Interfacial contribution to the dielectric response in semiconducting LaBiMn4/3Co2/3O6

Impedance measurements have been performed on a sintered polycrystalline sample of the perovskite LaBiMn4/3Co2/3O6. Colossal dielectric permittivity often is measured in this class of semiconducting materials as a result of extrinsic factors. Our results show that a large offset in the capacitance, measured on a series of samples with different thickness, is due to the interfacial polarization. This contribution then can be removed from the data, creating a general procedure for dielectric measurements in semiconducting samples.Comment: 13 pages, 4 figure

The key to the yellow-to-cyan tuning in the green fluorescent protein family is polarisation

Computational approaches have to date failed to fully capture the large (about 0.4 eV) excitation energy tuning displayed by the nearly identical anionic chromophore in different green fluorescent protein (GFP) variants. Here, we present a thorough comparative study of a set of proteins in this sub-family, including the most red- (phiYFP) and blue-shifted (mTFP0.7) ones. We employ a classical polarisable embedding through induced dipoles and combine it with time-dependent density functional theory and multireference perturbation theory in order to capture both state-specific induction contributions and the coupling of the polarisation of the protein to the chromophore transition density. The obtained results show that only upon inclusion of both these two effects generated by the mutual polarisation between the chromophore and the protein can the full spectral tuning be replicated. We finally discuss how this mutual polarisation affects the correlation between excitation energies, dipole moment variation, and molecular electrostatic field

Ferromagnetism and magneto-dielectric effect in insulating LaBiMn4/3Co2/3O6 thin films

High quality epitaxial thin films of LaBiMn4/3Co2/3O6 perovskite were fabricated on (001)-oriented SrTiO3 and LaAlO3 substrates by the pulsed laser deposition technique. Magnetization measurements reveal a strong magnetic anisotropy and a ferromagnetic behavior that is in agreement with a super-exchange interaction between Mn4+ and Co2+ ions, which are randomly distributed in the B-site. A distinct anomaly is observed in the dielectric measurements at 130K corresponding to the onset of the magnetic ordering, suggesting a coupling. Above this temperature, the extrinsic Maxwell-Wagner effect is dominating. Theses results are explained using the Raman spectroscopic studies indicating a weak spin-lattice interaction around this magnetic transition.Comment: Submitted to Appl. Phys. Lett. (2008

Conformational Transitions Accompanying Oligomerization of Yeast Alcohol Oxidase, a Peroxisomal Flavoenzyme

Alcohol oxidase (AO) is a homo-octameric flavoenzyme which catalyzes methanol oxidation in methylotrophic yeasts. AO protein is synthesized in the cytosol and subsequently sorted to peroxisomes where the active enzyme is formed. To gain further insight in the molecular mechanisms involved in AO activation, we studied spectroscopically native AO from Hansenula polymorpha and Pichia pastoris and three putative assembly intermediates. Fluorescence studies revealed that both Trp and FAD are suitable intramolecular markers of the conformation and oligomeric state of AO. A direct relationship between dissociation of AO octamers and increase in Trp fluorescence quantum yield and average fluorescence lifetime was found. The time-resolved fluorescence of the FAD cofactor showed a rapid decay component which reflects dynamic quenching due to the presence of aromatic amino acids in the FAD-binding pocket. The analysis of FAD fluorescence lifetime profiles showed a remarkable resemblance of pattern for purified AO and AO present in intact yeast cells. Native AO contains a high content of ordered secondary structure which was reduced upon FAD-removal. Dissociation of octamers into monomers resulted in a conversion of β-sheets into α-helices. Our results are explained in relation to a 3D model of AO, which was built based on the crystallographic data of the homologous enzyme glucose oxidase from Aspergillus niger. The implications of our results for the current model of the in vivo AO assembly pathway are discussed.

Local structure of REFeAsO (RE=La, Pr, Nd, Sm) oxypnictides studied by Fe K-edge EXAFS

Local structure of REOFeAs (RE=La, Pr, Nd, Sm) system has been studied as a function of chemical pressure varied due to different rare-earth size. Fe K-edge extended X-ray absorption fine structure (EXAFS) measurements in the fluorescence mode has permitted to compare systematically the inter-atomic distances and their mean square relative displacements (MSRD). We find that the Fe-As bond length and the corresponding MSRD hardly show any change, suggesting the strongly covalent nature of this bond, while the Fe-Fe and Fe-RE bond lengths decrease with decreasing rare earth size. The results provide important information on the atomic correlations that could have direct implication on the superconductivity and magnetism of REOFeAs system, with the chemical pressure being a key ingredient

Dark matter from the scalar sector of 3-3-1 models without exotic electric charges

We show that three SU(2) singlet neutral scalars (two CP-even and one CP-odd) in the spectrum of models based on the gauge symmetry SU(3)_c X SU(3)_L X U(1)_X, which do not contain exotic electric charges, are realistic candidates for thermally generated self-interacting dark matter in the Universe, a type of dark matter that has been recently proposed in order to overcome some difficulties of collisionless cold dark matter models at the galactic scale. These candidates arise without introducing a new mass scale in the model and/or without the need for a discrete symmetry to stabilize them, but at the expense of tuning several combinations of parameters of the scalar potential.Comment: RevTeX, 11 pages. v2: typos corrected, one reference added. v3: clarifications added, four more references added. To appear in Europhys. Let

Early-type Galaxies in the Hubble Deep Field. The <mu_e>-r_e relation and the lack of large galaxies at high redshift

We present the results of the detailed surface photometry of a sample of early-type galaxies in the Hubble Deep Field. Effective radii, surface brightnesses and total V_606 magnitudes have been obtained, as well as U_300, B_450, I_814, J, H and K colors, which are compared with the predictions of chemical-spectrophotometric models of population synthesis. Spectroscopic redshifts are available for 23 objects. For other 25 photometric redshifts are given. In the -r_e plane the early-type galaxies of the HDF, once the appropriate K+E corrections are applied, turn out to follow the `rest frame' Kormendy relation. This evidence, linked to the dynamical information gathered by Steidel et al.(1996), indicates that these galaxies, even at z~2-3, lie in the Fundamental Plane, in a virial equilibrium condition. At the same redshifts a statistically significant lack of large galaxies [i.e. with Log r_e(kpc) > 0.2] is observed.Comment: 30 pages, LaTeX with aasms4.sty macros, 9 embedded postscript figures + 1 postscript Table. To appear in the Astronomical Journa

Quantum Monte Carlo calculations of H2_2 dissociation on Si(001)

We present quantum Monte Carlo calculations for various reaction pathways of H$_2$ with Si(001), using large model clusters of the surface. We obtain reaction energies and energy barriers noticeably higher than those from approximate exchange-correlation functionals. In improvement over previous studies, our adsorption barriers closely agree with experimental data. For desorption, the calculations give barriers for conventional pathways in excess of the presently accepted experimental value, and pinpoint the role of coverage effects and desorption from steps.Comment: 4 pages, 1 figur

Incidence of abortion-related near-miss complications in Zambia: cross-sectional study in Central, Copperbelt and Lusaka Provinces

OBJECTIVES: To describe the magnitude and severity of abortion-related complications in health facilities and calculate the incidence of abortion-related near-miss complications at the population level in three provinces in Zambia, a country where abortion is legal but stigmatized. STUDY DESIGN: We conducted a cross-sectional study in 35 district, provincial and tertiary hospitals over 5 months. All women hospitalized for abortion-related complications were eligible for inclusion. Cases of abortion-related near-miss, moderate and low morbidity were identified using adapted World Health Organization (WHO) near-miss and the prospective morbidity methodology criteria. Incidence was calculated by annualizing the number of near-misses and dividing by the population of women of reproductive age. We calculated the abortion-related near-miss rate, abortion-related near-miss ratio and the hospital mortality index. RESULTS: Participating hospitals recorded 26,723 births during the study. Of admissions for post-abortion care, 2406 (42%) were eligible for inclusion. Near-misses constituted 16% of admitted complications and there were 14 abortion-related maternal deaths. The hospital mortality index was 3%; the abortion-related near-miss rate for the three provinces was 72 per 100,000 women, and the near-miss ratio was 450 per 100,000 live births. CONCLUSIONS: Abortion-related near-miss and mortality are challenges for the Zambian health system. Adapted to reflect health systems capabilities, the WHO near-miss criteria can be applied to routine hospital records to obtain useful data in low-income settings. Reducing avoidable maternal mortality and morbidity due to abortion requires efforts to de-stigmatize access to abortion provision, and expanded access to modern contraception. IMPLICATIONS: The abortion-related near-miss rate is high in Zambia compared with other restrictive contexts. Our results suggest that near-miss is a promising indicator of unsafe abortion; can be measured using routine hospital data, conveniently defined using the WHO criteria; and can be incorporated into the frequently utilized prospective morbidity methodology

Flutter analysis of rotary laminated composite structures using higher-order kinematics

Abstract The flutter analysis of rotary laminated structures has been performed using Carrera Unified Formulation (CUF). CUF is a one-dimensional higher-order structural model, in which the displacement at the cross-section is the only unknown parameter. The cross-sectional displacement fields of the model are defined using the Lagrange- and Taylor expansion. The quasi-steady and unsteady theories (Theodorsen and Loewy) have been used to apply the aerodynamic force. Subsequently, the equation of motion is defined in 'fundamental nucleus' form using Hamilton's principle. The engineering solution of the flutter condition has been obtained by using p-k method. The computational studies of flutter analysis have been done for various rotor hub, lamination sequence, and structural models. The regular, irregular plies and arbitrary fiber orientation of the orthotropic structures have also been considered. The present study suggests that the proposed CUF model can obtain an aeroelastic solution of rotary structure in a computationally and economically efficient manner