Activated carbons as catalytic support for Cu nanoparticles

There are a wide range of catalytic applications for Cu-based nanoparticles materials, since Cu is an abundant and inexpensive metal and Cu nanoparticles possess unusual electrical, thermal and optical properties. The possible modification of the chemical and physical properties of these nanoparticles using different synthetic strategies and conditions and/or via postsynthetic chemical treatments has been largely responsible for the rapid growth of interest in these nanomaterials and their applications in catalysis. A previous work have explored the possibilities of SBA-15 (1,2) as support for Cu nanoparticles. In the present contribution, those results will be compared with the use of a carbon material as support, since activated carbon present many advantages with respect SBA, as the high surface area.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

Gigantism: microsurgical treatment by transsphenoidal approach and prognostic factors

Purpose: We present the results of transsphenoidal microsurgical treatment in 14 patients with gigantism. The influence on the prognosis of factors such as the tumor size and preoperative levels of GH and IGF-1 is also quantified. Materials and methods: The patients, operated between 1982 and 2004, were reviewed retrospectively in June 2022. All patients had complete endocrinological studies in the preoperative period and a postoperative control between 6 days and 3 weeks. Follow-up has been supported with annual check-ups between 3 and 31 years. We have compared the preoperative levels of GH and IGF-1 of these patients with the levels of a series of acromegalic patients operated on in the same Center. Results: In this series there were 4 women and 10 men. The age ranged between 14 and 21 years. In 6 patients, postoperative hormone levels achieved the disease control criteria (42.8%). The CT/MRI studies revealed the existence of invasive tumors in 10 of the patients (71.4%). Postoperative CT/MRI showed no tumor tissue in 3 patients but in 7 patients there were tumor remains. The remaining 4 patients had abnormal images although not considered as tumor. A statistical comparison of preoperative serum GH and IGF-1 levels in patients with gigantism and patients with acromegaly showed a significant elevation in the former. Conclusion: Pituitary adenomas that cause gigantism are generally large and invasive, which makes them difficult to cure. High preoperative levels of GH and IGF-1 are also factors that decrease remission

Microbial rDNA sequences as markers to determine microbial synthesis in Rusitec fermenters: A comparison with 15N

Microbial rDNA sequences have been proposed as potential internal markers to determine microbial synthesis in the rumen. The objective of this experiment was to compare values of microbial growth determined using 15N as external marker with concentrations of microbial DNA in fermenters, and to assess if both procedures detected similar differences between diets and solid (SOL) and liquid (LIQ) digesta phases

Analysis of famnily interviews in uncontrolled donors after cardiac death.

pre-print616 K

Multi-phase feedback processes in the Sy2 galaxy NGC 5643

We study the multi-phase feedback processes in the central ~3 kpc of the barred Sy 2 galaxy NGC 5643. We use observations of the cold molecular gas (ALMA CO(2-1)) and ionized gas (MUSE IFU). We study different regions along the outflow zone which extends out to ~2.3 kpc in the same direction (east-west) as the radio jet, as well as nuclear/circumnuclear regions in the host galaxy disk. The deprojected outflowing velocities of the cold molecular gas (median Vcentral~189 km s^-1) are generally lower than those of the outflowing ionized gas, which reach deprojected velocities of up to 750 km s^-1 close to the AGN, and their spatial profiles follow those of the ionized phase. This suggests that the outflowing molecular gas in the galaxy disk is being entrained by the AGN wind. We derive molecular and ionized outflow masses of ~5.2x10^7 Msun and 8.5x10^4 Msun and molecular and ionized outflow mass rates of ~51 Msun yr^-1 and 0.14 Msun yr^-1. Therefore, the molecular phase dominates the outflow mass and outflow mass rate, while the outflow kinetic power and momentum are similar in both phases. However, the wind momentum load for the molecular and ionized outflow phases are ~27-5 and <1, which suggests that the molecular phase is not momentum conserving while the ionized one most certainly is. The molecular gas content (~1.5x10^7 Msun) of the eastern spiral arm is approximately 50-70% of the content of the western one. We interpret this as destruction/clearing of the molecular gas produced by the AGN wind impacting in the host galaxy. The increase of the molecular phase momentum implies that part of the kinetic energy from the AGN wind is transmitted to the molecular outflow. This suggest that in Sy-like AGN such as NGC 5643, the radiative/quasar and the kinetic/radio AGN feedback modes coexist and may shape the host galaxies even at kpc-scales via both positive and (mild) negative feedback.Comment: 26 pages, 21 figures, 5 tables. Astronomy and Astrophysics, Accepted 2020 September 11, in pres

Accelerated and Scalable C(sp³)-H Amination via Decatungstate Photocatalysis Using a Flow Photoreactor Equipped with High-Intensity LEDs

[Image: see text] Carbon–nitrogen bonds are ubiquitous in biologically active compounds, prompting synthetic chemists to design various methodologies for their preparation. Arguably, the ideal synthetic approach is to be able to directly convert omnipresent C–H bonds in organic molecules, enabling even late-stage functionalization of complex organic scaffolds. While this approach has been thoroughly investigated for C(sp(2))–H bonds, only few examples have been reported for the direct amination of aliphatic C(sp(3))–H bonds. Herein, we report the use of a newly developed flow photoreactor equipped with high intensity chip-on-board LED technology (144 W optical power) to trigger the regioselective and scalable C(sp(3))–H amination via decatungstate photocatalysis. This high-intensity reactor platform enables simultaneously fast results gathering and scalability in a single device, thus bridging the gap between academic discovery (mmol scale) and industrial production (>2 kg/day productivity). The photocatalytic transformation is amenable to the conversion of both activated and nonactivated hydrocarbons, leading to protected hydrazine products by reaction with azodicarboxylates. We further validated the robustness of our manifold by designing telescoped flow approaches for the synthesis of pyrazoles, phthalazinones and free amines

H-alpha kinematics of S4G spiral galaxies-II. Data description and non-circular motions

We present a kinematical study of 29 spiral galaxies included in the Spitzer Survey of Stellar Structure in Galaxies, using Halpha Fabry-Perot data obtained with the Galaxy Halpha Fabry-Perot System instrument at the William Herschel Telescope in La Palma, complemented with images in the R-band and in Halpha. The primary goal is to study the evolution and properties of the main structural components of galaxies through the kinematical analysis of the FP data, complemented with studies of morphology, star formation and mass distribution. In this paper we describe how the FP data have been obtained, processed and analysed. We present the resulting moment maps, rotation curves, velocity model maps and residual maps. Images are available in FITS format through the NASA/IPAC Extragalactic Database and the Centre de Donn\'ees Stellaires. With these data products we study the non-circular motions, in particular those found along the bars and spiral arms. The data indicate that the amplitude of the non-circular motions created by the bar does not correlate with the bar strength indicators. The amplitude of those non-circular motions in the spiral arms does not correlate with either arm class or star formation rate along the spiral arms. This implies that the presence and the magnitude of the streaming motions in the arms is a local phenomenon.Comment: 23 pages, 14 figures, without appendices, accepted to be published in MNRA