11,097 research outputs found

    Resolving the structure of TiBe12_{12}

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    There has been considerable controversy regarding the structure of TiBe12_{12}, which is variously reported as hexagonal and tetragonal. Lattice dynamics simulations based on density functional theory show the tetragonal phase space group I4/mmmI4/mmm to be more stable over all temperatures, while the hexagonal phase exhibits an imaginary phonon mode, which, if followed, would lead to the cell adopting the tetragonal structure. We then report the predicted ground state elastic constants and temperature dependence of the bulk modulus and thermal expansion for the tetragonal phase.Comment: In press at Acta Crystallographica B. Supplementary material appende

    Evidence for Black Hole Growth in Local Analogs to Lyman Break Galaxies

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    We have used XMM-Newton to observe six Lyman Break Analogs (LBAs): members of the rare population of local galaxies that have properties that are very similar to distant Lyman Break Galaxies. Our six targets were specifically selected because they have optical emission-line properties that are intermediate between starbursts and Type 2 (obscured) AGN. Our new X-ray data provide an important diagnostic of the presence of an AGN. We find X-ray luminosities of order 10^{42} erg/s and ratios of X-ray to far-IR luminosities that are higher than values in pure starburst galaxies by factors ranging from ~ 3 to 30. This strongly suggests the presence of an AGN in at least some of the galaxies. The ratios of the luminosities of the hard (2-10 keV) X-ray to [O III]\lambda 5007 emission-line are low by about an order-of-magnitude compared to Type 1 AGN, but are consistent with the broad range seen in Type 2 AGN. Either the AGN hard X-rays are significantly obscured or the [O III] emission is dominated by the starburst. We searched for an iron emission line at ~ 6.4 keV, which is a key feature of obscured AGN, but only detected emission at the ~ 2\sigma level. Finally, we find that the ratios of the mid-infrared (24\mu m) continuum to [O III]\lambda 5007 luminosities in these LBAs are higher than the values for Type 2 AGN by an average of 0.8 dex. Combining all these clues, we conclude that an AGN is likely to be present, but that the bolometric luminosity is produced primarily by an intense starburst. If these black holes are radiating at the Eddington limit, their masses would lie in the range of 10^5 to 10^6 M_{sun}. These objects may offer ideal local laboratories to investigate the processes by which black holes grew in the early universe.Comment: Accepted for publication in Ap

    Effects of Gallium Doping in Garnet-Type Li7La3Zr2O12 Solid Electrolytes

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    Garnet-type Li7La3Zr2O12 (LLZrO) is a candidate solid electrolyte material that is now being intensively optimized for application in commercially competitive solid state Li+ ion batteries. In this study we investigate, by force-field-based simulations, the effects of Ga3+ doping in LLZrO. We confirm the stabilizing effect of Ga3+ on the cubic phase. We also determine that Ga3+ addition does not lead to any appreciable structural distortion. Li site connectivity is not significantly deteriorated by the Ga3+ addition (>90% connectivity retained up to x = 0.30 in Li7–3xGaxLa3Zr2O12). Interestingly, two compositional regions are predicted for bulk Li+ ion conductivity in the cubic phase: (i) a decreasing trend for 0 ≤ x ≤ 0.10 and (ii) a relatively flat trend for 0.10 < x ≤ 0.30. This conductivity behavior is explained by combining analyses using percolation theory, van Hove space time correlation, the radial distribution function, and trajectory density

    A Chandra observation of the ultraluminous infrared galaxy IRAS 19254--7245 (the Superantennae): X-ray emission from the Compton-thick AGN and the diffuse starburst

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    We present a {\it Chandra} observation of IRAS 19254--7245, a nearby ULIRG also known as {\it the Superantennae}. The high spatial resolution of {\it Chandra} allows us to disentangle for the first time the diffuse starburst emission from the embedded Compton-thick AGN. The 2-10 keV spectrum of the AGN emission is fitted by a flat power-law Γ=1.3\Gamma=1.3) and a He-like Fe Kα\alpha line with EW\sim1.5 keV, consistent with previous observations. The Fe Kα\alpha line profile could be resolved as a blend of a neutral 6.4 keV line and an ionized 6.7 keV (He-like) or 6.9 keV (H-like) line. Variability is detected compared with the previous {\it XMM-Newton} and {\it suzaku} observations, demonstrating the compact size of the iron line emission. We fit the spectrum of the galaxy-scale extended emission excluding the AGN and other bright point sources with a soft thermal component with kT~0.8 keV. The luminosity of the extended emission is about one order of magnitude lower than that of the AGN. The basic physical and structural properties of the extended emission are fully consistent with a galactic wind being driven by the starburst (no contribution to the feedback by the AGN is required). A candidate ultra-luminous X-ray source is detected 8\arcsec\ south of the southern nucleus. The 0.3-10 keV luminosity of this off-nuclear point source is ~6×10406\times 10^{40} erg s1^{-1} if the emission is isotropic and the source is associated with the Superantennae.Comment: 31 pages, 10 figures, submitted to Ap

    Hydrogen solubility in zirconium intermetallic second phase particles

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    The enthalpies of solution of H in Zr binary intermetallic compounds formed with Cu, Cr, Fe, Mo, Ni, Nb, Sn and V were calculated by means of density functional theory simulations and compared to that of H in {\alpha}-Zr. It is predicted that all Zr-rich phases (formed with Cu, Fe, Ni and Sn), and those phases formed with Nb and V, offer lower energy, more stable sites for H than {\alpha}-Zr. Conversely, Mo and Cr containing phases do not provide preferential solution sites for H. In all cases the most stable site for H are those that offer the highest coordination fraction of Zr atoms. Often these are four Zr tetrahedra but not always. Implications with respect to H-trapping properties of commonly observed ternary phases such as Zr(Cr,Fe)2, Zr2(Fe,Ni) and Zr(Nb,Fe)2 are also discussed.Comment: manuscript accepted for publication in Journal of Nuclear Materials (2013

    Enhancing efficiency of single, large-aperture antennas

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    Numerical analysis method provides means of describing energy distribution in focal plane of parabolic surface in terms of phase and wavelength. Two approaches for enhancing antenna efficiency include single, large reflector focused to feeding element, and array of smaller apertures whose individual outputs are summed

    Ethnic identity and aspirations among rural Alaska youth

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    The villages of rural Alaska comprise one of the most exceptional, yet least visible, sociocultural environments in the United States They are geographically remote, and set off from the mainstream also by their unique Eskimo, Indian or Aleut cultures. At the same time many economic, legal and cultural connections pull these villages toward the dominant U.S. society, impelling continual and rapid social change. Our research focuses on adolescents growing up in this culturally complex and changing environment. We employ survey data from adolescents in 19 rural schools to explore relationships between ethnic identity and students\u27 expectations about moving away or attending college. Many students describe their ethnic identity as mixed, both Native and non-Native. On some key variables, the responses of mixed-identity students fall between those of Natives and non-Natives, supporting a theoretical conception of ethnicity as a matter of degree rather than category. Migration and college expectations vary with ethnic identity, but the college expectations/identity relationship fades when we adjust for other variables. Ethnicity affects expectations for the most part indirectly, through “cultural tool kit” variables including family role models and support. Gender differences in expectations, on the other hand, remain substantial even after adjusting for other variables

    A 1974 survey of large-scale hog production in the U.S.

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