Oxygen Generation from Carbon Dioxide for Advanced Life Support

The partial electrochemical reduction of carbon dioxide (CO2) using ceramic oxygen generators (COGs) is well known and widely studied. However, complete reduction of metabolically produced CO2 (into carbon and oxygen) has the potential of reducing oxygen storage weight for life support if the oxygen can be recovered. Recently, the University of Florida devel- oped novel ceramic oxygen generators employing a bilayer elec- trolyte of gadolinia-doped ceria and erbia-stabilized bismuth ox- ide (ESB) for NASA's future exploration of Mars. The results showed that oxygen could be reliably produced from CO2 at temperatures as low as 400 C. The strategy discussed here for advanced life support systems employs a catalytic layer com- bined with a COG cell so that CO2 is reduced all the way to solid carbon and oxygen without carbon buildup on the COG cell and subsequent deactivation

Oxygen Generation from Carbon Dioxide for Advanced Life Support

The partial electrochemical reduction of CO2 using ceramic oxygen generators (COGs) is well known and has been studied. Conventional COGs use yttria-stabilized zirconia (YSZ) electrolytes and operate at temperatures greater than 700 C (1, 2). Operating at a lower temperature has the advantage of reducing the mass of the ancillary components such as insulation. Moreover, complete reduction of metabolically produced CO2 (into carbon and oxygen) has the potential of reducing oxygen storage weight if the oxygen can be recovered. Recently, the University of Florida developed ceramic oxygen generators employing a bilayer electrolyte of gadolinia-doped ceria and erbia-stabilized bismuth oxide (ESB) for NASA s future exploration of Mars (3). The results showed that oxygen could be reliably produced from CO2 at temperatures as low as 400 C. These results indicate that this technology could be adapted to CO2 removal from a spacesuit and other applications in which CO2 removal is an issue. This strategy for CO2 removal in advanced life support systems employs a catalytic layer combined with a COG so that the CO2 is reduced completely to solid carbon and oxygen. First, to reduce the COG operating temperature, a thin, bilayer electrolyte was employed. Second, to promote full CO2 reduction while avoiding the problem of carbon deposition on the COG cathode, a catalytic carbon deposition layer was designed and the cathode utilized materials shown to be coke resistant. Third, a composite anode was used consisting of bismuth ruthenate (BRO) and ESB that has been shown to have high performance (4). The inset of figure 1 shows the conceptual design of the tubular COG and the rest of the figure shows schematically the test apparatus. Figure 2 shows the microstructure of a COG tube prior to testing. During testing, current is applied across the cell and initially CuO is reduced to copper metal by electrochemical pumping. Then the oxygen source becomes the CO/CO2. This presentation details the results of testing the COG

Photocatalyzed hydrogen evolution from water by a composite catalyst of NH2-MIL-125(Ti) and surface nickel(II) species

A composite of the metal–organic framework (MOF) NH2-MIL-125(Ti) and molecular and ionic nickel(II) species, catalyzed hydrogen evolution from water under UV light. In 95 v/v¿% aqueous conditions the composite produced hydrogen in quantities two orders of magnitude higher than that of the virgin framework and an order of magnitude greater than that of the molecular catalyst. In a 2 v/v¿% water and acetonitrile mixture, the composite demonstrated a TOF of 28 mol H2 g(Ni)-1 h-1 and remained active for up to 50 h, sustaining catalysis for three times longer and yielding 20-fold the amount of hydrogen. Appraisal of physical mixtures of the MOF and each of the nickel species under identical photocatalytic conditions suggest that similar surface localized light sensitization and proton reduction processes operate in the composite catalyst. Both nickel species contribute to catalytic conversion, although different activation behaviors are observed.Peer ReviewedPostprint (author's final draft

Two-Loop Large-mtm_t Electroweak Corrections to K→πννˉK\to\pi\nu\bar\nu for Arbitrary Higgs Boson Mass

We consider for the first time the leading large top mass corrections, arising at higher order in electroweak interactions, to the rare decays $K\to\pi\nu\bar\nu$ and the related modes $B\to X_s\nu\bar\nu$ and $B\to l^+l^-$. Higher order effects of similar type have previously been calculated in the large-$m_t$ limit for key observables of precision electroweak physics at Z-factories. Here we obtain the corresponding corrections of order ${\cal O}(G^2_F m^4_t)$ at the amplitude level for short-distance dominated rare meson decays. This allows us to quantify the importance of higher order electroweak effects for these processes, which can be reliably computed and have very small uncertainties from strong interactions. Simultaneously it becomes possible to remove, to some extent, ambiguities in the definition of electroweak parameters describing the strength of FCNC interactions. The corrections we discuss are at the level of a few percent.Comment: 11 pages, LaTeX, 1 eps-figur

Interface and electronic characterization of thin epitaxial Co3O4 films

The interface and electronic structure of thin (~20-74 nm) Co3O4(110) epitaxial films grown by oxygen-assisted molecular beam epitaxy on MgAl2O4(110) single crystal substrates have been investigated by means of real and reciprocal space techniques. As-grown film surfaces are found to be relatively disordered and exhibit an oblique low energy electron diffraction (LEED) pattern associated with the O-rich CoO2 bulk termination of the (110) surface. Interface and bulk film structure are found to improve significantly with post-growth annealing at 820 K in air and display sharp rectangular LEED patterns, suggesting a surface stoichiometry of the alternative Co2O2 bulk termination of the (110) surface. Non-contact atomic force microscopy demonstrates the presence of wide terraces separated by atomic steps in the annealed films that are not present in the as-grown structures; the step height of ~ 2.7 A corresponds to two atomic layers and confirms a single termination for the annealed films, consistent with the LEED results. A model of the (1 * 1) surfaces that allows for compensation of the polar surfaces is presented.Comment: 8 pages, 7 figure

KL→π0ννˉK_L \to \pi^0 \nu \bar \nu Beyond the Standard Model

We analyze the decay $K_L \to \pi^0 \nu \bar \nu$ in a model independent way. If lepton flavor is conserved the final state is (to a good approximation) purely CP even. In that case this decay mode goes mainly through CP violating interference between mixing and decay. Consequently, a theoretically clean relation between the measured rate and electroweak parameters holds in any given model. Specifically, $\Gamma(K_L \to \pi^0 \nu \bar \nu)/\Gamma(K^+ \to \pi^+ \nu \bar \nu)= \sin^2\theta$ (up to known isospin corrections), where $\theta$ is the relative CP violating phase between the $K-\bar K$ mixing amplitude and the $s\to d\nu\bar\nu$ decay amplitude. The experimental bound on $BR(K^+ \to \pi^+ \nu \bar \nu)$ provides a model independent upper bound: $BR(K_L \to \pi^0 \nu \bar \nu) < 1.1 \times 10^{-8}$. In models with lepton flavor violation, the final state is not necessarily a CP eigenstate. Then CP conserving contributions can dominate the decay rate.Comment: 12 pages, revtex, no figure

Rare Kaon Decays

The phenomenology of rare kaon decays is reviewed, with emphasis on tests of standard model flavordynamics.Comment: 10 pages, Latex, espcrc2.sty; Invited Talk presented at 4th KEK Topical Conference on Flavor Physics, Tsukuba, Japan, 29-31 Oct. 1996, to appear in Nucl. Phys. B proc. supp

Rare KK Decays

The rare decays of the $K$ meson have had a long tradition as a laboratory for testing the symmetry properties of the weak interactions, and the manner in which these symmetries are broken by higher order effects. Present--day interest is focussed on decays that are suppressed by $CP$--symmetry or GIM symmetry. Such decays, in the standard theory, are sensitive to effects of the virtual top quark, and could also reveal new interactions transcending the standard model. In addition, the radiative decays of the $K$ meson have become a useful testing--ground for effective Lagrangians describing the low energy interactions of pions, kaons and photons.Comment: Invited Talk at the Third Workshop on High Energy Particle Physics (WHEPP 3) Madras, 1994, LaTex, 14 pages, 3 figures available upon reques

Weak Decays Beyond Leading Logarithms

We review the present status of QCD corrections to weak decays beyond the leading logarithmic approximation including particle-antiparticle mixing and rare and CP violating decays. After presenting the basic formalism for these calculations we discuss in detail the effective hamiltonians for all decays for which the next-to-leading corrections are known. Subsequently, we present the phenomenological implications of these calculations. In particular we update the values of various parameters and we incorporate new information on m_t in view of the recent top quark discovery. One of the central issues in our review are the theoretical uncertainties related to renormalization scale ambiguities which are substantially reduced by including next-to-leading order corrections. The impact of this theoretical improvement on the determination of the Cabibbo-Kobayashi-Maskawa matrix is then illustrated in various cases.Comment: 229 pages, 32 PostScript figures (included); uses RevTeX, epsf.sty, rotate.sty, rmpbib.sty (included), times.sty (included; requires LaTeX 2e); complete PostScript version available at ftp://feynman.t30.physik.tu-muenchen.de/pub/preprints/tum-100-95.ps.gz or ftp://feynman.t30.physik.tu-muenchen.de/pub/preprints/tum-100-95.ps2.gz (scaled down and rotated version to print two pages on one sheet of paper