Point defects on graphene on metals

Understanding the coupling of graphene with its local environment is critical to be able to integrate it in tomorrow's electronic devices. Here we show how the presence of a metallic substrate affects the properties of an atomically tailored graphene layer. We have deliberately introduced single carbon vacancies on a graphene monolayer grown on a Pt(111) surface and investigated its impact in the electronic, structural and magnetic properties of the graphene layer. Our low temperature scanning tunneling microscopy studies, complemented by density functional theory, show the existence of a broad electronic resonance above the Fermi energy associated with the vacancies. Vacancy sites become reactive leading to an increase of the coupling between the graphene layer and the metal substrate at these points; this gives rise to a rapid decay of the localized state and the quenching of the magnetic moment associated with carbon vacancies in free-standing graphene layers

Assessing the influence of the carbon source on the abatement of industrial N2O emissions coupled with the synthesis of added-value bioproducts

Producción CientíficaThe continuous abatement of a synthetic N2O emission from a nitric acid plant coupled with the simultaneously production of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) copolymer and the coenzyme Q10 (CoQ10) in a bubble column reactor (BCR) was tested using methanol, glycerol and a mixture of sodium acetate-acetic acid (Ac-HAc) as a carbon and electron donor source. The BCRs were inoculated with Paracoccus denitrificans and supplied with the carbon/electron donor at a loading rate of 139 g C m− 3 d− 1. High N2O removal efficiencies (81–91%) were achieved, with glycerol supporting the highest abatement. The PHBV cell content ranged from 25 to 53%, with highest accumulation in the culture obtained with methanol and Ac-HAc. However, the greatest PHBV productivities were observed in the BCRs operated with glycerol and Ac-HAc (21.7 and 33.5 g PHBV m− 3 d− 1, respectively). Glycerol supply induced the highest molar ratio (23%) of the homopolymer 3-hydroxyvalerate in the composition of PHBV. In addition, the specific cell content of CoQ10 ranged from 0.4 to 1 mg g− 1. This work constitutes, to the best of our knowledge, the first study combining N2O abatement with the simultaneous production of multiple bioproducts, which pave the way to the development of greenhouse gas biorefineries for climate change mitigation.Ministerio de Economía, Industria y Competitividad (Project CTM2015-70442-R and Red NOVEDAR

Density and reproductive characteristics of female brown bears in the Cantabrian Mountains, NW Spain

Here we present annual nearest-neighbour distances (as a proxy of density) between females with cubs-of-the-year (hereafter FCOY) and reproductive characteristics of brown bears Ursus arctos in the Cantabrian Mountains (NW Spain), from 1989 to 2017. FCOY nearest-neighbour distances and reproduction parameters of 19 focal females followed over several consecutive years (from 2004 to 2017) were obtained from bears inhabiting the western sector of the Cantabrian Mountains, where most of the bear population resides. In contrast, general reproductive characteristics were studied in the whole Cantabrian Mountains (western and eastern sectors together) on a sample of 362 litter sizes and 695 cubs. Mean nearest-neighbour distance between FCOY was 2559 ± 1222 m (range = 1305–4757 m). Mean litter size was significantly larger in the west (1.8 ± 0.2 cubs) than in the east (1.3 ± 0.6 cubs). Mean litter size for the whole of the Cantabrian Mountains was 1.6 ± 0.3 cubs. Litter sizes of one, two and three cubs represented 33.4, 56.1 and 10.5% of observed family groups, respectively. Interannual variations in litter size were not significant for both the western and the eastern areas. Mean cub mortality was 0.2 ± 0.5 cubs and did not vary among years. Cub mortality per litter size was 3.9% for one cub, 69.2% for two cubs and 26.9% for three cubs. Mean reproductive rate of the 19 focal females was 1.5 ± 0.6 cubs (n = 58 litters). Litter size of focal FCOY did not differ from the litter size obtained from systematic observations in the whole Cantabrian Mountains. During this period, cub mortality occurred in 24.1% of the 58 litters. Females usually bred every second year (average litter interval = 2.2 years). The estimated reproductive rate for the bear population was 0.7 young born/year/reproductive adult female

Utilización inadecuada de un servicio de urgencias hospitalario. Una evaluación con criterios explícitos

ResumenFundamentoExiste un crecimiento del número de visitas en los servicios de urgencias hospitalarios (SUH) con una elevada proporción de utilización inapropiada. Los métodos empleados para identificar el uso inadecuado basados en criterios implícitos limitan las comparaciones entre hospitales. El objetivo de este estudio es conocer la proporción de visitas inadecuadas en un SUH y sus factores asociados, utilizando un método objetivo.Material y métodoSe utilizó un instrumento basado en criterios explícitos e independientes del diagnóstico para identificar las visitas inapropiadas en una muestra aleatoria de 1.845 pacientes mayores de 14 años que acudieron a los servicios médicos de un SUH, y se analizaron los factores asociados a la demanda inadecuada.ResultadosLa proporción de urgencias inadecuadas fue del 26,8% (495/1.845). En el análisis bivariante la menor edad, la ausencia de patología asociada, las visitas espontáneas y determinados grupos diagnósticos (enfermedades de la piel, músculo-esqueléticas, mentales y sintamos mal definidos) se asociaron a una mayor proporción de uso inadecuado del SUH. Al ajustar las variables mediante regresión logística, la edad, la patología asociada, las consultas espontáneas y los grupos diagnósticos, mantuvieron la asociación con el uso inadecuado, pero otras variables como el ser mujer y la llegada al SUH fuera del turno de noche también se asociaron a una mayor utilización inadecuada.ConclusionesAl menos la cuarta parte de las visitas realizadas en los servicios médicos de los SUH no requieren atención urgente. La inadecuación de las visitas se asocia a características del paciente y el proceso asistido.SummaryBackgroundSeveral studies have shown a growth in the number of visits to accident and emergency (A&E) hospital departments with a high proportion of inappropriate utilization. Methods to identify improper use based on implicit criteria limit the comparisons between hospitals. The aim of this study is to know the proportion of inappropriate attendance's in an A&E department and their associated factors, using a method with objective criteria.MethodsAn instrument based on diagnosis-independent explicit criteria was used to identify inappropriate visits in a random sample of 1845 14-year-old greater patients attended to A&E medical services, and the factors associated with improper demand were analysed.ResultsThe proportion of inappropriate attendance's was of the 26,8% (495/1.845). The unadjusted analysis show that the smaller age, absence of comorbidity, spontaneous visit and some diagnostic groups (diseases of the skin, muscle-skeletal, mental, and bad defined symptoms) were associated to a greater proportion of improper use. Upon adjusting the variables through logistics regression, the age, associated pathology, the spontaneous attendance's and diagnostic groups, maintained the association with improper use, but other variables as woman gender, and night hours were also associated to inappropriate utilization.ConclusionsAt least the fourth part of the attendance's in the A&E medical services do not require urgent attention. Inappropriate utilization is associated to characteristic of the patient and the attended process

Biogas from anaerobic digestion as an energy vector: Current upgrading development

Producción CientíficaThe present work reviews the role of biogas as advanced biofuel in the renewable energy system, summarizing the main raw materials used for biogas production and the most common technologies for biogas upgrading and delving into emerging biological methanation processes. In addition, it provides a description of current European legislative framework and the potential biomethane business models as well as the main biogas production issues to be addressed to fully deploy these upgrading technologies. Biomethane could be competitive due to negative or zero waste feedstock prices, and competitive to fossil fuels in the transport sector and power generation if upgrading technologies become cheaper and environmentally sustainable.Unión Europea - (URBIOFIN project 745785, H2020-BBI-JTI-2016)Junta de Castilla y León y Fondo Europeo de Desarrollo Regional (FEDER) - (grant CLU 2017-09

High pressure and temperature spinning capillary cell for in-situ synchrotron X-ray powder diffraction

In situ research of materials under moderate pressures (hundreds of bar) is essential in many scientific fields. These range from gas sorption to chemical and biological processes. One industrially important discipline is the hydration of oil well cements. Existing capillary cells in this pressure range are static as they are easy to design and operate. This is convenient for the study of single-phase materials; however, powder diffraction quantitative analyses for multiphase systems cannot be performed accurately as a good powder average cannot be attained. Here, the design, construction and commissioning of a cost-effective spinning capillary cell for in situ powder X-ray diffraction is reported, for pressures currently up to 200 bar. The design addresses the importance of reducing the stress on the capillary by mechanically synchronizing the applied rotation power and alignment on both sides of the capillary while allowing the displacement of the supports needed to accommodate different capillaries sizes and to insert the sample within the tube. This cell can be utilized for multiple purposes allowing the introduction of gas or liquid from both ends of the capillary. The commissioning is reported for the hydration of a commercial oil well cement at 150 bar and 150°C. The quality of the resulting powder diffraction data has allowed in situ Rietveld quantitative phase analyses for a hydrating cement containing seven crystalline phases.The design, production and commissioning of this cell was carried out at the ALBA synchrotron as part of Edmundo Fraga’s PhD project. This work was financially supported by the Spanish Ministry of Economy and Competitiveness through Grants BIA2014-57658-C2-1-R and BIA2017-82391-R which are co-funded by FEDER. We are grateful to Prof. Angus Wilkinson, Georgia Institute of Technology Atlanta, for sharing his knowledge and details on the high pressure cell developed by his team. We also thank Dr. Marcus Paul, Dyckerhoff-Lengerich, Germany, for fruitful discussion on Oil Well Cements. The cell was commissioned at BL11-NCD-SWEET beamline

Carbon dioxide fluxes across the Sierra de Guadarrama, Spain

Understanding the spatial and temporal variation in soil respiration within small geographic areas is essential to accurately assess the carbon budget on a global scale. In this study, we investigated the factors controlling soil respiration in an altitudinal gradient in a southern Mediterranean mixed pine–oak forest ecosystem in the north face of the Sierra de Guadarrama in Spain. Soil respiration was measured in five Pinus sylvestris L. plots over a period of 1 year by means of a closed dynamic system (LI-COR 6400). Soil temperature and water content were measured at the same time as soil respiration. Other soil physico-chemical and microbiological properties were measured during the study. Measured soil respiration ranged from 6.8 to 1.4 lmol m-2 s-1, showing the highest values at plots situated at higher elevation. Q10 values ranged between 1.30 and 2.04, while R10 values ranged between 2.0 and 3.6. The results indicate that the seasonal variation of soil respiration was mainly controlled by soil temperature and moisture. Among sites, soil carbon and nitrogen stocks regulate soil respiration in addition to soil temperature and moisture. Our results suggest that application of standard models to estimate soil respiration for small geographic areas may not be adequate unless other factors are considered in addition to soil temperature

Accurate photometric redshifts for the CFHT Legacy Survey calibrated using the VIMOS VLT Deep Survey

We present photometric redshifts for an uniquely large and deep sample of 522286 objects with i'_{AB}<25 in the Canada-France Legacy Survey ``Deep Survey'' fields, which cover a total effective area of 3.2 deg^2. We use 3241 spectroscopic redshifts with 0<z<5 from the VIMOS VLT Deep Survey as a calibration to derive these photometric redshifts. We devise a robust calibration method which removes systematic trends in the photometric redshifts and significantly reduces the fraction of catastrophic errors. We use our unique spectroscopic sample to present a detailed assessment of the robustness of the photometric redshift sample. For a sample selected at i'_{AB}<24, we reach a redshift accuracy of \sigma_{\Delta z/(1+z)}=0.037 with \eta=3.7% of catastrophic error. The reliability of our photometric redshifts is lower for fainter objects: we find \sigma_{\Delta z/(1+z)}=0.029, 0.043 and \eta=1.7%, 5.4% for samples selected at i'_{AB}=17.5-22.5 and 22.5-24 respectively. We find that the photometric redshifts of starburst galaxies in our sample are less reliable: although these galaxies represent only 18% of the spectroscopic sample they are responsible for 54% of the catastrophic errors. We find an excellent agreement between the photometric and the VVDS spectroscopic redshift distributions at i'_{AB}<24. Finally, we compare the redshift distributions of i' selected galaxies on the four CFHTLS deep fields, showing that cosmic variance is already present on fields of 0.8 deg^2.Comment: 19 pages, 17 figures, submitted to A&A. The photometric redshifts described in this paper will be made publicly available from 1st may 2006 at http://terapix.iap.fr and http://cencosw.oamp.fr