XV.?On the decomposition-products of quinine

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PHL 5038: a spatially resolved white dwarf + brown dwarf binary

A near-infrared excess is detected at the white dwarf PHL 5038 in UKIDSS photometry, consistent with the presence of a cool, substellar companion. We have obtained H- and K-grism spectra and images of PHL 5038 using NIRI on Gemini North. The target is spatially and spectrally resolved into two components: an 8000 K DA white dwarf, and a likely L8 brown dwarf companion, separated by 0.94\arcsec. The spectral type of the secondary was determined using standard spectral indices for late L and T dwarfs. The projected orbital separation of the binary is 55 AU, so it becomes only the second known wide WD+dL binary to be found after GD 165AB. This object could potentially be used as a benchmark for testing substellar evolutionary models at intermediate to older ages

Parameterization of sea-salt optical properties and physics of the associated radiative forcing

The optical properties of sea-salt aerosol have been parameterized at shortwave and longwave wavelengths. The optical properties were parameterized in a simple functional form in terms of the ambient relative humidity based on Mie optical property calculations. The proposed parameterization is tested relative to Mie calculations and is found to be accurate to within a few percent. In the parameterization, the effects of the size distribution on the optical properties are accounted for in terms of effective radius of the sea-salt size distribution. This parameterization differs from previous works by being formulated directly with the wet sea-salt size distribution and, to our knowledge, this is the first published sea-salt parameterization to provide a parameterization for both shortwave and longwave wavelengths. <br><br> We have used this parameterization in a set of idealized 1-D radiative transfer calculations to investigate the sensitivity of various attributes of sea-salt forcing, including the dependency on sea-salt column loading, effective variance, solar angle, and surface albedo. From these sensitivity tests, it is found that sea-salt forcings for both shortwave and longwave spectra are linearly related to the sea-salt loading for realistic values of loadings. The radiative forcing results illustrate that the shortwave forcing is an order of magnitude greater than the longwave forcing results and opposite in sign, for various loadings. Forcing sensitivity studies show that the influence of effective variance for sea-salt is minor; therefore, only one value of effective variance is used in the parameterization. The dependence of sea-salt forcing with solar zenith angle illustrates an interesting result that sea-salt can generate a positive top-of-the-atmosphere result (i.e. warming) when the solar zenith angle is relatively small (i.e. <30°). Finally, it is found that the surface albedo significantly affects the shortwave radiative forcing, with the forcing diminishing to zero as the surface albedo tends to unity

Reverse graded relaxed buffers for high Ge content SiGe virtual substrates

An innovative approach is proposed for epitaxial growth of high Ge content, relaxed Si1−xGex buffer layers on a Si(001) substrate. The advantages of the technique are demonstrated by growing such structures via chemical vapor deposition and their characterization. Relaxed Ge is first grown on the substrate followed by the reverse grading approach to reach a final buffer composition of 0.78. The optimized buffer structure is only 2.8 µm thick and demonstrates a low surface threading dislocation density of 4×106 cm−2, with a surface roughness of 2.6 nm. The buffers demonstrate a relaxation of up to 107%

Representing time-dependent freezing behaviour in immersion mode ice nucleation

In order to understand the impact of ice formation in clouds, a quantitative understanding of ice nucleation is required, along with an accurate and efficient representation for use in cloud resolving models. Ice nucleation by atmospherically relevant particle types is complicated by interparticle variability in nucleating ability, as well as a stochastic, time-dependent, nature inherent to nucleation. Here we present a new and computationally efficient Framework for Reconciling Observable Stochastic Time-dependence (FROST) in immersion mode ice nucleation. This framework is underpinned by the finding that the temperature dependence of the nucleation-rate coefficient controls the residence-time and cooling-rate dependence of freezing. It is shown that this framework can be used to reconcile experimental data obtained on different timescales with different experimental systems, and it also provides a simple way of representing the complexities of ice nucleation in cloud resolving models. The routine testing and reporting of time-dependent behaviour in future experimental studies is recommended, along with the practice of presenting normalised data sets following the methods outlined here

X-ray Spectral Variability and Rapid Variability of the Soft X-ray Spectrum Seyfert 1 Galaxies Ark 564 and Ton S180

The bright, soft X-ray spectrum Seyfert 1 galaxies Ark 564 and Ton S180 were monitored for 35 days and 12 days with ASCA and RXTE (and EUVE for Ton S180). The short time scale (hours-days) variability patterns were very similar across energy bands, with no evidence of lags between any of the energy bands studied. The fractional variability amplitude was almost independent of energy band. It is difficult to simultaneously explain soft Seyferts stronger variability, softer spectra, and weaker energy-dependence of the variability relative to hard Seyferts. The soft and hard band light curves diverged on the longest time scales probed, consistent with the fluctuation power density spectra that showed relatively greater power on long time scales in the softest bands. The simplest explanation is that a relatively hard, rapidly-variable component dominates the total X-ray spectrum and a slowly-variable soft excess is present in the lowest energy channels of ASCA. Although it would be natural to identify the latter with an accretion disk and the former with a corona surrounding it, a standard thin disk could not get hot enough to radiate significantly in the ASCA band, and the observed variability time scales are much too short. The hard component may have a more complex shape than a pure power-law. The most rapid factor of 2 flares and dips occurred within ~1000 sec in Ark 564 and a bit more slowly in Ton S180. The speed of the luminosity changes rules out viscous or thermal processes and limits the size of the individual emission regions to <~15 Schwarzschild radii (and probably much less), that is, to either the inner disk or small regions in a corona

Vaping for weight control: Findings from a qualitative study

Introduction: Smokers have expressed concern about weight gain once they stop smoking and weight gain is a risk factor associated with smoking relapse. Nicotine in e-cigarettes, as well as vaping behaviour, may support smoking cessation by reducing weight gain. This study explored the factors that influence attitudes towards, and awareness of, e-cigarettes and weight control post smoking cessation. Methods: Qualitative study involving focus groups with adults in the UK (n = 58) who were either exclusive vapers or dual users. Results: There was limited awareness and/or inclination to vape to prevent weight gain after stopping smoking. Reasons for this centred on: the health gains of stopping smoking outweighing any potential weight gain; a lack of understanding of the appetite supressing effects of nicotine; a belief that vaping could not suppress appetite like a cigarette and could result in craving for certain flavours; concerns about the longer-term effects of e-cigarettes on health and the ethics of promoting vaping as way to support smoking cessation by limiting weight gain, especially for young women. Conclusion: Participants in this study do not appear inclined to use e-cigarettes to prevent weight gain after smoking cessation. There is a lack of understanding about why nicotine might help prevent weight gain and a concern that e-cigarette flavours could provoke cravings and that vaping may be unsafe in the long-term