Exfoliated graphite flakes as soft-electrodes for precisely contacting nanoobjects

This is the post-peer reviewed version of the following article: P. ares et al. “Exfoliated graphite flakes as soft-electrodes for precisely contacting nanoobjects”. 2D Matererials, 2015, 2(3): 035008. Which has been published in final form at:http://dx.doi.org/10.1088/2053-1583/2/3/035008We introduce a simple, clean and reliable method to transfer exfoliated graphite flakes as soft-electrodes for the electrical contacts of nano-objects. The microelectrodes thus produced exhibit extremely well-defined and thin edges and can be placed at any sample location with sub-micrometer precision. The procedure is carried out under ambient conditions and does not require chemical agents. We present electrical characterization of relevant examples including carbon nanotubes, metal-organic MMX nanoribbons, reduced graphene sheets and damaged circuit repair. The quality of the electrical contacts thus obtained is as good as those fabricated with conventional techniques. This technique is particularly relevant for conductive atomic force microscopy (AFM) studiesThis work was supported by Consolider CSD2010-0024, MAD2D-CM, S2013/MIT-3007 and MAT2013-46753-C2-1 and

THE ADVANTAGES OF EVAPORATION IN MICRO-SCALE CHANNELS TO COOL MICROELETRONIC DEVICES

In this paper, the importance of the development of new high power density thermal management systems for electronic devices is assessed. It is described the new heat sink technologies under development to be used in the cooling of microprocessors. The main difficulties to be overcome before the spreading of one specific heat sink configuration are identified. At the end, it is concluded that a heat sink based on flow boiling in micro-scale channels is the most promising approach

Assessment of the Production of Value-Added Chemical Compounds from Sewage Sludge Pyrolysis Liquids

A procedure to analyze sewage sludge (SS) pyrolysis liquids based on solvent fractionation has been developed. Pyrolysis liquids are separated into three different fractions: heptane soluble (Hep-sol), dichloromethane soluble (DCM-sol), and hydrochloric acid soluble (HCl-sol). Diverse techniques (GC-MS, UPLC-TOF-MS) were employed to qualitatively and quantitatively analyze liquid fractions to assess the potential production of value-added chemicals. Aliphatic hydrocarbons, aliphatic nitriles, and steroids were mostly separated in the Hep-sol fraction, phenols and fatty acids in the DCM-sol fraction, and carboxylic acids and amides in the HCl-sol fraction. The largest production was obtained for ammonia (10–14 kg per tonne of SS) and a-olefins (8–9 kg per tonne of SS). The potential production of some of these value-added chemicals from SS pyrolysis liquid was compared with their current European production. In the case of a-olefins, 16 % of their European production could be achieved by SS pyrolysis

Removing Cool Cores and Central Metallicity Peaks in Galaxy Clusters with Powerful AGN Outbursts

Recent X-ray observations of galaxy clusters suggest that cluster populations are bimodally distributed according to central gas entropy and are separated into two distinct classes: cool core (CC) and non-cool core (NCC) clusters. While it is widely accepted that AGN feedback plays a key role in offsetting radiative losses and maintaining many clusters in the CC state, the origin of NCC clusters is much less clear. At the same time, a handful of extremely powerful AGN outbursts have recently been detected in clusters, with a total energy ~10^{61}-10^{62} erg. Using two dimensional hydrodynamic simulations, we show that if a large fraction of this energy is deposited near the centers of CC clusters, which is likely common due to dense cores, these AGN outbursts can completely remove CCs, transforming them to NCC clusters. Our model also has interesting implications for cluster abundance profiles, which usually show a central peak in CC systems. Our calculations indicate that during the CC to NCC transformation, AGN outbursts efficiently mix metals in cluster central regions, and may even remove central abundance peaks if they are not broad enough. For CC clusters with broad central abundance peaks, AGN outbursts decrease peak abundances, but can not effectively destroy the peaks. Our model may simultaneously explain the contradictory (possibly bimodal) results of abundance profiles in NCC clusters, some of which are nearly flat, while others have strong central peaks similar to those in CC clusters. A statistical analysis of the sizes of central abundance peaks and their redshift evolution may shed interesting insights on the origin of both types of NCC clusters and the evolution history of thermodynamics and AGN activity in clusters.Comment: Slightly revised version, accepted for publication in ApJ. 12 pages, 11 figure

Perspectives of regional paleoclimate modeling

Regional climate modeling bridges the gap between the coarse resolution of current global climate models and the regional‐to‐local scales, where the impacts of climate change are of primary interest. Here, we present a review of the added value of the regional climate modeling approach within the scope of paleoclimate research and discuss the current major challenges and perspectives. Two time periods serve as an example: the Holocene, including the Last Millennium, and the Last Glacial Maximum. Reviewing the existing literature reveals the benefits of regional paleo climate modeling, particularly over areas with complex terrain. However, this depends largely on the variable of interest, as the added value of regional modeling arises from a more realistic representation of physical processes and climate feedbacks compared to global climate models, and this affects different climate variables in various ways. In particular, hydrological processes have been shown to be better represented in regional models, and they can deliver more realistic meteorological data to drive ice sheet and glacier modeling. Thus, regional climate models provide a clear benefit to answer fundamental paleoclimate research questions and may be key to advance a meaningful joint interpretation of climate model and proxy data

Long-Term Carbon Sequestration in Pine Forests under Different Silvicultural and Climatic Regimes in Spain

Proactive silviculture treatments (e.g., thinning) may increase C sequestration contributing to climate change mitigation, although, there are still questions about this effect in Mediterranean pine forests. The aim of this research was to quantify the storage of biomass and soil organic carbon in Pinus forests along a climatic gradient from North to South of the Iberian Peninsula. Nine experimental Pinus spp trials were selected along a latitudinal gradient from the pre-Pyrenees to southern Spain. At each location, a homogeneous area was used as the operational scale, and three thinning intensity treatments: unthinned or control (C), intermediate thinning (LT, removal of 30–40% of the initial basal area) and heavy thinning (HT, removal of 50–60%) were conducted. Growth per unit area (e.g., expressed as basal area increment-BAI), biomass, and Soil Organic Carbon (SOC) were measured as well as three sets of environmental variables (climate, soil water availability and soil chemical and physical characteristics). One-way ANOVA and Structural Equation Modelling (SEM) were used to study the effect of thinning and environmental variables on C sequestration. Biomass and growth per unit area were higher in the control than in the thinning treatments, although differences were only significant for P. halepensis. Radial growth recovered after thinning in all species, but it was faster in the HT treatments. Soil organic carbon (SOC10, 0–10 cm depth) was higher in the HT treatments for P. halepensis and P. sylvestris, but not for P. nigra. SEM showed that Pinus stands of the studied species were beneficed by HT thinning, recovering their growth quickly. The resulting model explained 72% of the variation in SOC10 content, and 89% of the variation in silvicultural condition (basal area and density) after thinning. SOC10 was better related to climate than to silvicultural treatments. On the other hand, soil chemical and physical characteristics did not show significant influence over SOC10- Soil water availability was the latent variable with the highest influence over SOC10. This work is a new contribution that shows the need for forest managers to integrate silviculture and C sequestration in Mediterranean pine plantations

Detection of antibodies against bovine viral diarrhoea virus in goats of four provinces of Lima, Peru

El objetivo del presente estudio fue determinar anticuerpos contra el virus de la diarrea viral bovina (VDVB) en muestras de suero de caprinos adultos, hembras y machos, de crianza estabulada, semi-extensiva y trashumante, pertenecientes a 89 criadores de cuatro provincias del departamento de Lima: Huaura (n=196), Huaral (n=233), Canta (n=153) y Lima (n=172). La detección de los anticuerpos neutralizantes contra el VDVB en muestras de suero (n=754) se hizo mediante la prueba de neutralización viral. El 1.2% (9/754) de las muestras presentaron anticuerpos contra el VDVB. Las muestras serorreactoras fueron de cabras de crianza trashumante de las provincias de Canta y Huaura.The aim of this study was to determine antibodies against the bovine viral diarrhea virus (BVDv) in serum samples of adult goats, females and males, of intensive, semi-extensive and transhumant production systems, from 89 farmers of four provinces of the department of Lima: Huaura (n=196), Huaral (n=233), Canta (n=153) and Lima (n=172). The detection of neutralizing antibodies against the BVDv in serum samples (n=754) was done by the viral neutralization test. The results showed that 1.2% (9/754) of the samples had antibodies against the virus. Seroreactive samples were from transhumant goats from the provinces of Canta and Huaura

On the identification of merger debris in the {\it Gaia} Era

We model the formation of the Galactic stellar halo via the accretion of satellite galaxies onto a time-dependent semi-cosmological galactic potential. Our goal is to characterize the substructure left by these accretion events in a close manner to what may be possible with the {\it Gaia} mission. We have created a synthetic {\it Gaia} Solar Neighbourhood catalogue by convolving the 6D phase-space coordinates of stellar particles from our disrupted satellites with the latest estimates of the {\it Gaia} measurement errors, and included realistic background contamination due to the Galactic disc(s) and bulge. We find that, even after accounting for the expected observational errors, the resulting phase-space is full of substructure. We are able to successfully isolate roughly 50% of the different satellites contributing to the `Solar Neighbourhood' by applying the Mean-Shift clustering algorithm in energy-angular momentum space. Furthermore, a Fourier analysis of the space of orbital frequencies allows us to obtain accurate estimates of time since accretion for approximately 30% of the recovered satellites.Comment: 13 pages, 11 figures, submitted to MNRA