Nonlinear shock acceleration beyond the Bohm limit

We suggest a physical mechanism whereby the acceleration time of cosmic rays by shock waves can be significantly reduced. This creates the possibility of particle acceleration beyond the knee energy at ~10^15eV. The acceleration results from a nonlinear modification of the flow ahead of the shock supported by particles already accelerated to the knee momentum at p ~ p_*. The particles gain energy by bouncing off converging magnetic irregularities frozen into the flow in the shock precursor and not so much by re-crossing the shock itself. The acceleration rate is thus determined by the gradient of the flow velocity and turns out to be formally independent of the particle mean free path (m.f.p.). The velocity gradient is, in turn, set by the knee-particles at p ~ p_* as having the dominant contribution to the CR pressure. Since it is independent of the m.f.p., the acceleration rate of particles above the knee does not decrease with energy, unlike in the linear acceleration regime. The reason for the knee formation at p ~ p_* is that particles with $p > p_*$ are effectively confined to the shock precursor only while they are within limited domains in the momentum space, while other particles fall into ``loss-islands'', similar to the ``loss-cone'' of magnetic traps. This structure of the momentum space is due to the character of the scattering magnetic irregularities. They are formed by a train of shock waves that naturally emerge from unstably growing and steepening magnetosonic waves or as a result of acoustic instability of the CR precursor. These losses steepen the spectrum above the knee, which also prevents the shock width from increasing with the maximum particle energy.Comment: aastex, 13 eps figure

The Evolution of Hydrocarbons in Saturn's Northern Storm Region

The massive storm at 40N on Saturn that began in December 2010 has produced significant and lasting effects in the northern hemisphere on temperature and species abundances (Fletcher et aL 2011). The northern storm region was observed on several occasions between March 2011 and April 2012 by Cassini's Composite Infrared Spectrometer (CIRS) at a spectral resolution (0.5/cm) which permits the study of trace species in Saturn's stratosphere. During this time period, stratospheric temperatures in regions referred to as "beacons" (warm regions at specific longitudes at the latitude of the storm) became significantly warmer than pre-storm values of 140K, peaking near 220K, and subsequently cooling. These warm temperatures led to greatly enhanced infrared emission due to C4H2, C3H4, C2H2, and C2H6 in the stratosphere as well as the first detection of C2H4 on Saturn in the thermal infrared (Hesman et al. 2012). Using CH4 as a thermometer of Saturn's stratosphere in the beacon regions, we can derive the mixing ratios of each of these molecules. The most common hydrocarbons (C2H2 and C2H6) serve as dynamical tracers on Saturn and their abundances may constrain vertical motion in the stratosphere. All of these hydrocarbons are products of methane photolysis. Since many of the photochemical reactions that produce heavier hydrocarbons such as C4H2 and C3H4 are temperature sensitive, the beacon region provides a natural laboratory for studying these reactions on Saturn. We will discuss the time evolution of the abundances of each of these hydrocarbons from their pre-storm values, through the period of maximum heating , and during the period of cooling that is taking place in Saturn's stratosphere

A current driven instability in parallel, relativistic shocks

Recently, Bell has reanalysed the problem of wave excitation by cosmic rays propagating in the pre-cursor region of a supernova remnant shock front. He pointed out a strong, non-resonant, current-driven instability that had been overlooked in the kinetic treatments, and suggested that it is responsible for substantial amplification of the ambient magnetic field. Magnetic field amplification is also an important issue in the problem of the formation and structure of relativistic shock fronts, particularly in relation to models of gamma-ray bursts. We have therefore generalised the linear analysis to apply to this case, assuming a relativistic background plasma and a monoenergetic, unidirectional incoming proton beam. We find essentially the same non-resonant instability noticed by Bell, and show that also under GRB conditions, it grows much faster than the resonant waves. We quantify the extent to which thermal effects in the background plasma limit the maximum growth rate.Comment: 8 pages, 1 figur

Measurements of the stable carbon isotope composition of dissolved inorganic carbon in the northeastern Atlantic and Nordic Seas during summer 2012

The stable carbon isotope composition of dissolved inorganic carbon (δ13CDIC) in seawater was measured in a batch process for 552 samples collected during two cruises in the northeastern Atlantic and Nordic Seas from June to August 2012. One cruise was part of the UK Ocean Acidification research programme, and the other was a repeat hydrographic transect of the Extended Ellett Line. In combination with measurements made of other variables on these and other cruises, these data can be used to constrain the anthropogenic component of dissolved inorganic carbon (DIC) in the interior ocean, and to help to determine the influence of biological carbon uptake on surface ocean carbonate chemistry. The measurements have been processed, quality-controlled and submitted to an in-preparation global compilation of seawater δ13CDIC data, and are available from the British Oceanographic Data Centre. The observed δ13CDIC values fall in a range from −0.58 to +2.37 ‰, relative to the Vienna Pee Dee Belemnite standard. The mean of the absolute differences between samples collected in duplicate in the same container type during both cruises and measured consecutively is 0.10 ‰, which corresponds to a 1σ uncertainty of 0.09 ‰, and which is within the range reported by other published studies of this kind. A crossover analysis was performed with nearby historical δ13CDIC data, indicating that any systematic offsets between our measurements and previously published results are negligible. Data doi:10.5285/09760a3a-c2b5-250b-e053-6c86abc037c0 (northeastern Atlantic), doi:10.5285/09511dd0-51db-0e21-e053-6c86abc09b95 (Nordic Seas)

Distributions of dissolved trace metals (Cd, Cu, Mn, Pb, Ag) in the southeastern Atlantic and the Southern Ocean

International audienceComprehensive synoptic datasets (surface water down to 4000 m) of dissolved cadmium (Cd), copper (Cu), manganese (Mn), lead (Pb) and silver (Ag) are presented along a section between 34° S and 57° S in the southeastern Atlantic Ocean and the Southern Ocean to the south off South Africa. The vertical distributions of Cu and Ag display nutrient-like profiles similar to silicic acid, and of Cd similar to phosphate. The distribution of Mn shows a subsurface maximum in the oxygen minimum zone, whereas Pb concentrations are rather invariable with depth. Dry deposition of aerosols is thought to be an important source of Pb to surface waters close to South Africa, and dry deposition and snowfall may have been significant sources of Cu and Mn at the higher latitudes. Furthermore, the advection of water masses enriched in trace metals following contact with continental margins appeared to be an important source of trace elements to the surface, intermediate and deep waters in the southeastern Atlantic Ocean and the Antarctic Circumpolar Current. Hydrothermal inputs may have formed a source of trace metals to the deep waters over the Bouvet Triple Junction ridge crest, as suggested by relatively enhanced dissolved Mn concentrations. The biological utilization of Cu and Ag was proportional to that of silicic acid across the section, suggesting that diatoms formed an important control over the removal of Cu and Ag from surface waters. However, uptake by dino- and nano-flagellates may have influenced the distribution of Cu and Ag in the surface waters of the subtropical Atlantic domain. Cadmium correlated strongly with phosphate (P), yielding lower Cd / P ratios in the subtropical surface waters where phosphate concentrations were below 0.95 μM. The greater depletion of Cd relative to P observed in the Weddell Gyre compared to the Antarctic Circumpolar Current could be due to increase Cd uptake induced by iron-limiting conditions in these high-nutrient-low-chlorophyll waters. Similarly, an increase of Mn uptake under Fe-depleted conditions may have caused the highest depletion of Mn relative to P in the surface waters of the Weddell Gyre. In addition, a cellular Mn-transport channel of Cd was possibly activated in the Weddell Gyre, which in turn may have yielded depletion of both Mn and Cd in these surface waters

Intercomparison of carbonate chemistry measurements on a cruise in northwestern European shelf seas

Four carbonate system variables were measured in surface waters during a cruise aimed at investigating ocean acidification impacts traversing northwestern European shelf seas in the summer of 2011. High-resolution surface water data were collected for partial pressure of carbon dioxide (pCO2; using two independent instruments) and pH using the total pH scale (pHT), in addition to discrete measurements of total alkalinity and dissolved inorganic carbon. We thus overdetermined the carbonate system (four measured variables, two degrees of freedom), which allowed us to evaluate the level of agreement between the variables on a cruise whose main aim was not intercomparison, and thus where conditions were more representative of normal working conditions. Calculations of carbonate system variables from other measurements generally compared well with direct observations of the same variables (Pearson’s correlation coefficient always greater than or equal to 0.94; mean residuals were similar to the respective accuracies of the measurements). We therefore conclude that four of the independent data sets of carbonate chemistry variables were of high quality. A diurnal cycle with a maximum amplitude of 41 μatm was observed in the difference between the pCO2 values obtained by the two independent analytical pCO2 systems, and this was partly attributed to irregular seawater flows to the equilibrator and partly to biological activity inside the seawater supply and one of the equilibrators. We discuss how these issues can be addressed to improve carbonate chemistry data quality on future research cruises

EVOLUTION OF THE STRATOSPHERIC TEMPERATURE AND CHEMICAL COMPOSITION OVER ONE TITANIAN YEAR

Since the Voyager 1 (V1) flyby in 1980, Titans exploration from space and the ground has been ongoing for more than a full revolution of Saturn around the Sun (one Titan year or 29.5 Earth years was completed in May 2010). In this study we search for temporal variations affecting Titans atmospheric thermal and chemical structure within that year. We process Cassini CIRS data taken during the Titan flybys from 2006-2013 and compare them to the 1980 V1IRIS spectra (re-analyzed here). We also consider data from Earth-based and -orbiting observatories (such as from the ISO, re-visited). When we compare the CIRS 2010 and the IRIS data we find limited inter-annual variations, below the 25 or35 levels for the lower and middle, or the high latitudes, respectively. A return to the 1980 stratospheric temperatures and abundances is generally achieved from 50degN to 50degS, indicative of the solar radiation being the dominating energy source at 10 AU, as for the Earth, as predicted by GCM and photochemical models. However, some exceptions exist among the most complex hydrocarbons (C4H2 and C3H4), especially in the North. In the Southern latitudes, since 2012, we see a trend for an increase of several trace gases, possibly indicative of a seasonal atmospheric reversal. At the Northern latitudes we found enhanced abundances around the period of the northern spring equinox in mid-2009 (as in Bampasidis et al. 2012), which subsequently decreased (from 2010-2012) returning to values similar to those found in the V1 epoch a Titanian year before

Types, aspects, and impact of relocation initiatives deployed within and between long-term care facilities:A scoping review

Relocation of residents within or between long-term care facilities occurs regularly. To mitigate potential negative consequences, supportive relocation initiatives have been developed. This scoping review addresses types, aspects, and impact of relocation initiatives developed to relocate residents between or within long-term care facilities. A total of 704 articles were identified in a systematic literature search of 11 databases between April and July 2021. Using predefined eligibility criteria, two researchers independently screened titles and abstracts, resulting in 36 articles for full-text screening. Finally, six articles were included. Analysis was performed using thematic coding. Three types of relocation initiatives were identified, namely, interventions (n = 3), guidelines (n = 2), and a plan (n = 1). These initiatives described specific aspects of relocation, namely, spatial orientation (n = 3), practical assistance (n = 3), psychological support (n = 3), staff preparation (n = 2), and client engagement (n = 2). Only three intervention studies reported the impact of relocation initiatives on residents, namely, improved mental health (n = 3), spatial orientation (n = 2), self-reliance (n = 2), and social behavior (n = 1). The scope of the found relocation initiatives was often limited as they focused on specific designs, aspects, and residents. Therefore, the complexity of relocation processes is often overlooked, and more comprehensive relocation initiatives should be developed

The great barrier reef: A source of CO2 to the atmosphere

Highlights • Seasonal variations in air-sea CO2 fluxes on the Great Barrier Reef reveal a strong CO2 release during the early-dry season. • The Great Barrier Reef is overall a net source of CO2. • CO2 fluxes are largely controlled by cross-shelf advection of oversaturated warm surface waters from the Coral Sea. Abstract The Great Barrier Reef (GBR) is the largest contiguous coral reef system in the world. Carbonate chemistry studies and flux quantification within the GBR have largely focused on reef calcification and dissolution, with relatively little work on shelf-scale CO2 dynamics. In this manuscript, we describe the shelf-scale seasonal variability in inorganic carbon and air-sea CO2 fluxes over the main seasons (wet summer, early dry and late dry seasons) in the GBR. Our large-scale dataset reveals that despite spatial-temporal variations, the GBR as a whole is a net source of CO2 to the atmosphere, with calculated air–sea fluxes varying between −6.19 and 12.17 mmol m−2 d−1 (average ± standard error: 1.44 ± 0.15 mmol m−2 d−1), with the strongest release of CO2 occurring during the wet season. The release of CO2 to the atmosphere is likely controlled by mixing of Coral Sea surface water, typically oversaturated in CO2, with the warm shelf waters of the GBR. This leads to oversaturation of the GBR system relative to the atmosphere and a consequent net CO2 release