opportunities for real-time control engineers. These openings arise from drivers such as ever-increasing system complexity and sophistication, environmental legislation, economic competition, safety and reliability. These are typical of the themes that were highlighted at the IFAC Workshop on Algorithms and Architectures for Real-Time Control (AARTC '97)

Prevalence of dietary supplement use by gym members in Portugal and associated factors

Background Although there seems to be an increasing interest in the use of dietary supplements in those who exercise recreationally and want to improve body composition, there is little published data regarding gym users and dietary supplement use. Methods This cross-sectional study describes the prevalence and type of supplements used by gyms members, the reasons for using them and the information source using a self-administered online questionnaire. Results Of the 459 participants (301 females) who answered the survey, 43.8% reported using dietary supplements. Users were more likely men (62.7% vs. 33.9%, p 70%) of participants declared being well or very well informed about supplements, while only a minority (4%) felt very poorly or poorly informed. Most individuals purchased dietary supplements from the internet (56.2%) and supplement/health food stores (43.4%). Conclusion This study concluded that gyms users are large consumers of dietary supplements, and are more likely to be men, young, use protein powders, aiming to increase muscle mass, obtain information from registered dietitians, consider themselves well informed and buy supplements online

The Permeation mechanism of cisplatin through a dioleoylphosphocholine bilayer

The investigation of the intermolecular interactions between platinum-based anticancer drugs and lipid bilayers is of special relevance to unveil the mechanisms involved in different steps of the anticancer mode of action of these drugs. We have simulated the permeation of cisplatin through a model membrane composed of 1,2-dioleoyl-sn-glycero-3-phosphocholine lipids by means of umbrella sampling classical molecular dynamics simulations. The initial physisorption of cisplatin into the polar region of the lipid membrane is controlled, in a first moment, by long-range electrostatic interactions with the choline groups and, in a second step, by long-range electrostatic and hydrogen bond interactions with the phosphate groups. The second half of the permeation pathway, in which cisplatin diffuses through the nonpolar region of the bilayer, is characterized by the drop of the interactions with the polar heads and the rise of attractive interactions with the non-polar tails, which are dominated by van der Waals contributions

Decoding of Matrix-Product Codes

We propose a decoding algorithm for the $(u\mid u+v)$-construction that decodes up to half of the minimum distance of the linear code. We extend this algorithm for a class of matrix-product codes in two different ways. In some cases, one can decode beyond the error correction capability of the code

DNA barcoding of Iberian Peninsula and North Africa Tawny Owls Strix aluco suggests the Strait of Gibraltar as an important barrier for phylogeography

Eight subspecies have been proposed within the Tawny Owl (Strix aluco) species. However, recent molecular data have challenged this view, encouraging further work in this species complex. Here we reevaluated the taxonomic status between the North-Western African Tawny Owl, S. a. mauritanica, and its closest Iberian Tawny Owl population (from the S. a. sylvatica to S. a. aluco clade) separated by the Strait of Gibraltar. The Tawny Owl is a non-migratory and territorial species, and juvenile dispersal is restricted to a few kilometers around the natal site. This limited dispersal and the barrier imposed by the Strait of Gibraltar predicted a strong differentiation between the two populations. We tested this using DNA barcoding, Bayesian phylogenetic and species delimitation analysis. We found that an 81.1% of variation is due to the intergroups variation. In addition, the inter-intraspecific distances distribution revealed a barcoding gap among the two subspecies. Also, posterior probabilities and the PAB value allowed to reject the hypothesis that observed degree of distinctiveness is due to random coalescence processes. These findings clearly support the Strait of Gibraltar as an isolating barrier for this species. The subspecific status is confirmed and species status is even suggested for S. a. mauritanica.Peer reviewe

An advanced control strategy for biological nutrient removal in continuous systems based on pH and ORP sensors

[EN] A fuzzy logic-based control system that uses low-cost sensors for controlling and optimizing the biological nitrogen removal in continuous systems has been developed. The novelty of this control system is the use of several pH, ORP, and dissolved oxygen (DO) sensors instead of on-line nitrogen sensors/analyzers. The nitrogen control system was developed and implemented in a UCT pilot plant fed with wastewater from a full-scale plant. The developed nitrification controller allows the effluent ammonium concentration to be maintained below the effluent criteria discharge with the minimum energy consumption. The denitrification process controller allows the energy consumption derived from pumping to be minimized, as the control system only increases the internal recycle flow rate when the anoxic reactor reveals further capacity for denitrification. This advanced control strategy offers an attractive alternative to on-line, nitrogen analyzer-based control systems since it involves lower investment, maintenance, and operational costs that are derived from the instrumentation. (C) 2011 Elsevier B.V. All rights reserved.The authors would like to express their gratitude to the Ministry of Science and Education for the financial support (Project reference CTM2005-06919-C03-01/TECNO). Financial support from Entitat Publica de Sanejament d'Aigues Residuals de la Comunitat Valenciana and Depuracion de Aguas del Mediterraneo is also gratefully acknowledged.Ruano, MV.; Ribes, J.; Seco Torrecillas, A.; Ferrer, J. (2012). An advanced control strategy for biological nutrient removal in continuous systems based on pH and ORP sensors. Chemical Engineering Journal. 183:212-221. https://doi.org/10.1016/j.cej.2011.12.064S21222118

An improved sampling strategy based on trajectory design for application of the Morris method to systems with many input factors

[EN] In this paper, a revised version of the Morris approach, which includes an improved sampling strategy based on trajectory design, has been adapted to the screening of the most influential parameters of a fuzzy controller applied to WWTPs. Due to the high number of parameters, a systematic approach has been proposed to apply this improved sampling strategy with low computational demand. In order to find out the proper repetition number of elementary effects of each input factor on model output (EEi) calculations, an iterative and automatic procedure has been applied. The results show that the sampling strategy has a significant effect on the parameter significance ranking and that random sampling could lead to a non-proper coverage of the parameter space. (C) 2012 Elsevier Ltd. All rights reserved.This research study has been supported by the Spanish Research Foundation (CICYT Project reference CTM2005-06919-C03-01/TECNO), which is gratefully acknowledged.Ruano García, MV.; Ribes, J.; Seco Torrecillas, A.; Ferrer, J. (2012). An improved sampling strategy based on trajectory design for application of the Morris method to systems with many input factors. Environmental Modelling & Software. 37:103-109. https://doi.org/10.1016/j.envsoft.2012.03.008S1031093

Global sensitivity analysis of a filtration model for submerged anaerobic membrane bioreactors (AnMBR)

The results of a global sensitivity analysis of a filtration model for submerged anaerobic MBRs (AnMBRs) are assessed in this paper. This study aimed to (1) identify the less- (or non-) influential factors of the model in order to facilitate model calibration and (2) validate the modelling approach (i.e. to determine the need for each of the proposed factors to be included in the model). The sensitivity analysis was conducted using a revised version of the Morris screening method. The dynamic simulations were conducted using long-term data obtained from an AnMBR plant fitted with industrial-scale hollow-fibre membranes. Of the 14 factors in the model, six were identified as influential, i.e. those calibrated using off-line protocols. A dynamic calibration (based on optimisation algorithms) of these influential factors was conducted. The resulting estimated model factors accurately predicted membrane performance.This research work has been supported by the Spanish Ministry of Economy and Competitiveness (MINECO, Projects CTM2011-28595-C02-01/02) jointly with the European Regional Development Fund (ERDF) which are gratefully acknowledged.Robles Martínez, Á.; Ruano García, MV.; Ribes Bertomeu, J.; Seco Torrecillas, A.; Ferrer, J. (2014). Global sensitivity analysis of a filtration model for submerged anaerobic membrane bioreactors (AnMBR). Bioresource Technology. 158:365-376. https://doi.org/10.1016/j.biortech.2014.02.087S36537615