Planetary Spectrum Generator: an accurate online radiative transfer suite for atmospheres, comets, small bodies and exoplanets

We have developed an online radiative-transfer suite (https://psg.gsfc.nasa.gov) applicable to a broad range of planetary objects (e.g., planets, moons, comets, asteroids, TNOs, KBOs, exoplanets). The Planetary Spectrum Generator (PSG) can synthesize planetary spectra (atmospheres and surfaces) for a broad range of wavelengths (UV/Vis/near-IR/IR/far-IR/THz/sub-mm/Radio) from any observatory (e.g., JWST, ALMA, Keck, SOFIA), any orbiter (e.g., ExoMars, Juno), or any lander (e.g., MSL). This is achieved by combining several state-of-the-art radiative transfer models, spectroscopic databases and planetary databases (i.e., climatological and orbital). PSG has a 3D (three-dimensional) orbital calculator for most bodies in the solar system, and all confirmed exoplanets, while the radiative-transfer models can ingest billions of spectral signatures for hundreds of species from several spectroscopic repositories. It integrates the latest radiative-transfer and scattering methods in order to compute high resolution spectra via line-by-line calculations, and utilizes the efficient correlated-k method at moderate resolutions, while for computing cometary spectra, PSG handles non-LTE and LTE excitation processes. PSG includes a realistic noise calculator that integrates several telescope / instrument configurations (e.g., interferometry, coronagraphs) and detector technologies (e.g., CCD, heterodyne detectors, bolometers). Such an integration of advanced spectroscopic methods into an online tool can greatly serve the planetary community, ultimately enabling the retrieval of planetary parameters from remote sensing data, efficient mission planning strategies, interpretation of current and future planetary data, calibration of spectroscopic data, and development of new instrument/spacecraft concepts.Comment: Journal of Quantitative Spectroscopy and Radiative Transfer, submitte

The volatile composition of comet C/2017 K2 (PanSTARRS)

We present high resolution spectra of comet C/2017 K2 (PanSTARRS) (hereafter 17K2), obtained using the upgraded high resolution spectrometer of the VLT, CRIRES+. We will show our findings in the (2.8 - 5.3) μm range, searching for primary volatiles (e.g., H2O, HCN, NH3, CO, C2H6, CH4, ...) and studying their evolution as the comet approach the Sun. 17K2 is a long period comet, very active already at record heliocentric distances of 16 au, and represents a unique opportunity to study the composition of a mostly unaltered comet.Comets formed from the material surrounding the proto-Sun about 4.6 billion years ago, and after their formation they were scattered into their current reservoirs [1,2], where the frozen nuclei have preserved most of the chemical and mineralogical properties linked to their formation site until today. Probing the chemical diversity in comets may thus unveil the processes that were in effect within the mid-plane of our proto-planetary disk, and test the hypothesis that comets may have contributed in delivering water and prebiotics to the early Earth [3].Among other techniques, the composition of active comets can be studied from ground based telescopes using high resolution spectroscopy in the infrared (IR - 3 to 5 μm), where it is possible to observe emission lines produced by solar-pumped fluorescence of primary species, i.e., molecules released directly from the nucleus. High spectral and spatial resolutions are necessary to resolve different molecular species in the spectra, to study their distribution within the coma and to separate emission lines of the comet from their counterpart in the atmosphere.Comet 17K2 is in excellent observing conditions in 2022, allowing infrared high resolution studies. The comet shows already activity, probably driven by CO and other hyper-volatiles that can sublimate at distances from the Sun larger than 5 au [4,5]. Discovered in 2017 at about 16 au from the Sun [6], it is most likely entering the inner solar system for the first time, and its observation offers a unique opportunity to study its mostly unaltered material.We will present the results obtained from different spectra acquired using CRIRES+ at ESO-VLT at various epochs. We acquired comprehensive high-resolution spectra of the comet as it progressively moved towards the Sun, with the goal of monitoring the evolution of sublimating material with the heliocentric distance. In particular, we have granted time at the beginning of May, beginning of July, and end of August 2022, with the Sun-17K2 distance varying from about 3.5 to 2.3 au. In this heliocentric range, the comet is crossing the CO to H2O ice sublimation regime [7].Data are reduced using custom semi-automated procedures (see [8] and references therein) that allow a fast analysis of the spectra. Spectral calibration and compensation for telluric absorption are achieved by comparing the data with highly accurate atmospheric radiance and transmittance models obtained with PUMAS/PSG [9]. Flux calibration is obtained using the spectra of a standard star observed closely in time with the comet, and reduced with the same algorithms. Production rates and relative abundances (i.e. mixing ratios with respect to water) of different primary species in the coma are obtained using state-of-the-art fluorescence models (see for example [10] and [11]).The molecular abundances found in this comet will be compared to reference median values retrieved for the comet population [12] and with the abundances found in other Oort Cloud Comets

Polymethylferrocene-induced photopolymerization of cyanoacrylates using visible and near-infrared light

Metallocene-induced photopolymerization of cyanoacrylates based on electron transfer processes has been proposed as an alternative to more conventional light-curing strategies relying on photobase generators. However, successful application of this methodology has so far only been achieved for very reactive cyanoacrylates under UV illumination and long irradiation times, which eventually hampers its practical use. To overcome these limitations, we describe in this work the use of electron-rich polymethylferrocenes as photoinitiators, with which fast light-induced polymerization of commercial formulations of less reactive, but more relevant long alkyl chain cyanoacrylates has been accomplished by illumination with visible and even near-infrared light. In addition, generalization of this technology to other electron-deficient, noncyanoacrylate monomers has been demonstrated. The low oxidation potential of polymethylferrocenes accounts for these excellent results, which strongly favors the formation of radical anions by electron transfer that initiate the polymerization reaction. Because of the high molecular weight and superior adhesive behavior of the resulting polymer materials as well as the facile access to polymethylferrocenes, they emerge as very attractive photoinitiators for the light-curing of cyanoacrylate (and other) glues in real applications

Detailed Analysis of Near-IR Water (H2O) Emission in Comet C/2014 Q2 (LOVEJOY) with the GIANO/TNG Spectrograph

We observed the Oort cloud comet C/2014 Q2 (Lovejoy) on 2015 January 31 and February 1 and 2 at a heliocentric distance of 1.3 au and geocentric distance of 0.8 au during its approach to the Sun. Comet Lovejoy was observed with GIANO, the near-infrared high-resolution spectrograph mounted at the Nasmyth-A focus of the TNG (Telescopio Nazionale Galileo) telescope in La Palma, Canary Islands, Spain. We detected strong emissions of radical CN and water, along with many emission features of unidentified origin, across the 1-2.5 μm region. Spectral lines from eight ro-vibrational bands of H2O were detected, six of them for the first time. We quantified the water production rate [Q(H2O), (3.11 ± 0.14) × 1029 s-1] by comparing the calibrated line fluxes with the Goddard full non-resonance cascade fluorescence model for H2O. The production rates of ortho-water [Q(H2O)ORTHO, (2.33 ± 0.11) × 1029 s-1] and para-water [Q(H2O)PARA, (0.87 ± 0.21) × 1029 s-1] provide a measure of the ortho-to-para ratio (2.70 ± 0.76)). The confidence limits are not small enough to provide a critical test of the nuclear spin temperature

Distant activity of 67P/Churyumov-Gerasimenko in 2014: Ground-based results during the Rosetta pre-landing phase

Context. As the ESA Rosetta mission approached, orbited, and sent a lander to comet 67P/Churyumov-Gerasimenko in 2014, a large campaign of ground-based observations also followed the comet. Aims. We constrain the total activity level of the comet by photometry and spectroscopy to place Rosetta results in context and to understand the large-scale structure of the comet’s coma pre-perihelion. Methods. We performed observations using a number of telescopes, but concentrate on results from the 8 m VLT and Gemini South telescopes in Chile. We use R-band imaging to measure the dust coma contribution to the comet’s brightness and UV-visible spectroscopy to search for gas emissions, primarily using VLT/FORS. In addition we imaged the comet in near-infrared wavelengths (JHK) in late 2014 with Gemini-S/Flamingos-2. Results. We find that the comet was already active in early 2014 at heliocentric distances beyond 4 au. The evolution of the total activity (measured by dust) followed previous predictions. No gas emissions were detected despite sensitive searches. Conclusions. The comet maintains a similar level of activity from orbit to orbit, and is in that sense predictable, meaning that Rosetta results correspond to typical behaviour for this comet. The gas production (for CN at least) is highly asymmetric with respect to perihelion, as our upper limits are below the measured production rates for similar distances post-perihelion in previous orbits

Synergies between ground-based and space-based observations in the solar system and beyond

The goal of this white paper is to provide examples where ground-based and space-based observations are combined, and used to obtain understanding or constrain parameters beyond what the separate measurements could yield

The Comet Interceptor Mission

Here we describe the novel, multi-point Comet Interceptor mission. It is dedicated to the exploration of a little-processed long-period comet, possibly entering the inner Solar System for the first time, or to encounter an interstellar object originating at another star. The objectives of the mission are to address the following questions: What are the surface composition, shape, morphology, and structure of the target object? What is the composition of the gas and dust in the coma, its connection to the nucleus, and the nature of its interaction with the solar wind? The mission was proposed to the European Space Agency in 2018, and formally adopted by the agency in June 2022, for launch in 2029 together with the Ariel mission. Comet Interceptor will take advantage of the opportunity presented by ESA’s F-Class call for fast, flexible, low-cost missions to which it was proposed. The call required a launch to a halo orbit around the Sun-Earth L2 point. The mission can take advantage of this placement to wait for the discovery of a suitable comet reachable with its minimum ΔV capability of 600 ms−1. Comet Interceptor will be unique in encountering and studying, at a nominal closest approach distance of 1000 km, a comet that represents a near-pristine sample of material from the formation of the Solar System. It will also add a capability that no previous cometary mission has had, which is to deploy two sub-probes – B1, provided by the Japanese space agency, JAXA, and B2 – that will follow different trajectories through the coma. While the main probe passes at a nominal 1000 km distance, probes B1 and B2 will follow different chords through the coma at distances of 850 km and 400 km, respectively. The result will be unique, simultaneous, spatially resolved information of the 3-dimensional properties of the target comet and its interaction with the space environment. We present the mission’s science background leading to these objectives, as well as an overview of the scientific instruments, mission design, and schedule