1,378 research outputs found
Shocks in dense clouds. IV. Effects of grain-grain processing on molecular line emission
Grain-grain processing has been shown to be an indispensable ingredient of
shock modelling in high density environments. For densities higher than
\sim10^5 cm-3, shattering becomes a self-enhanced process that imposes severe
chemical and dynamical consequences on the shock characteristics. Shattering is
accompanied by the vaporization of grains, which can directly release SiO to
the gas phase. Given that SiO rotational line radiation is used as a major
tracer of shocks in dense clouds, it is crucial to understand the influence of
vaporization on SiO line emission. We have developed a recipe for implementing
the effects of shattering and vaporization into a 2-fluid shock model,
resulting in a reduction of computation time by a factor \sim100 compared to a
multi-fluid modelling approach. This implementation was combined with an
LVG-based modelling of molecular line radiation transport. Using this model we
calculated grids of shock models to explore the consequences of different
dust-processing scenarios. Grain-grain processing is shown to have a strong
influence on C-type shocks for a broad range of magnetic fields: they become
hotter and thinner. The reduction in column density of shocked gas lowers the
intensity of molecular lines, at the same time as higher peak temperatures
increase the intensity of highly excited transitions compared to shocks without
grain-grain processing. For OH the net effect is an increase in line
intensities, while for CO and H2O it is the contrary. The intensity of H2
emission is decreased in low transitions and increased for highly excited
lines. For all molecules, the highly excited lines become sensitive to the
value of the magnetic field. Although vaporization increases the intensity of
SiO rotational lines, this effect is weakened by the reduced shock width. The
release of SiO early in the hot shock changes the excitation characteristics of
SiO radiation.Comment: Published in Astronomy and Astrophysics (2013). 26 pages, 16 figures,
14 table
Processing and Transmission of Information
Contains reports on four research projects.National Aeronautics and Space Administration (Grant NGL 22-009-013)Joint Services Electronics Program (Contract DAAB07-71-C-0300
Efficient calculation of van der Waals dispersion coefficients with time-dependent density functional theory in real time: application to polycyclic aromatic hydrocarbons
The van der Waals dispersion coefficients of a set of polycyclic aromatic
hydrocarbons, ranging in size from the single-cycle benzene to circumovalene
(C66H20), are calculated with a real-time propagation approach to
time-dependent density functional theory (TDDFT). In the non-retarded regime,
the Casimir-Polder integral is employed to obtain C6, once the dynamic
polarizabilities have been computed at imaginary frequencies with TDDFT. On the
other hand, the numerical coefficient that characterizes the fully retarded
regime is obtained from the static polarizabilities. This ab initio strategy
has favorable scaling with the size of the system - as demonstrated by the size
of the reported molecules - and can be easily extended to obtain higher order
van der Waals coefficients.Comment: submitted to J. Chem. Phy
Massive expanding torus and fast outflow in planetary nebula NGC 6302
We present interferometric observations of CO and CO =21
emission from the butterfly-shaped, young planetary nebula NGC 6302. The high
angular resolution and high sensitivity achieved in our observations allow us
to resolve the nebula into two distinct kinematic components: (1) a massive
expanding torus seen almost edge-on and oriented in the North-South direction,
roughly perpendicular to the optical nebula axis. The torus exhibits very
complex and fragmentated structure; (2) high velocity molecular knots moving at
high velocity, higher than 20 \kms, and located in the optical bipolar lobes.
These knots show a linear position-velocity gradient (Hubble-like flow), which
is characteristic of fast molecular outflow in young planetary nebulae. From
the low but variable CO/CO =21 line intensity ratio we
conclude that the CO =21 emission is optically thick over much of
the nebula. Using the optically thinner line CO =21 we estimate a
total molecular gas mass of 0.1 M, comparable to the ionized gas
mass; the total gas mass of the NGC 6302 nebula, including the massive ionized
gas from photon dominated region, is found to be 0.5 M. From
radiative transfer modelling we infer that the torus is seen at inclination
angle of 75 with respect to the plane of the sky and expanding at
velocity of 15 \kms. Comparison with recent observations of molecular gas in
NGC 6302 is also discussed.Comment: 24 pages, 7 figures, accepted for publication in Astrophysical
Journa
Advanced Software for Analysis of High-Speed Rolling-Element Bearings
COBRA-AHS is a package of advanced software for analysis of rigid or flexible shaft systems supported by rolling-element bearings operating at high speeds under complex mechanical and thermal loads. These loads can include centrifugal and thermal loads generated by motions of bearing components. COBRA-AHS offers several improvements over prior commercial bearing-analysis programs: It includes innovative probabilistic fatigue-life-estimating software that provides for computation of three-dimensional stress fields and incorporates stress-based (in contradistinction to prior load-based) mathematical models of fatigue life. It interacts automatically with the ANSYS finite-element code to generate finite-element models for estimating distributions of temperature and temperature-induced changes in dimensions in iterative thermal/dimensional analyses: thus, for example, it can be used to predict changes in clearances and thermal lockup. COBRA-AHS provides an improved graphical user interface that facilitates the iterative cycle of analysis and design by providing analysis results quickly in graphical form, enabling the user to control interactive runs without leaving the program environment, and facilitating transfer of plots and printed results for inclusion in design reports. Additional features include roller-edge stress prediction and influence of shaft and housing distortion on bearing performance
Formation of Hydrogen, Oxygen, and Hydrogen Peroxide in Electron Irradiated Crystalline Water Ice
Water ice is abundant both astrophysically, for example in molecular clouds,
and in planetary systems. The Kuiper belt objects, many satellites of the outer
solar system, the nuclei of comets and some planetary rings are all known to be
water-rich. Processing of water ice by energetic particles and ultraviolet
photons plays an important role in astrochemistry. To explore the detailed
nature of this processing, we have conducted a systematic laboratory study of
the irradiation of crystalline water ice in an ultrahigh vacuum setup by
energetic electrons holding a linear energy transfer of 4.3 +/- 0.1 keV mm-1.
The irradiated samples were monitored during the experiment both on line and in
situ via mass spectrometry (gas phase) and Fourier transform infrared
spectroscopy (solid state). We observed the production of hydrogen and oxygen,
both molecular and atomic, and of hydrogen peroxide. The likely reaction
mechanisms responsible for these species are discussed. Additional formation
routes were derived from the sublimation profiles of molecular hydrogen (90-140
K), molecular oxygen (147 -151 K) and hydrogen peroxide (170 K). We also
present evidence on the involvement of hydroxyl radicals and possibly oxygen
atoms as building blocks to yield hydrogen peroxide at low temperatures (12 K)
and via a diffusion-controlled mechanism in the warming up phase of the
irradiated sample.Comment: ApJ, March 2006, v639 issue, 43 pages, 7 figure
T-cell epitope prediction and immune complex simulation using molecular dynamics: state of the art and persisting challenges
Atomistic Molecular Dynamics provides powerful and flexible tools for the prediction and analysis of molecular and macromolecular systems. Specifically, it provides a means by which we can measure theoretically that which cannot be measured experimentally: the dynamic time-evolution of complex systems comprising atoms and molecules. It is particularly suitable for the simulation and analysis of the otherwise inaccessible details of MHC-peptide interaction and, on a larger scale, the simulation of the immune synapse. Progress has been relatively tentative yet the emergence of truly high-performance computing and the development of coarse-grained simulation now offers us the hope of accurately predicting thermodynamic parameters and of simulating not merely a handful of proteins but larger, longer simulations comprising thousands of protein molecules and the cellular scale structures they form. We exemplify this within the context of immunoinformatics
State-resolved rotational cross sections and thermal rate coefficients for ortho-/para-H2+HD at low temperatures and HD+HD elastic scattering
Results for quantum mechanical calculations of the integral cross sections
and corresponding thermal rate coefficients for para-/ortho-H2+HD collisions
are presented. Because of significant astrophysical interest in regard to the
cooling of primodial gas the low temperature limit of para-/ortho-H2+HD is
investigated. Sharp resonances in the rotational state-resolved cross sections
have been calculated at low energies. These resonances are important and
significantly contribute to the corresponding rotational state-resolved thermal
rate coefficients, particularly at low temperatures, that is less than K. Additionally in this work, the cross sections for the elastic HD+HD
collision have also been calculated. We obtained quite satisfactory agreement
with the results of other theoretical works and experiments.Comment: 16 pages, 5 figures, additional results include
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