Pilot actions in European cities - Stuttgart

The field of urban climatology has a long tradition in Stuttgart. It exists as discipline in Stuttgart since 1938. Stuttgart was the first city to establish its own Department of Climatology to research ways of improving the flow of fresh air into the city and to reduce thermal stress in most populated city districts. The specialist department of Urban Climatology, within the Environmental Protection Office, deals with tasks relating to environmental meteorology within the scope of air pollution control and also relating to urban and global climate protection. So in Stuttgart the urban heat island phenomenon (UHI) is studied for several decades, leading to a high level understanding of the UHI and the problems which it causes. The UHI causes an increase in air temperatures and thermal stress, that are identified as most negative impacts on human health and urban living. In the view of global climate change and the predicted temperature rise for the Stuttgart region of 1.5–2 K in this century, the negative impacts of UHI on human health and urban living will become more problematic in the future. According to the results of climate models the frequency of very hot days is expected to jump by nearly 30 % at the end of the century. The rising temperatures due to the global climate change in combination with the temperature shift as a result of the UHI will intensify the heat stress in urban areas, that leads to a significant increasing risk to human health, in particular to the very young and elderly. Not least due its importance for the human health and the quality of urban life in Stuttgart, the UHI is focussed by urban planners and is noticed by the future development of the city. Within the pilot action study in Stuttgart several measure for reducing the UHI and the impacts on urban living and human health are analysed by the use of micro-scale and macro-scale simulations. With the help of these analysis realisable measure are selected. The most useful measures are implemented into a developmoutline plan for the redevelopment of the city district Stuttgart-West by the municipal urban planners

Beyond the energy gap law : the influence of selection rules and host compound effects on nonradiative transition rates in boltzmann thermometers

P.N. and M.H. contributed equally to this work. H.A.H., P.N., M.H., and E.T. thank the Deutsche Forschungsgemeinschaft (DFG) for generous support (Project HO 4503/5-1). Open access funding enabled and organized by Projekt DEAL.Apart from the energy gap law, control parameters over nonradiative transitions are so far only scarcely regarded. In this work, the impact of both covalence of the lanthanoid–ligand bond and varying bond distance on the magnitude of the intrinsic nonradiative decay rate between the excited 6P5/2 and 6P7/2 spin–orbit levels of Gd3+ is investigated in the chemically related compounds Y2[B2(SO4)6] and LaBO3. Analysis of the temperature-dependent luminescence spectra reveals that the intrinsic nonradiative transition rates between the excited 6PJ (  J = 5/2, 7/2) levels are of the order of only 10 ms−1 (Y2[B2(SO4)6]:Gd3+: 8.9 ms−1; LaBO3:Gd3+: 10.5 ms−1) and differ due to the different degree of covalence of the Gd—O bonds in the two compounds. Comparison to the established luminescent Boltzmann thermometer Er3+ reveals, however, that the nonradiative transition rates between the excited levels of Gd3+ are over three orders of magnitude slower despite a similar energy gap and the presence of a single resonant phonon mode. This hints to a fundamental magnetic dipolar character of the nonradiative coupling in Gd3+. These findings can pave a way to control nonradiative transition rates and how to tune the dynamic range of luminescent Boltzmann thermometers.Publisher PDFPeer reviewe

Low Temperature Precursor Route for Highly Efficient Spherically Shaped LED-Phosphors M2Si5N8:Eu2+ (M = Eu, Sr, Ba)

The highly efficient nitridosilicate phosphors M2Si5N8 (M = Sr, Ba, Eu) for phosphor-converted pc-LEDs were synthesized at low temperatures using a novel precursor route involving metal amides M(NH2)2. These precursors have been synthesized by dissolution of the respective metals in supercritical ammonia at 150°C and 300 bar. The thermal behavior and decomposition process of the amides were investigated with temperature programmed powder X-ray diffractometry and thermoanalytical measurements (DTA/TG). These investigations rendered the amides as suitable intermediates for reaction with silicon diimide (Si(NH)2). Thus, the desired nitridosilicate phosphors were obtained at relatively low temperatures around 1150−1400°C which is approximately 300°C lower compared to common synthetic approaches starting from metals or oxides. The influence of the thermal treatment on the phosphor morphology has been studied extensively. The accessibility of spherical phosphor particles represents another striking feature of this route since it improves light extraction from the crystallites due to decreasing light guiding and decreasing re-absorption inside the phosphor particle. The synthesized luminescent materials M2Si5N8:Eu2+ (M = Sr, Ba) exhibit quantum efficiencies and emission band widths (FWHM 70−90 nm) comparable to standard phosphor powders. Employment of Eu(NH2)2 as dopant reagent for synthesis of Ba2Si5N8:Eu2+ proved favorable for the formation of spherical crystallites compared to doping with Eu metal, halides, or oxide

Beyond the Energy Gap Law: The Influence of Selection Rules and Host Compound Effects on Nonradiative Transition Rates in Boltzmann Thermometers

Apart from the energy gap law, control parameters over nonradiative transitions are so far only scarcely regarded. In this work, the impact of both covalence of the lanthanoid–ligand bond and varying bond distance on the magnitude of the intrinsic nonradiative decay rate between the excited 6P5/2 and 6P7/2 spin–orbit levels of Gd3+ is investigated in the chemically related compounds Y2[B2(SO4)6] and LaBO3. Analysis of the temperature-dependent luminescence spectra reveals that the intrinsic nonradiative transition rates between the excited 6PJ (J = 5/2, 7/2) levels are of the order of only 10 ms−1 (Y2[B2(SO4)6]:Gd3+: 8.9 ms−1; LaBO3:Gd3+: 10.5 ms−1) and differ due to the different degree of covalence of the Gd-O bonds in the two compounds. Comparison to the established luminescent Boltzmann thermometer Er3+ reveals, however, that the nonradiative transition rates between the excited levels of Gd3+ are over three orders of magnitude slower despite a similar energy gap and the presence of a single resonant phonon mode. This hints to a fundamental magnetic dipolar character of the nonradiative coupling in Gd3+. These findings can pave a way to control nonradiative transition rates and how to tune the dynamic range of luminescent Boltzmann thermometers

Ba3Ga3N5 - A Novel Host Lattice for Eu2+ - Doped Luminescent Materials with Unexpected Nitridogallate Substructure

The alkaline earth nitridogallate Ba3Ga3N5 was synthesized from the elements in a sodium flux at 760°C utilizing weld shut tantalum ampules. The crystal structure was solved and refined on the basis of single-crystal X-ray diffraction data. Ba3Ga3N5 (space group C2/c (No. 15), a = 16.801(3), b = 8.3301(2), c = 11.623(2) Å, β = 109.92 (3)°, Z = 8) contains a hitherto unknown structural motif in nitridogallates, namely, infinite strands made up of GaN4 tetrahedra, each sharing two edges and at least one corner with neighboring GaN4 units. There are three Ba2+ sites with coordination numbers six or eight, respectively, and one Ba2+ position exhibiting a low coordination number 4 corresponding to a distorted tetrahedron. Eu2+ - doped samples show red luminescence when excited by UV irradiation at room temperature. Luminescence investigations revealed a maximum emission intensity at 638 nm (FWHM =2123 cm−1). Ba3Ga3N5 is the first nitridogallate for which parity allowed broadband emission due to Eu2+ - doping has been found. The electronic structure of both Ba3Ga3N5 as well as isoelectronic but not isostructural Sr3Ga3N5 was investigated by DFT methods. The calculations revealed a band gap of 1.53 eV for Sr3Ga3N5 and 1.46 eV for Ba3Ga3N5

Conforto térmico em espaços públicos de passagem: estudos em ruas de pedestres no estado de São Paulo

Este artigo apresenta resultados de um estudo sobre conforto térmico em espaços públicos de passagem, em ruas de pedestres nas cidades de Campinas, Bauru e Presidente Prudente, no Estado de São Paulo. O estudo foi desenvolvido dentro de uma pesquisa mais ampla sobre o conforto térmico em diferentes tipos de espaços urbanos abertos, nas mesmas cidades. A metodologia empregada envolveu o monitoramento microclimático (temperatura, temperatura de globo, umidade relativa do ar, velocidade do ar e radiação solar global), em diferentes condições de tempo, e entrevistas estruturadas, para identificar a sensação térmica e as variáveis pessoais dos usuários. A análise dos resultados permitiu identificar diferenças entre a sensação térmica real (ASV) e o conforto calculado pela temperatura fisiológica equivalente (PET). Os limites de conforto térmico variaram entre as cidades: 20-29 ºC para Campinas, 21-30 ºC para Bauru, e 14-24 ºC para Presidente Prudente. Entretanto, a sensação de neutralidade térmica para 59,5% do total da amostra (308 de 519 indivíduos) foi de 18 a 26 ºC. Esses resultados são compatíveis com os limites propostos por Monteiro e Alucci (2007) para a cidade de São Paulo e podem contribuir como parâmetro de avaliação da qualidade térmica de outros espaços públicos de passagem nas mesmas cidades

Engrained experience—a comparison of microclimate perception schemata and microclimate measurements in Dutch urban squares

Acceptance of public spaces is often guided by perceptual schemata. Such schemata also seem to play a role in thermal comfort and microclimate experience. For climate-responsive design with a focus on thermal comfort it is important to acquire knowledge about these schemata. For this purpose, perceived and “real” microclimate situations were compared for three Dutch urban squares. People were asked about their long-term microclimate perceptions, which resulted in “cognitive microclimate maps”. These were compared with mapped microclimate data from measurements representing the common microclimate when people stay outdoors. The comparison revealed some unexpected low matches; people clearly overestimated the influence of the wind. Therefore, a second assumption was developed: that it is the more salient wind situations that become engrained in people’s memory. A comparison using measurement data from windy days shows better matches. This suggests that these more salient situations play a role in the microclimate schemata that people develop about urban places. The consequences from this study for urban design are twofold. Firstly, urban design should address not only the “real” problems, but, more prominently, the “perceived” problems. Secondly, microclimate simulations addressing thermal comfort issues in urban spaces should focus on these perceived, salient situations

Influence of ground surface characteristics on the mean radiant temperature in urban areas

The effect of variations in land cover on mean radiant surface temperature (Tmrt) is explored through a simple scheme developed within the radiation model SOLWEIG. Outgoing longwave radiation is parameterised using surface temperature observations on a grass and an asphalt surface, whereas outgoing shortwave radiation is modelled through variations in albedo for the different surfaces. The influence of surface materials on Tmrt is small compared to the effects of shadowing. Nevertheless, altering ground surface materials could contribute to a reduction on Tmrt to reduce the radiant load during heat-wave episodes in locations where shadowing is not an option. Evaluation of the new scheme suggests that despite its simplicity it can simulate the outgoing fluxes well, especially during sunny conditions. However, it underestimates at night and in shadowed locations. One grass surface used to develop the parameterisation, with very different characteristics compared to an evaluation grass site, caused Tmrt to be underestimated. The implications of using high resolution (e.g. 15 minutes) temporal forcing data under partly cloudy conditions are demonstrated even for fairly proximal sites

the urban corridor of venice and the case of padua

Urban Heat Island effect was widely studied in large cities around the world, more rarely in medium size ones. The chapter reports on the study of the UHI phenomenon in Padua, a medium size city of the North-East of Italy, one of the most industrialized and developed parts of the country. Experimental measurements were carried out during 2012 summer, recording the main thermo-hygrometric variables (dry-bulb temperature, relative humidity, global solar radiation) by a mobile survey along an exact path crossing different zones of the city area: urban, sub-urban and rural. The analysis of the data highlights the presence of UHI effect with different magnitudes in function of the zone of the city. In the city centre, an historical zone, the effect was up to 7 °C. In the meantime, some measurements in situ were carried out in order to evaluate other thermal comfort indexes rather than air temperature and humidity only: wind velocity and mean radiant temperature (besides the other meteorological variables) in some characteristic sites of the city area like historic centre, high and low density populated residential zones, industrial zone, rural zone, were recorded. In particular, a very famous square of the city (Prato della Valle) was analysed: it can be considered representative of the phenomenon because of the size and the very different characteristics from the UHI effect point of view. RayMan simulation model was used to calculate some outdoor comfort indexes and Envimet model was further used to evaluate the effect of some mitigation strategies in characteristic sites of the city

Effect Modification of the Association between Short-term Meteorological Factors and Mortality by Urban Heat Islands in Hong Kong

Background Prior studies from around the world have indicated that very high temperatures tend to increase summertime mortality. However possible effect modification by urban micro heat islands has only been examined by a few studies in North America and Europe. This study examined whether daily mortality in micro heat island areas of Hong Kong was more sensitive to short term changes in meteorological conditions than in other areas. Method An urban heat island index (UHII) was calculated for each of Hong Kong’s 248 geographical tertiary planning units (TPU). Daily counts of all natural deaths among Hong Kong residents were stratified according to whether the place of residence of the decedent was in a TPU with high (above the median) or low UHII. Poisson Generalized Additive Models (GAMs) were used to estimate the association between meteorological variables and mortality while adjusting for trend, seasonality, pollutants and flu epidemics. Analyses were restricted to the hot season (June-September). Results Mean temperatures (lags 0–4) above 29°C and low mean wind speeds (lags 0–4) were significantly associated with higher daily mortality and these associations were stronger in areas with high UHII. A 1°C rise above 29°C was associated with a 4.1% (95% confidence interval (CI): 0.7%, 7.6%) increase in natural mortality in areas with high UHII but only a 0.7% (95% CI: −2.4%, 3.9%) increase in low UHII areas. Lower mean wind speeds (5th percentile vs. 95th percentile) were associated with a 5.7% (95% CI: 2.7, 8.9) mortality increase in high UHII areas vs. a −0.3% (95% CI: −3.2%, 2.6%) change in low UHII areas. Conclusion The results suggest that urban micro heat islands exacerbate the negative health consequences of high temperatures and low wind speeds. Urban planning measures designed to mitigate heat island effects may lessen the health effects of unfavorable summertime meteorological conditions