Me, Myself, and Future Generations: The Role of Affinity and Effectiveness in the Creation of Consumer Environmental Stewardship (CENS)

Policymakers, consumer advocate groups, and researchers agree that consumers need to increase their proenvironmental behaviors if a decent standard of living is to be ensured for future generations. Despite high levels of environmental concern, consumers still refrain from large-scale adoption of proenvironmental behaviors. Social marketers agree that a change in attitudes is not enough to stimulate the necessary behavioral change and are looking for ways to help consumers overcome the costs (e.g., price premiums, inconvenience) that are often associated with proenvironmental behaviors. Currently, consumers often see proenvironmental behavior as a trade-off between short-term personal benefits and longer term collective benefits. The authors contribute to the social marketing literature on proenvironmental behavior by introducing the concept of Consumer Environmental Stewardship (CENS), which centers on the use of intrinsic motivation to stimulate a personal sense of responsibility for the environment. The findings, based on a survey and three experiments, show that the stimulation of consumers’ affinity with future generations (AFGs) and perceived consumer effectiveness (PCE) can help to promote CENS, which in turn raises proenvironmental behaviors. However, this research also shows that increasing levels of AFGs can backfire and result in lower levels of CENS, if consumers experience low levels of PCE

Optical and Thermal-Transport Properties of an Inhomogeneous d-Wave Superconductor

We calculate transport properties of disordered 2D d-wave superconductors from solutions of the Bogoliubov-de Gennes equations, and show that weak localization effects give rise to a finite frequency peak in the optical conductivity similar to that observed in experiments on disordered cuprates. At low energies, order parameter inhomogeneities induce linear and quadratic temperature dependencies in microwave and thermal conductivities respectively, and appear to drive the system towards a quasiparticle insulating phase.Comment: 5 pages,3 figure

Enhanced Photoresponse of FeS₂ Films: The Role of Marcasite-Pyrite Phase Junctions

The beneficial role of marcasite in iron-sulfide-based photo-electrochemical applications is reported for the first time. A spectacular improvement of the photoresponse observed experimentally for mixed pyrite/marcasite-FeS2 films can be ascribed to the presence of p/m phase junctions at the interface. Density functional theory calculations show that the band alignment at the phase boundary contributes to enhanced charge separation and transfer across the interface

Role of strontium cations in ZSM-5 zeolite in the methanol-to-hydrocarbons reaction

The selectivity of the methanol-to-hydrocarbons (MTH) reaction can be tuned by modifying zeolite catalysts with alkaline earth metals, which typically increase propylene selectivity and catalyst stability. Here we employed Sr2+ as its higher atomic number in comparison to the zeolite T atoms facilitates characterization by scanning transmission electron microscopy and operando X-ray absorption spectroscopy. Sr2+ dispersed in the ZSM-5 micropores coordinates water, methanol, and dimethyl ether during the MTH reaction. Complementary characterization with nuclear magnetic resonance spectroscopy, thermogravimetric analysis combined with mass spectrometry, operando infrared spectroscopy, and X-ray diffraction points to the retention of substantially more adsorbates during the MTH reaction in comparison to Sr-free zeolites. Our findings support the notion that alkaline earth metals modify the porous reaction environment such that the olefin cycle is favored over the aromatic cycle in the MTH, explaining the increased propylene yield and lower deactivation rate

Energy saving potential of climate adaptive building shells - Inverse modelling of optimal thermal and visual behaviour

In common building design practice energy performance calculation programs or, in the best case, dynamic building simulation programs are used to optimize the properties of a building shell. However, even with use of dynamic building simulation programs adaptive behaviour, in terms of changing building shell properties, is not easy to simulate since many inputs - like insulation values, window ratio, etc. are ‘fixed’ values. The result of these optimization calculations is therefore rather an optimization in fixed design values then a set of ideal optimal adaptive behaviour building shell parameters. In the Dutch FACET project (Dutch acronym: ‘Adaptive façade technology for increased comfort and lower energy use in the future’) a quest for the ideal building shell with adaptive, variable properties is performed. Since the standard way of simulating does not allow fully adaptive building shell behaviour, a completely new, inverse modelling approach is set up. The key question here is: "What would be the ideal, dynamic properties of a building shell to get the desired indoor climate at variable outdoor climate conditions?" By reversing the design approach, and using inverse modelling, a set of ideal, hypothetical building shell parameters is computed for different climate conditions at various time steps (seasons, daynight, instantaneous), for different building categories like offices, schools and dwellings. This ‘ideal’ adaptive behaviour will make it possible to maximize indoor comfort and to minimize energy use for heating, cooling, ventilation and lighting. It does not start with having existing concepts in mind, but instead focuses on clarifying the theoretical potential of adaptive architecture. In the TRNSYS and Radiance simulations the building shell input is given as a black box, with a wide range of possible (combinations of) thermal and visual properties. Technologies and materials to meet the requirements can be more futuristic but also very ‘down to earth’. Partial solutions are already available, in low or high tech solutions, such as smart glazing, variable vacuum insulation, insulating window covering, etc. Further technology development is expected to be desired to fully meet the ideally adaptive behaviour requirements. Based on state of the art ‘adaptive temperature’ criteria optimal thermal behaviour was simulated in a first step. This gives the energy saving potential for an optimal thermal adaptive building shell. In a second step the computed optimal daylight characteristics of the building shell is given by optimizing visual comfort in Radiance. In a next step, both visual and thermal behaviour is optimized in an integral way, using a multi objective criteria approach. This paper describes the thermal and visual simulation optimization results of the FACET project. Preliminary results show that optimal adaptive building shell properties can reduce the total heating and cooling demand by a factor 10 compared to state of the art new built offices. For the Netherlands this means a factor 3 compared to the very efficient passive house technology. In the case of offices the heat demand is practically eliminated and the cooling demand can be reduced significantly by a factor two. The resulting extremely low energy demand means that less effort is needed to enable zero energy, or energy producing buildings in the future

Resolving the contributions of the membrane-bound and periplasmic nitrate reductase systems to nitric oxide and nitrous oxide production in Salmonella enterica serovar Typhimurium

The production of cytotoxic nitric oxide (NO) and conversion into the neuropharmacological agent and potent greenhouse gas nitrous oxide (N2O) is linked with anoxic nitrate catabolism by Salmonella enterica serovar Typhimurium. Salmonella can synthesize two types of nitrate reductase: a membrane-bound form (Nar) and a periplasmic form (Nap). Nitrate catabolism was studied under nitrate-rich and nitrate-limited conditions in chemostat cultures following transition from oxic to anoxic conditions. Intracellular NO production was reported qualitatively by assessing transcription of the NO-regulated genes encoding flavohaemoglobin (Hmp), flavorubredoxin (NorV) and hybrid cluster protein (Hcp). A more quantitative analysis of the extent of NO formation was gained by measuring production of N2O, the end-product of anoxic NO-detoxification. Under nitrate-rich conditions, the nar, nap, hmp, norV and hcp genes were all induced following transition from the oxic to anoxic state, and 20% of nitrate consumed in steady-state was released as N2O when nitrite had accumulated to millimolar levels. The kinetics of nitrate consumption, nitrite accumulation and N2O production were similar to those of wild-type in nitrate-sufficient cultures of a nap mutant. In contrast, in a narG mutant, the steady-state rate of N2O production was ~30-fold lower than that of the wild-type. Under nitrate-limited conditions, nap, but not nar, was up-regulated following transition from oxic to anoxic metabolism and very little N2O production was observed. Thus a combination of nitrate-sufficiency, nitrite accumulation and an active Nar-type nitrate reductase leads to NO and thence N2O production, and this can account for up to 20% of the nitrate catabolized

Commentary and Worked Examples to EN 1993-1-10 "Material Toughness and Through Thickness Properties" and Other Toughness Oriented Rules in EN 1993

This commentary gives explanations and worked examples to the design rules in Eurocode 3 that are influenced by the strength and toughness properties of the structural steels used. It is a commentary and background document to EN 1993-1-10 "Material toughness and through thickness properties" and its extension in EN 1993-1-12 "Design rules for high-strength steels", where toughness properties are explicitly addressed. It however provides also background to other parts of EN 1993, e.g. to EN 1993-1-1 "Design of steel structures - Basic rules and rules for buildings", where the design rules are related only to strength properties as the yield strength and the tensile strength without explicitly mentioning the role of toughness that is hidden behind the resistance formulae. Finally it gives some comments to chapter 6 of EN 1998-1: "Design of structures for earthquake resistance - Part 1: General rules, seismic actions and rules for buildings".JRC.G.5-European laboratory for structural assessmen