181 research outputs found
Effects of different long-term soil management systems on some physical and chemical properties and crop production in soils in Berlin-Dahlem and Dedelow- Zalf Müncheberg (Germany)
Soil management systems influence the agricultural system as they have in short- and long term period different
effects on soil physical and chemical properties, therefore influencing the efficiency of production as well. A
well directed choice of tillage equipments leads to a better soil protection and enables a higher fertility which is
an important requirement for sustainable agriculture. The aim of this study is to investigate the effects of
different soil management systems on some physical and chemical properties and the crop production of these
sandy soils. This study demonstrates the first results obtained from the year 2006, performed on the long-term
land use experiment with the effects of three different factors (deep and shallow tillage; 17 and 28 cm, lime
application; +Ca and –Ca and Farmyard manure; +FYM and –FYM) in Berlin-Dahlem (Germany), Humboldt
University of Berlin and the ZALF experimental station at Dedelow (Germany) in 5 different tillage systems
(no-tillage, mulch; 10 cm, cultivator; 15 cm, plough; 15 cm and plough; 25 cm).
The soil heterogeneity were determined and evaluated with the computer program “Surfer” depending on the
different depths of the sand and loam layers. The penetration resistances of both experimental fields showed that
the deep tillage systems caused a higher compacted zone in deeper soil layers. It was found that there are
significant differences in the soil aggregate stability and pH values between the shallow and deep tillage systems
in Berlin-Dahlem. The pH values were significantly higher in the deep tillage systems. The soil organic matter
contents were found higher in the deep tillage systems but there were no significant differences. There were also
no significant differences in grain yield between these two tillage systems in Berlin-Dahlem
Self-organization of (001) cubic crystal surfaces
Self-organization on crystal surface is studied as a two dimensional spinodal
decomposition in presence of a surface stress. The elastic Green function is
calculated for a cubic crystal surface taking into account the crystal
anisotropy. Numerical calculations show that the phase separation is driven by
the interplay between domain boundary energy and long range elastic
interactions. At late stage of the phase separation process, a steady state
appears with different nanometric patterns according to the surface coverage
and the crystal elastic constants
Atomistic mechanisms for the ordered growth of Co nano-dots on Au(788): comparison of VT-STM experiments and multi-scaled calculations
Hetero-epitaxial growth on a strain-relief vicinal patterned substrate has
revealed unprecedented 2D long range ordered growth of uniform cobalt
nanostructures. The morphology of a Co sub-monolayer deposit on a Au(111)
reconstructed vicinal surface is analyzed by Variable Temperature Scanning
Tunneling Microscopy (VT-STM) experiments. A rectangular array of nano-dots
(3.8 nm x 7.2 nm) is found for a particularly large deposit temperature range
lying from 60 K to 300 K. Although the nanodot lattice is stable at room
temperature, this paper focus on the early stage of ordered nucleation and
growth at temperatures between 35 K and 480 K. The atomistic mechanisms leading
to the nanodots array are elucidated by comparing statistical analysis of
VT-STM images with multi-scaled numerical calculations combining both Molecular
Dynamics for the quantitative determination of the activation energies for the
atomic motion and the Kinetic Monte Carlo method for the simulations of the
mesoscopic time and scale evolution of the Co submonolayer
The suppression of fluorescence peaks in energy-dispersive X-ray diffraction
A novel method to separate diffraction and fluorescence peaks in energy-
dispersive X-ray diffraction (EDXRD) is described. By tuning the excitation energy of an X-ray tube source to just below an elemental absorption edge, the corresponding fluorescence peaks of that element are completely suppressed in the resulting spectrum. Since Bremsstrahlung photons are present in the source spectrum up to the excitation energy, any diffraction peaks that lie at similar energies to the suppressed fluorescence peaks are uncovered. This technique is an alternative to the more usual method in EDXRD of altering the scattering angle in order to shift the energies of the diffraction peaks. However, in the back-reflection EDXRD technique [Hansford (2011). J. Appl. Cryst. 44, 514–525] changing the scattering angle would lose the unique property of insensitivity to sample morphology and is therefore an unattractive option. The use of fluorescence suppression to reveal diffraction peaks is demonstrated experimentally by suppressing the Ca K fluorescence peaks in the back-reflection EDXRD spectra of several limestones and dolomites. Three substantial benefits are derived: uncovering of diffraction peak(s) that are otherwise obscured by fluorescence; suppression of the Ca K escape peaks; and an increase in the signal-to-background ratio. The improvement in the quality of the EDXRD spectrum allows the identification of a secondary mineral in the samples, where present. The results for a pressed-powder pellet of the geological standard JDo-1 (dolomite) show the presence of crystallite preferred orientation in this prepared sample. Preferred orientation is absent in several unprepared limestone and dolomite rock specimens, illustrating an advantage of the observation of rocks in their natural state enabled by back-reflection EDXRD
One-Step Synthesis of Monodisperse In-Doped ZnO Nanocrystals
A method for the synthesis of high quality indium-doped zinc oxide (In-doped ZnO) nanocrystals was developed using a one-step ester elimination reaction based on alcoholysis of metal carboxylate salts. The resulting nearly monodisperse nanocrystals are well-crystallized with typically crystal structure identical to that of wurtzite type of ZnO. Structural, optical, and elemental analyses on the products indicate the incorporation of indium into the host ZnO lattices. The individual nanocrystals with cubic structures were observed in the 5% In–ZnO reaction, due to the relatively high reactivity of indium precursors. Our study would provide further insights for the growth of doped oxide nanocrystals, and deepen the understanding of doping process in colloidal nanocrystal syntheses
Identification and design principles of low hole effective mass p-type transparent conducting oxides
The development of high-performance transparent conducting oxides is critical to many technologies from transparent electronics to solar cells. Whereas n-type transparent conducting oxides are present in many devices, their p-type counterparts are not largely commercialized, as they exhibit much lower carrier mobilities due to the large hole effective masses of most oxides. Here we conduct a high-throughput computational search on thousands of binary and ternary oxides and identify several highly promising compounds displaying exceptionally low hole effective masses (up to an order of magnitude lower than state-of-the-art p-type transparent conducting oxides), as well as wide band gaps. In addition to the discovery of specific compounds, the chemical rationalization of our findings opens new directions, beyond current Cu-based chemistries, for the design and development of future p-type transparent conducting oxides.United States. Office of Naval Research (Award N00014-11-1-0212
Pbca-Type In2O3: the high-pressure post-corundum phase at room temperature
This document is the Accepted Manuscript version of a Published Work that appeared in final form in
Journal of Physical Chemistry C, copyright © American Chemical Society after peer review and technical editing by the publisher.
To access the final edited and published work see http://dx.doi.org/10.1021/jp5061599High-pressure powder X-ray diffraction and Raman scattering measurements in cubic bixbyite-type indium oxide (c-In2O3) have been performed at room temperature. On increasing pressure c-In2O3 undergoes a transition to the Rh2O3-II structure but on decreasing pressure Rh2O3-II-type In2O3 undergoes a transition to a previously unknown phase with Pbca space group which is isostructural to Rh2O3-III. On further decrease of pressure, we observed a phase transition to the metastable corundum-type In2O3 near room conditions. Recompression of the metastable corundum-type In2O3 at room temperature leads to a transition to the Rh2O3-III phase, thus showing that the Rh2O3-III phase is the post-corundum phase at room temperature. Our results are supported by theoretical ab initio calculations. Furthermore, they show that the Rh2O3-III phase could be present in other sesquioxides, thus prompting to a revision of the pressure-temperature phase diagrams of sesquioxidesFinancial support by the Spanish MEC under Grant No. MAT2010-21270-C04-01/03/04, MAT2013-46649-C4-1/2/3-P, by MALTA Consolider Ingenio 2010 project (CSD2007-00045) and by Generalitat Valenciana (GVA-ACOMP-2013-012). Red Espanola de Supercomputacion (RES) and ALBA Synchrotron Light Source are also acknowledged. B.G.-D. and J.A.S. acknowledge financial support through the FPI program and Juan de la Cierva fellowship, respectively. We also thank J. L. Jorda for fruitful discussions. A.L.J.P. acknowledges financial support through Brazilian CNPq. A.S. expresses thanks to FEDER Grant UNLV10-3E-1253 for financial support.García-Domene, B.; Sans Tresserras, JÁ.; Gomis, O.; Manjón Herrera, FJ.; Ortiz, HM.; Errandonea, D.; Santamaría Pérez, D.... (2014). Pbca-Type In2O3: the high-pressure post-corundum phase at room temperature. Journal of Physical Chemistry C. 118(35):20545-20552. https://doi.org/10.1021/jp5061599S20545205521183
Tuning of Electrical and Optical Properties of Highly Conducting and Transparent Ta-Doped TiO2 Polycrystalline Films
We present a detailed study on polycrystalline transparent conducting Ta-doped TiO2 films, obtained by room temperature pulsed laser deposition followed by an annealing treatment at 550°C in vacuum. The effect of Ta as a dopant element and of different synthesis conditions are explored in order to assess the relationship between material structure and functional properties, i.e. electrical conductivity and optical transparency. We show that for the doped samples it is possible to achieve low resistivity (of the order of 5×10-4 Ωcm) coupled with transmittance values exceeding 80% in the visible range, showing the potential of polycrystalline Ta:TiO2 for application as a transparent electrode in novel photovoltaic devices. The presence of trends in the structural (crystalline domain size, anatase cell parameters), electrical (resistivity, charge carrier density and mobility) and optical (transmittance, optical band gap, effective mass) properties as a function of the oxygen background pressures and laser fluence used during the deposition process and of the annealing atmosphere is discussed, and points towards a complex defect chemistry ruling the material behavior. The large mobility values obtained in this work for Ta:TiO2 polycrystalline films (up to 13 cm2V-1s-1) could represent a definitive advantage with respect to the more studied Nb-doped TiO2
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