Photoelectron angular distribution in two-pathway ionization of neon with femtosecond XUV pulses

We analyze the photoelectron angular distribution in two-pathway interference between non\-resonant one-photon and resonant two-photon ionization of neon. We consider a bichromatic femtosecond XUV pulse whose fundamental frequency is tuned near the $2p^5 3s$ atomic states of neon. The time-dependent Schr\"odinger equation is solved and the results are employed to compute the angular distribution and the associated anisotropy parameters at the main photoelectron line. We also employ a time-dependent perturbative approach, which allows obtaining information on the process for a large range of pulse parameters, including the steady-state case of continuous radiation, i.e., an infinitely long pulse. The results from the two methods are in relatively good agreement over the domain of applicability of perturbation theory

Vector parameters in atomic ionization by twisted light: polarization of electron and residual ion

The electron and ion properties observed in a photoionization inherit a symmetry properties of both a target and a radiation. Introducing a symmetry breaking in a photoionization process one can expect to observe a noticeable variation of the vector correlation parameters of either outgoing photoelectron or a residual ion. One of the ways to violate symmetry is to irradiate a matter by the twisted radiation which involves an additional screw. In the paper we present the extension of the approach developed in [Phys. Rev. A 108, 023117 (2023)] for the photoelectron angular distribution to the other vector correlation parameters, exactly photoelectron spin polarization, orientation and alignment of the residual ion. Usually two conditions are needed to produce polarized photoelectrons: a system possesses a helix and a noticeable spin-orbital interaction. In the paper we investigate if a twisted light brings an additional helicity to a system. As an illustrative example we consider ionization of valence $4p$-shell of atomic krypton by circularly and linearly polarized Bessel light. The photoelectron spin components are analyzed as a function of the cone angle of the twisted radiation

Displacement effect in strong-field atomic ionization by an XUV pulse

We study strong-field atomic ionization driven by an XUV pulse with a non\-zero displacement, the quantity defined as the integral of the pulse vector potential taken over the pulse duration. We demonstrate that the use of such pulses may lead to an extreme sensitivity of the ionization process to subtle changes of the parameters of a driving XUV pulse, in particular, the ramp-on/off profile and the carrier envelope phase. We illustrate this sensitivity for atomic hydrogen and lithium driven by few-femto\-second XUV pulses with intensity in the $\rm 10^{14}~W/cm^2$ range. We argue that the observed effect is general and should modify strong-field ionization of any atom, provided the ionization rate is sufficiently high.Comment: 5 pages, 7 figure

Interfering one-photon and two-photon ionization by femtosecond VUV pulses in the region of an intermediate resonance

The electron angular distribution after atomic photoionization by the fundamental frequency and its second harmonic is analyzed for a case when the frequency of the fundamental scans the region of an intermediate atomic state. The angular distribution and its left-right asymmetry, due to the two-pathway interference between nonresonant one-photon and resonant two-photon ionization, sharply change as a function of the photon energy. The phenomenon is exemplified by both solving the time-dependent Schr\"odinger equation on a numerical space-time grid and by applying perturbation theory for ionization of the hydrogen atom in the region of the 1s\text{\ensuremath{-}}2p transition for femtosecond pulses as well as an infinitely long exposure to the radiation. Parametrizations for the asymmetry and the anisotropy coefficients, obtained within perturbation theory, reveal general characteristics of observable quantities as functions of the parameters of the radiation beam

A new method for measuring angle-resolved phases in photoemission

Quantum mechanically, photoionization can be fully described by the complex photoionization amplitudes that describe the transition between the ground state and the continuum state. Knowledge of the value of the phase of these amplitudes has been a central interest in photoionization studies and newly developing attosecond science, since the phase can reveal important information about phenomena such as electron correlation. We present a new attosecond-precision interferometric method of angle-resolved measurement for the phase of the photoionization amplitudes, using two phase-locked Extreme Ultraviolet pulses of frequency $\omega$ and $2\omega$, from a Free-Electron Laser. Phase differences $\Delta \tilde \eta$ between one- and two-photon ionization channels, averaged over multiple wave packets, are extracted for neon $2p$ electrons as a function of emission angle at photoelectron energies 7.9, 10.2, and 16.6 eV. $\Delta \tilde \eta$ is nearly constant for emission parallel to the electric vector but increases at 10.2 eV for emission perpendicular to the electric vector. We model our observations with both perturbation and \textit{ab initio} theory, and find excellent agreement. In the existing method for attosecond measurement, Reconstruction of Attosecond Beating By Interference of Two-photon Transitions (RABBITT), a phase difference between two-photon pathways involving absorption and emission of an infrared photon is extracted. Our method can be used for extraction of a phase difference between single-photon and two-photon pathways and provides a new tool for attosecond science, which is complementary to RABBITT

Complex attosecond waveform synthesis at fel fermi

Free-electron lasers (FELs) can produce radiation in the short wavelength range extending from the extreme ultraviolet (XUV) to the X-rays with a few to a few tens of femtoseconds pulse duration. These facilities have enabled significant breakthroughs in the field of atomic, molecular, and optical physics, implementing different schemes based on two-color photoionization mechanisms. In this article, we present the generation of attosecond pulse trains (APTs) at the seeded FEL FERMI using the beating of multiple phase-locked harmonics. We demonstrate the complex attosecond waveform shaping of the generated APTs, exploiting the ability to manipulate independently the amplitudes and the phases of the harmonics. The described generalized attosecond waveform synthesis technique with an arbitrary number of phase-locked harmonics will allow the generation of sub-100 as pulses with programmable electric fields

Roadmap on photonic, electronic and atomic collision physics: I. Light-matter interaction

We publish three Roadmaps on photonic, electronic and atomic collision physics in order to celebrate the 60th anniversary of the ICPEAC conference. In Roadmap I, we focus on light-matter interaction. In this area, studies of ultrafast electronic and molecular dynamics have been rapidly growing, with the advent of new light sources such as attosecond lasers and X-ray free electron lasers. In parallel, experiments with established synchrotron radiation sources and femtosecond lasers using cutting- edge detection schemes are revealing new scientific insights that have never been exploited. Relevant theories are also being rapidly developed. Target samples for photon-impact experiments are expanding from atoms and small molecules to complex systems such as biomolecules, fullerene, clusters and solids. This Roadmap aims at looking back along the road, explaining the development of these fields, and looking forward, collecting contributions from twenty leading groups from the field

Angular distribution of photoelectrons generated in atomic ionization by twisted radiation

Until recently, theoretical and experimental studies of photoelectron angular distributions (PADs) including non-dipole effects in atomic photo\-ionization have been performed mainly for the conventional plane-wave radiation. One can expect, however, that the non-dipole contributions to the angular- and polarization-resolved photo\-ionization properties are enhanced if an atomic target is exposed to twisted light. The purpose of the present study is to develop a theory for PADs to the case of twisted light, especially for many-electron atoms. The theoretical analysis is performed for the experimentally relevant case of macroscopic atomic targets, i.e., when the cross-sectional area of the target is larger than the characteristic transversal size of the twisted beam. For such a scenario, we derive expressions for the angular distribution of the emitted photoelectrons under the influence of twisted Bessel beams. As an illustrative example, we consider helium photo\-ionization in the region of the lowest dipole $2s2p\,[{^1P}_1]$ and quadrupole $2p^2\,[{^1D}_2]$ autoionization resonances. A noticeable variation of the PAD caused by changing the parameters of the twisted light is predicted.Comment: One more reference has been added in the Introduction. English throughout the manuscript has been improve

Many particle spectroscopy of atoms, molecules, clusters and surfaces: international conference MPS-2016

The conference on Many Particle Spectroscopy of Atoms, Molecules, Clusters and Surfaces (MPS-2016) brought together near to a hundred scientists in the field of electronic, photonic, atomic and molecular collisions, and spectroscopy from around the world. We deliver an Editorial of a topical issue presenting original research results from some of the participants on both experimental and theoretical studies involving many particle spectroscopy of atoms, molecules, clusters and surfaces