23 research outputs found
Hedge fund return predictability; To combine forecasts or combine information?
- Author
- Ackermann
- Agarwal
- Agarwal
- Agarwal
- Aggarwal
- Aiolfi
- Alexander
- Amenc
- Ang
- Avramov
- Avramov
- Bai
- Bali
- Bali
- Bali
- Bali
- Bali
- Bates
- Berk
- Billio
- Breiman
- Bussiere
- Campbell
- Campbell
- Cao
- Chan
- Chen
- Clark
- Della Corte
- Della Corte
- Ekaterini Panopoulou
- Fleming
- Friedman
- Fung
- Fung
- Fung
- Fung
- Fung
- Ghosh
- Goyal
- Greyserman
- Hamza
- Harlow
- Harlow
- Harris
- Hendry
- Hoerl
- Huang
- Inoue
- Jagannathan
- Jore
- Kosowski
- Krokhmal
- Liang
- Liang
- Markowitz
- Marquering
- Meligkotsidou
- Meligkotsidou
- Mitchell
- Olmo
- Pastor
- Patton
- Petkova
- Rapach
- Rapach
- Rockafellar
- Rockafellar
- Sortino
- Spyridon Vrontos
- Stock
- Stock
- Sun
- Tibshirani
- Timmermann
- Titman
- Vassalou
- Vrontos
- Wachter
- Wegener
- West
- Zou
- Zou
- Zou
- Publication venue
- Kent Business School
- Publication date
- 01/04/2014
- Field of study
While the majority of the predictability literature has been devoted to the predictability of traditional asset classes, the literature on the predictability of hedge fund returns is quite scanty. We focus on assessing the out-of-sample predictability of hedge fund strategies by employing an extensive list of predictors. Aiming at reducing uncertainty risk associated with a single predictor model, we first engage into combining the individual forecasts. We consider various combining methods ranging from simple averaging schemes to more sophisticated ones, such as discounting forecast errors, cluster combining and principal components combining. Our second approach combines information of the predictors and applies kitchen sink, bootstrap aggregating (bagging), lasso, ridge and elastic net specifications. Our statistical and economic evaluation findings point to the superiority of simple combination methods. We also provide evidence on the use of hedge fund return forecasts for hedge fund risk measurement and portfolio allocation. Dynamically constructing portfolios based on the combination forecasts of hedge funds returns leads to considerably improved portfolio performance
The impact of surgical delay on resectability of colorectal cancer: An international prospective cohort study
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- Abadia M
- Abassy J
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- Abbott Tom EF
- Abdelaal Samir A
- Abdeldayem H
- Abdelkabir M
- Abdelsamed A
- Abdulwahed E
- Abiyere H
- Abou Chaar MK
- Abukhalaf SA
- Abukhalaf Sadi
- Adamina Michel
- Ademuyiwa Adesoji
- Ademuyiwa Adesoji O
- Adeyeye A
- Adisa Adewale
- Afzal MF
- Agarwal Arnav
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- Publication venue
- 'Royal College of Obstetricians & Gynaecologists (RCOG)'
- Publication date
- 01/06/2022
- Field of study
AIM: The SARS-CoV-2 pandemic has provided a unique opportunity to explore the impact of surgical delays on cancer resectability. This study aimed to compare resectability for colorectal cancer patients undergoing delayed versus non-delayed surgery. METHODS: This was an international prospective cohort study of consecutive colorectal cancer patients with a decision for curative surgery (January-April 2020). Surgical delay was defined as an operation taking place more than 4âweeks after treatment decision, in a patient who did not receive neoadjuvant therapy. A subgroup analysis explored the effects of delay in elective patients only. The impact of longer delays was explored in a sensitivity analysis. The primary outcome was complete resection, defined as curative resection with an R0 margin. RESULTS: Overall, 5453 patients from 304 hospitals in 47 countries were included, of whom 6.6% (358/5453) did not receive their planned operation. Of the 4304 operated patients without neoadjuvant therapy, 40.5% (1744/4304) were delayed beyond 4âweeks. Delayed patients were more likely to be older, men, more comorbid, have higher body mass index and have rectal cancer and early stage disease. Delayed patients had higher unadjusted rates of complete resection (93.7% vs. 91.9%, PÂ =Â 0.032) and lower rates of emergency surgery (4.5% vs. 22.5%, Pâ<â0.001). After adjustment, delay was not associated with a lower rate of complete resection (OR 1.18, 95% CI 0.90-1.55, PÂ =Â 0.224), which was consistent in elective patients only (OR 0.94, 95% CI 0.69-1.27, PÂ =Â 0.672). Longer delays were not associated with poorer outcomes. CONCLUSION: One in 15 colorectal cancer patients did not receive their planned operation during the first wave of COVID-19. Surgical delay did not appear to compromise resectability, raising the hypothesis that any reduction in long-term survival attributable to delays is likely to be due to micro-metastatic disease
Global burden and strength of evidence for 88 risk factors in 204 countries and 811 subnational locations, 1990â2021: a systematic analysis for the Global Burden of Disease Study 2021
- Author
- Abate Kalkidan Hassen
- Abate Yohannes Habtegiorgis
- Abbafati Cristiana
- Abbasgholizadeh Rouzbeh
- Abbasi Madineh Akram
- Abbasi-Kangevari Mohsen
- Abbasian Mohammadreza
- Abbasifard Mitra
- Abd ElHafeez Samar
- Abd-Elsalam Sherief
- Abdi Parsa
- Abdollahi Mohammad
- Abdoun Meriem
- Abdulah Deldar Morad
- Abdullahi Auwal
- Abebe Mesfin
- Abedi Aidin
- Abedi Armita
- Abegaz Tadesse M
- AbeldanÌo ZunÌiga Roberto Ariel
- Abiodun Olumide
- Abiso Temesgen Lera
- Aboagye Richard Gyan
- Abolhassani Hassan
- Abouzid Mohamed
- Aboye Girma Beressa
- Abreu Lucas GuimaraÌes
- Abu-Gharbieh Eman
- Abu-Zaid Ahmed
- Abualruz Hasan
- Abubakar Bilyaminu
- Abukhadijah Hana Jihad Jihad
- Aburuz Salahdein
- Adane Mesafint Molla
- Addo Isaac Yeboah
- Addolorato Giovanni
- Adedoyin Rufus Adesoji
- Adekanmbi Victor
- Aden Bashir
- Adetunji Juliana Bunmi
- Adeyeoluwa Temitayo Esther
- Adha Rishan
- Adibi Amin
- Adnani Qorinah Estiningtyas Sakilah
- Adzigbli Leticia Akua
- Afolabi Aanuoluwapo Adeyimika
- Afolabi Rotimi Felix
- Afshin Ashkan
- Afyouni Shadi
- Afzal Muhammad Sohail
- Afzal Saira
- Agampodi Suneth Buddhika
- Agbozo Faith
- Aghamiri Shahin
- Agodi Antonella
- Agrawal Anurag
- Agyemang-Duah Williams
- Ahinkorah Bright Opoku
- Ahmad Aqeel
- Ahmad Danish
- Ahmad Firdos
- Ahmad Noah
- Ahmad Shahzaib
- Ahmad Tauseef
- Ahmed Ali
- Ahmed Anisuddin
- Ahmed Ayman
- Ahmed Luai A
- Ahmed Muktar Beshir
- Ahmed Safoora
- Ahmed Syed Anees
- Ajami Marjan
- Akalu Gizachew Taddesse
- Akara Essona Matatom
- Akbarialiabad Hossein
- Akhlaghi Shiva
- Akinosoglou Karolina
- Akinyemiju Tomi
- Akkaif Mohammed Ahmed
- Akkala Sreelatha
- Akombi-Inyang Blessing
- Al Awaidy Salah
- Al Hasan Syed Mahfuz
- AL-Ahdal Tareq Mohammed Ali
- Al-Aly Ziyad
- Al-Fatly Bassam
- Al-Gheethi Adel Ali Saeed
- Al-Habbal Khairat
- Al-Marwani Sabah
- Al-Mekhlafi Hesham M
- Al-Raddadi Rajaa M
- Al-Rifai Rami Hani
- Al-Sabah Salman Khalifah
- Al-Tawfiq Jaffar A
- Al-Wardat Mohammad Sami
- Al-Worafi Yaser Mohammed
- Al-Zyoud Walid
- Alahdab Fares
- Alalalmeh Samer O
- Alalwan Tariq A
- Alam Khurshid
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- Alanezi Fahad Mashhour
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- Alemayohu Mulubirhan Assefa
- Alemu Yihun Mulugeta
- Alhabib Khalid F
- Alhassan Robert Kaba
- Ali Abid
- Ali Amjad
- Ali Beriwan Abdulqadir
- Ali Iman
- Ali Liaqat
- Ali Mohammed Usman
- Ali Rafat
- Ali Syed Shujait Shujait
- Ali Waad
- Alicandro Gianfranco
- Alif Sheikh Mohammad
- Aljunid Syed Mohamed
- Alla François
- Almustanyir Sami
- Alomari Mahmoud A
- Alonso Jordi
- Alqahtani Jaber S
- Alqutaibi Ahmed Yaseen
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- Amaechi Uchenna Anderson
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- Amirzade-Iranaq Mohammad Hosein
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- Amugsi Dickson A
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- Anderson Jason A
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- Angappan Dhanalakshmi
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- Antriyandarti Ernoiz
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- Anvari Davood
- Anvari Saeid
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- Anwer Razique
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- Anyasodor Anayochukwu Edward
- Apostol Geminn Louis Carace
- Arabloo Jalal
- Arabzadeh Bahri Razman
- Arafat Mosab
- Aravkin Aleksandr Y
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- Aregawi Brhane Berhe
- Aremu Abdulfatai
- Armocida Benedetta
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- Athar Mohammad
- Athari Seyyed Shamsadin
- Atorkey Prince
- Atreya Alok
- Aujayeb Avinash
- Ausloos Marcel
- Avila-Burgos Leticia
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- Bansal Hansi
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- Beiranvand Maryam
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- Belgaumi Uzma Iqbal
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- Bhala Neeraj
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- Bhaskar Sonu
- Bhat Ajay Nagesh
- Bhat Vivek
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- Bhatti Jasvinder Singh
- Bhatti Manpreet S
- Bhatti Rajbir
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- Bhutta Zulfiqar A
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- BjĂžrge Tone
- Boachie Micheal Kofi
- Boakye Hosea
- Bockarie Moses John
- Bodolica Virginia
- Bodunrin Aadam Olalekan
- Bogale Eyob Ketema
- Bolla Srinivasa Rao
- Boloor Archith
- Bonakdar Hashemi Milad
- Boppana Sri Harsha
- Bora Basara Berrak
- Borhany Hamed
- Botero Carvajal Alejandro
- Bouaoud Souad
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- Boxe Christopher
- Braithwaite Dejana
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- Brar Amanpreet
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- Cao Chao
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- Carugno Andrea
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- CastanÌeda-Orjuela Carlos A
- Castelpietra Giulio
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- Catapano Alberico L
- Cattaruzza Maria Sofia
- Caye Arthur
- CaÌmera Luis Alberto
- CaÌrdenas Rosario
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- Cegolon Luca
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- Chandan Joht Singh
- Chandika Rama Mohan
- Chaturvedi Pankaj
- Chen An-Tian
- Chen Catherine S
- Chen Haowei
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- Chen Mingling
- Chen Simiao
- Cheng Ching-Yu
- Cheng Esther T W
- Cherbuin Nicolas
- Chi Gerald
- Chichagi Fatemeh
- Chimed-Ochir Odgerel
- Chimoriya Ritesh
- Ching Patrick R
- Chirinos-Caceres Jesus Lorenzo
- Chitheer Abdulaal
- Cho William C S
- Chong Bryan
- Chopra Hitesh
- Chowdhury Rajiv
- Christopher Devasahayam J
- Chu Dinh-Toi
- Chukwu Isaac Sunday
- Chung Eric
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- Cioffi Iolanda
- Cogen Rebecca M
- Cohen Aaron J
- Columbus Alyssa
- Conde Joao
- Corlateanu Alexandru
- Cortese Samuele
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- Costa Vera Marisa
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- Cruz Jessica A
- Cruz-Martins NataÌlia
- Culbreth Garland T
- D'Amico Emanuele
- D'Anna Lucio
- D'Oria Mario
- da Silva Alanna Gomes
- Dadras Omid
- Dai Xiaochen
- Dai Zhaoli
- Daikwo Patience Unekwuojo
- Dalli Lachlan L
- Damiani Giovanni
- Darwesh Aso Mohammad
- Das Jai K
- Das Subasish
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- Dashti Mohsen
- Davis Weaver Nicole
- Davitoiu Dragos Virgil
- DaÌvila-Cervantes Claudio Alberto
- De la Hoz Fernando Pio
- de la Torre-Luque Alejandro
- De Leo Diego
- Debopadhaya Shayom
- Degenhardt Louisa
- Del Bo' Cristian
- Delgado-Enciso Ivan
- Delgado-Saborit Juana Maria
- Demoze Chalachew Kassaw
- Denova-GutieÌrrez Edgar
- Dervenis Nikolaos
- DervisÌevicÌ Emina
- Desai Hardik Dineshbhai
- Desai Rupak
- Devanbu Vinoth Gnana Chellaiyan
- Dewan Syed Masudur Rahman
- Dhali Arkadeep
- Dhama Kuldeep
- Dhane Amol S
- Dhimal Mandira Lamichhane
- Dhimal Meghnath
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- Dhulipala Vishal R
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- Diaz Luis Antonio
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- Dima Adriana
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- Djalalinia Shirin
- do Prado Camila Bruneli
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- Do Thao Huynh Phuong
- Dodangeh Masoud
- Dohare Sushil
- Dokova Klara Georgieva
- Dong Wanyue
- Dongarwar Deepa
- Dorostkar Fariba
- Dorsey E Ray
- Doshi Rajkumar
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- Dowou Robert Kokou
- Driscoll Tim Robert
- Dsouza Ashel Chelsea
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- Dushpanova Anar
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- Dziedzic Arkadiusz Marian
- Ebrahimi Alireza
- Echieh Chidiebere Peter
- Ed-Dra Abdelaziz
- Edinur Hisham Atan
- Edvardsson David
- Edvardsson Kristina
- Efendi Ferry
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- Eini Ebrahim
- Ekholuenetale Michael
- Ekundayo Temitope Cyrus
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- El-Dahiyat Faris
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- Elmehrath Ahmed O
- Elmeligy Omar Abdelsadek Abdou
- Elshaer Mohammed
- Elsohaby Ibrahim
- Emeto Theophilus I
- Esfandiari Negin
- Eshrati Babak
- Eslami Majid
- Esmaeili Sayed Vahid
- Estep Kara
- Etaee Farshid
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- Fagbamigbe Adeniyi Francis
- Fagbule Omotayo Francis
- Fahimi Saman
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- Farinha Carla Sofia e SaÌ
- Faris MoezAlIslam Ezzat Mahmoud
- Faris Pawan Sirwan
- Faro Andre
- Fasina Folorunso Oludayo
- Fatehizadeh Ali
- Fauk Nelsensius Klau
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- Feng Xiaoqi
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- Ferreira Nuno
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- Freitas Alberto
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- GajdaÌcs MaÌrioÌ
- Gakidou Emmanuela
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- Gandhi Aravind P
- Ganesan Balasankar
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- Garg Ravindra K
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- Zhang Liqun
- Zhang Meixin
- Zhang Yunquan
- Zhang Zhenyu
- Zhang Zhi-Jiang
- Zhao Hanqing
- Zhao Jeff T
- Zhao Xiu-Ju George
- Zhao Yang
- Zhao Yong
- Zheng Peng
- Zhong Chenwen
- Zhou Jingjing
- Zhou Juexiao
- Zhou Shangcheng
- Zhu Bin
- Zhu Lei
- Zhu Zhaohua
- Ziaeian Boback
- Ziafati Makan
- ZielinÌska Magdalena
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- Zumla Alimuddin
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- Publication venue
- Publication date
- 01/01/2024
- Field of study
Background: Understanding the health consequences associated with exposure to risk factors is necessary to inform public health policy and practice. To systematically quantify the contributions of risk factor exposures to specific health outcomes, the Global Burden of Diseases, Injuries, and Risk Factors Study (GBD) 2021 aims to provide comprehensive estimates of exposure levels, relative health risks, and attributable burden of disease for 88 risk factors in 204 countries and territories and 811 subnational locations, from 1990 to 2021. Methods: The GBD 2021 risk factor analysis used data from 54 561 total distinct sources to produce epidemiological estimates for 88 risk factors and their associated health outcomes for a total of 631 riskâoutcome pairs. Pairs were included on the basis of data-driven determination of a riskâoutcome association. Age-sex-location-year-specific estimates were generated at global, regional, and national levels. Our approach followed the comparative risk assessment framework predicated on a causal web of hierarchically organised, potentially combinative, modifiable risks. Relative risks (RRs) of a given outcome occurring as a function of risk factor exposure were estimated separately for each riskâoutcome pair, and summary exposure values (SEVs), representing risk-weighted exposure prevalence, and theoretical minimum risk exposure levels (TMRELs) were estimated for each risk factor. These estimates were used to calculate the population attributable fraction (PAF; ie, the proportional change in health risk that would occur if exposure to a risk factor were reduced to the TMREL). The product of PAFs and disease burden associated with a given outcome, measured in disability-adjusted life-years (DALYs), yielded measures of attributable burden (ie, the proportion of total disease burden attributable to a particular risk factor or combination of risk factors). Adjustments for mediation were applied to account for relationships involving risk factors that act indirectly on outcomes via intermediate risks. Attributable burden estimates were stratified by Socio-demographic Index (SDI) quintile and presented as counts, age-standardised rates, and rankings. To complement estimates of RR and attributable burden, newly developed burden of proof risk function (BPRF) methods were applied to yield supplementary, conservative interpretations of riskâoutcome associations based on the consistency of underlying evidence, accounting for unexplained heterogeneity between input data from different studies. Estimates reported represent the mean value across 500 draws from the estimate's distribution, with 95% uncertainty intervals (UIs) calculated as the 2·5th and 97·5th percentile values across the draws. Findings: Among the specific risk factors analysed for this study, particulate matter air pollution was the leading contributor to the global disease burden in 2021, contributing 8·0% (95% UI 6·7â9·4) of total DALYs, followed by high systolic blood pressure (SBP; 7·8% [6·4â9·2]), smoking (5·7% [4·7â6·8]), low birthweight and short gestation (5·6% [4·8â6·3]), and high fasting plasma glucose (FPG; 5·4% [4·8â6·0]). For younger demographics (ie, those aged 0â4 years and 5â14 years), risks such as low birthweight and short gestation and unsafe water, sanitation, and handwashing (WaSH) were among the leading risk factors, while for older age groups, metabolic risks such as high SBP, high body-mass index (BMI), high FPG, and high LDL cholesterol had a greater impact. From 2000 to 2021, there was an observable shift in global health challenges, marked by a decline in the number of all-age DALYs broadly attributable to behavioural risks (decrease of 20·7% [13·9â27·7]) and environmental and occupational risks (decrease of 22·0% [15·5â28·8]), coupled with a 49·4% (42·3â56·9) increase in DALYs attributable to metabolic risks, all reflecting ageing populations and changing lifestyles on a global scale. Age-standardised global DALY rates attributable to high BMI and high FPG rose considerably (15·7% [9·9â21·7] for high BMI and 7·9% [3·3â12·9] for high FPG) over this period, with exposure to these risks increasing annually at rates of 1·8% (1·6â1·9) for high BMI and 1·3% (1·1â1·5) for high FPG. By contrast, the global risk-attributable burden and exposure to many other risk factors declined, notably for risks such as child growth failure and unsafe water source, with age-standardised attributable DALYs decreasing by 71·5% (64·4â78·8) for child growth failure and 66·3% (60·2â72·0) for unsafe water source. We separated risk factors into three groups according to trajectory over time: those with a decreasing attributable burden, due largely to declining risk exposure (eg, diet high in trans-fat and household air pollution) but also to proportionally smaller child and youth populations (eg, child and maternal malnutrition); those for which the burden increased moderately in spite of declining risk exposure, due largely to population ageing (eg, smoking); and those for which the burden increased considerably due to both increasing risk exposure and population ageing (eg, ambient particulate matter air pollution, high BMI, high FPG, and high SBP). Interpretation: Substantial progress has been made in reducing the global disease burden attributable to a range of risk factors, particularly those related to maternal and child health, WaSH, and household air pollution. Maintaining efforts to minimise the impact of these risk factors, especially in low SDI locations, is necessary to sustain progress. Successes in moderating the smoking-related burden by reducing risk exposure highlight the need to advance policies that reduce exposure to other leading risk factors such as ambient particulate matter air pollution and high SBP. Troubling increases in high FPG, high BMI, and other risk factors related to obesity and metabolic syndrome indicate an urgent need to identify and implement interventions
Outcomes from elective colorectal cancer surgery during the SARS-CoV-2 pandemic
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- Rojo LĂłpez J. A.
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- Ronellenfitsch U. (University Hospital Halle (Saale))
- Rooney S.
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- Roslani A. C. (University Malaya Medical Centre). Mexico: Buerba G. A.
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- Rozzano (Mi) and Humanitas University
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- Russ J.
- RutegÄrd M. (Umea University Hospital). Switzerland: Arigoni M.
- Rutherford D.
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- Ryan M. (University Hospital Waterford/University College Cork). Italy: Macina S. (ASST Mantua)
- Ryan Ă. (University Hospital Galway)
- Ryska O. (Royal Lancaster Infirmary)
- RĂo Lafuente F. D.
- Saad M. M.
- Saafan T.
- Saavedra J.
- Sabah)
- Sabratha)
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- Sampaio da NĂłvoa Gomes Miguel I. I. (Centro Hospitalar UniversitĂĄrio do Algarve â Unidade de PortimĂŁo)
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- San Francisco (UCSF))
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- SaudĂ S. (Hospital Universitario Miguel Servet)
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- Sauvat F. (CHU RĂ©union). Romania: Bezede C.
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- Sayyed R. (Patel Hospital)
- Scabini S.
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- Schineis C. (Charité University Medicine
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- Schlesinger N.
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- Scrima O.
- Sechenov Medical State University)
- Seebah K.
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- Seguin-Givelet A.
- Sehgal T.
- Selmani J.
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- Senossi O.
- Serevina O. L.
- Serralta de Colsa D. (Infanta SofĂa University Hospital)
- Serrano GonzĂĄlez J. (Hospital Universitario de TorrejĂłn de Ardoz)
- Serrano-Navidad M.
- Sert Ä°.
- Seymour Z. (Ysbyty Gwynedd). USA: Haynes A.
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- Syed W. A. S.
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- SĂĄnchez del Pueblo C.
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- Thulasiraman S. V.
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- TU Dresden)
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- Universiti Sains Malaysia)
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- Xavier R. G.
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- Yang W.
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- Yesantharao P.
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- Yıldırım A.
- Yildiz A. (Yildirim Beyazit University Yenimahalle Training and Research Hospital). Uganda: Lule H.
- Young R. (York Teaching Hospitals NHS Trust)
- Yousof E. A. (Assiut University Hospital)
- Youssef M. (Norfolk and Norwich University Hospital)
- Yurttas C. (University Hospital Tuebingen)
- YĂĄnez C. (Royo Villanova)
- YĂŒksel E. (Kocaeli University Teaching Hospital)
- Zafar S. N. (University of Wisconsin)
- Zakaria A. D.
- Zakaria Z. (School of Medical Sciences and Hospital
- Zambon M. (Policlinico Umberto I Sapienza University of Rome)
- Zanus G. (Caâ Foncello Treviso â DISCOG â UniversitĂ di Padova)
- Zegarac M. (Institute for Oncology and Radiology of Serbia)
- ZeliÄ M. (University Hospital Center Rijeka)
- Zengin A. K. (Istanbul Universty â CerrahpaĆa Medical Faculty)
- Zerbib P. (CHU Lille)
- Zervas K.
- Zese M. (Santa Maria degli Angeli Hospital ULSS 5 â Adria)
- Zhang H. (Concord Repatriation General Hospital)
- Zizzo M. (Azienda UnitĂ Sanitaria Locale â IRCCS di Reggio Emilia)
- Zografos C. (Laiko University Hospital)
- Zorrilla OrtĂșzar J. (Hospital General Universitario Gregorio Marañón)
- Zourntou S. (General Hospital of Larissa âKoutlimpaneio and Triantafylleioâ)
- Zubaidi A. M. (King Saud University). Serbia: AleksiÄ L.
- Ăngelo M.
- Ăelebi F.
- Ăolak E.
- Ăfner D. (Medical University of Innsbruck)
- Ăhlberger L.
- Ăzçelık M. F.
- ĂÄĂŒcĂŒ H.
- ĂberrĂŒck L.
- Äoza I.
- Publication venue
- 'Wiley'
- Publication date
- 01/01/2020
- Field of study
This study aimed to describe the change in surgical practice and the impact of SARS-CoV-2 on mortality after surgical resection of colorectal cancer during the initial phases of the SARS-CoV-2 pandemic
SYNTHESIS, SPECTROSCOPIC AND THERMAL INVESTIGATIONS OF SOME METAL IMIDODIPHOSPHATES
- Publication venue
- 'Japanese Association of Inorganic Phosphorus Chemistry'
- Publication date
- 01/01/1999
- Field of study
The structure, function and properties of sirohaem decarboxylase - an enzyme with structural homology to a transcription factor family that is part of the alternative haem biosynthesis pathway.
- Author
- Publication venue
- 'Wiley'
- Publication date
- 01/01/2014
- Field of study
Some bacteria and archaea synthesize haem by an alternative pathway, which involves the sequestration of sirohaem as a metabolic intermediate rather than as a prosthetic group. Along this pathway the two acetic acid side-chains attached to C12 and C18 are decarboxylated by sirohaem decarboxylase, a heterodimeric enzyme composed of AhbA and AhbB, to give didecarboxysirohaem. Further modifications catalysed by two related radical SAM enzymes, AhbC and AhbD, transform didecarboxysirohaem into Fe-coproporphyrin III and haem respectively. The characterization of sirohaem decarboxylase is reported in molecular detail. Recombinant versions of Desulfovibrio desulfuricans, Desulfovibrio vulgaris and Methanosarcina barkeri AhbA/B have been produced and their physical properties compared. The D. vulgaris and M. barkeri enzyme complexes both copurify with haem, whose redox state influences the activity of the latter. The kinetic parameters of the D. desulfuricans enzyme have been determined, the enzyme crystallized and its structure has been elucidated. The topology of the enzyme reveals that it shares a structural similarity to the AsnC/Lrp family of transcription factors. The active site is formed in the cavity between the two subunits and a AhbA/B-product complex with didecarboxysirohaem has been obtained. A mechanism for the decarboxylation of the kinetically stable carboxyl groups is proposed
HemQ: An iron-coproporphyrin oxidative decarboxylase for protoheme synthesis in Firmicutes and Actinobacteria
- Author
- Alexander
- Astner
- Bab-Dinitz
- Bali
- Bali
- Battersby
- Blanc
- Boynton
- Boynton
- Breckau
- Buan
- Dailey
- Dailey
- Dailey
- Dailey
- Dailey
- Dailey
- Dailey
- Dailey
- Erskine
- Fan
- Giovannoni
- Hamza
- Hansson
- Harry A. Dailey
- Hofbauer
- Holliday
- Ishida
- Jacobs
- Jahn
- Jahn
- Kannangara
- Kato
- Kobayashi
- Kostan
- Kuhner
- Labbe-Bois
- Lacelles
- Lascelles
- Layer
- Layer
- Layer
- Lewis
- Louie
- Malmstrom
- Mayfield
- Medlock
- Medlock
- Medlock
- Mira
- Mobius
- Morris
- Munro
- Panek
- Phillips
- Rao
- Raux
- Sandy
- Schubert
- Schulze
- Svetlana Gerdes
- Tait
- Terry
- Townsley
- Wyckoff
- Publication venue
- 'Elsevier BV'
- Publication date
- Field of study
Making and breaking heme
- Author
- Al-Karadaghi
- Arianna I. Celis
- Avila
- Bali
- Boynton
- Boynton
- Celis
- Celis
- Celis
- Corradi
- Corrigal
- Dailey
- Dailey
- Ferreira
- Graves
- Hamza
- Hansson
- Heinemann
- Hörtensteiner
- Jennifer L. DuBois
- Kato
- Kobayashi
- Koch
- LaMattina
- Layer
- Layer
- Layer
- Lecerof
- Lee
- Lobo
- Lyles
- Mayfield
- Medlock
- Medlock
- Mielcarek
- Nagaraj
- Panek
- Phillips
- PruĆŸinskĂĄ
- Qin
- Schuller
- Shekhawat
- Shepherd
- Soderberg
- Streit
- Wilks
- Wilks
- Publication venue
- 'Elsevier BV'
- Publication date
- Field of study
KINETICS AND MECHANISM OF THE REACTION BETWEEN OLIGOSILOXANES AND P-TRICHLORO-N-DICHLOROPHOSPHORYL MONOPHOSPHAZENE (Cl 3
- Author
- Abdeslam Meliani
- Abouchakra T.
- Ahmed Mazzah
- Allcock H. R.
- Boileau S.
- Chojnowski J.
- Chojnowsky J.
- D'Halluin G.
- De Jaeger R.
- Dreyfus P.
- Eaborn C.
- Hager R.
- Hamza Bali
- Helioui M.
- Jean Habimana
- Mazzah A.
- Riesel L.
- Roger de Jaeger
- Sanderson R. T.
- Sigwalt P.
- Thomas L. C.
- Wilczek L.
- Williams E. A.
- Wright P. V.
- Yamada F.
- Yann Vaugeois
- Publication venue
- 'Informa UK Limited'
- Publication date
- Field of study