Absolute dimensions of eclipsing binaries. XVII. A metal-weak F-type system, perhaps with preference for Y = 0.23-0.24

V1130 Tau is a bright (m_V = 6.56), nearby (71 +/- 2 pc) detached system with a circular orbit (P = 0.80d). The components are deformed with filling factors above 0.9. Their masses and radii have been established to 0.6-0.7%. We derive a [Fe/H] abundance of -0.25 +/- 0.10. The measured rotational velocities, 92.4 +/- 1.1 (primary) and 104.7 +/- 2.7 (secondary) km/s, are in fair agreement with synchronization. The larger 1.39 Msun secondary component has evolved to the middle of the main-sequence band and is slightly cooler than the 1.31 Msun primary. Yonsai-Yale, BaSTI, and Granada evolutionary models for the observed metal abundance and a 'normal' He content of Y = 0.25-0.26, marginally reproduce the components at ages between 1.8 and 2.1 Gyr. All such models are, however, systematically about 200 K hotter than observed and predict ages for the more massive component, which are systematically higher than for the less massive component. These trends can not be removed by adjusting the amount of core overshoot or envelope convection level, or by including rotation in the model calculations. They may be due to proximity effects in V1130 Tau, but on the other hand, we find excellent agreement for 2.5-2.8 Gyr Granada models with a slightly lower Y of 0.23-0.24. V1130 Tau is a valuable addition to the very few well-studied 1-2 Msun binaries with component(s) in the upper half of the main-sequence band, or beyond. The stars are not evolved enough to provide new information on the dependence of core overshoot on mass (and abundance), but might - together with a larger sample of well-detached systems - be useful for further tuning of the helium enrichment law.Comment: Accepted for publication in Astronomy & Astrophysic

Extraction of silymarin compounds from milk thistle (Silybum marianum) seed using hot, liquid water as the solvent

High-value specialty chemicals are usually obtained from natural products by extracting with generally regarded as safe (GRAS) solvents. Because organic solvents are quite often used, high operating and disposal costs occur. When compared to traditional solvents, water is an interesting alternative because of its low operating and disposal costs. Milk thistle contains compounds (taxifolin, silychristin, silydianin, silybinin A, and silybinin B) that display hepatoxic protection properties. This paper examines the batch extraction of silymarin compounds from milk thistle seed meal in 50°C, 70°C, 85°C and 100°C water as a function of time. For taxifolin, silychristin, silybinin A, and silybinin B, extraction with 100°C water resulted in the highest yields. After 210 min of extraction at 100°C, the yield of taxifolin was 1.2 mg/g of seed while the yields of silychristin, silybinin A, and silybinin B were 5.0, 1.8 and 3.3 mg/g of seed, respectively. The ratios of the extracted compounds, and particularly the ratios at long extraction times, showed that the more polar compounds (taxifolin and silychristin) were preferentially extracted at 85°C, while the less polar silybinin was preferentially extracted at 100°C

A Study to Test the Effectiveness of Time-out in the Decrease of Moderate Stuttering

The purpose of this study was to examine the effect of time-out from speaking on the frequency of moderate stuttering. Two parallel single subject studies were carried out concurrently. Two adult moderate stutterers were selected as subjects. Two sessions of baserate measurement were followed by nine sessions in which 10 seconds of time-out from speaking was made contingent upon the stuttering of Subject A. Subject B was the control subject for the first nine sessions and he received no consequences for stuttering. With session twelve, Subject A became the control and Subject B was required to stop speaking for 10 seconds following each stuttering behavior. Time-out from speaking, signalled by a red light, was instituted contingent upon subject stuttering. Results of the study showed the rate of stuttering decreased during the use of time-out procedures. Stuttering was shown to increase when time-out from speaking was withdrawn as a consequence for stuttering. It was concluded that the time-out from speaking used in this study was effective in reducing stuttering behavior

Absolute dimensions of eclipsing binaries. XXVIII. BK Pegasi and other F-type binaries: Prospects for calibration of convective core overshoot

We present a detailed study of the F-type detached eclipsing binary BK Peg, based on new photometric and spectroscopic observations. The two components, which have evolved to the upper half of the main-sequence band, are quite different with masses and radii of (1.414 +/- 0.007 Msun, 1.988 +/- 0.008 Rsun) and (1.257 +/- 0.005 Msun, 1.474 +/- 0.017 Rsun), respectively. The 5.49 day period orbit of BK Peg is slightly eccentric (e = 0.053). The measured rotational velocities are 16.6 +/- 0.2 (primary) and 13.4 +/- 0.2 (secondary) km/s. For the secondary component this corresponds to (pseudo)synchronous rotation, whereas the primary component seems to rotate at a slightly lower rate. We derive an iron abundance of [Fe/H] =-0.12 +/- 0.07 and similar abundances for Si, Ca, Sc, Ti, Cr and Ni. Yonsei-Yale and Victoria-Regina evolutionary models for the observed metal abundance reproduce BK Peg at ages of 2.75 and 2.50 Gyr, respectively, but tend to predict a lower age for the more massive primary component than for the secondary. We find the same age trend for three other upper main-sequence systems in a sample of well studied eclipsing binaries with components in the 1.15-1.70 Msun range, where convective core overshoot is gradually ramped up in the models. We also find that the Yonsei-Yale models systematically predict higher ages than the Victoria-Regina models. The sample includes BW Aqr, and as a supplement we have determined a [Fe/H] abundance of -0.07 +/- 0.11 for this late F-type binary. We propose to use BK Peg, BW Aqr, and other well-studied 1.15-1.70 Msun eclipsing binaries to fine-tune convective core overshoot, diffusion, and possibly other ingredients of modern theoretical evolutionary models.Comment: Accepted for publication in Astronomy and Astrophysic

A 200-year 210Pb record from Greenland

A continuous profile of 210Pb activity extending back to 1766 has been developed for a firn/ice core collected at Site D in central Greenland in 1984. Unexpectedly high activities of 210Pb were found at the base of this core (0.032 pCi kg−1 in samples more than 200 years old), calling into question the common assumption that supported 210Pb can be neglected when constructing chronologies in glacial snow and ice. It is problematic to assert that all of the 210Pb measured at depth should be attributed to the supported fraction, given previous estimates of dust loading in Greenland ice cores. However, even if an estimated constant value of 0.032 pCi supported210Pb kg−1 is subtracted from the measured values to estimate excess 210Pb, the 210Pb chronology for Site D yields ages that are significantly younger (mean accumulation rate too high) than an independent depth-age scale based on annual layer counting. It is apparent that the flux of excess and/or supported 210Pb to this site must have decreased over the past 2 centuries, with decreasing trends in both fractions most likely. Previously published 210Pb profiles for cores from Summit and Dye 3, Greenland, show similar trends, which had been interpreted as decreasing fluxes of excess 210Pb only. For all three sites, it is not possible to separate variations in the fluxes of the excess and supported fractions of 210Pb, but variations in the total 210Pb flux will impact 210Pb-based chronologies generally if these variations have not been restricted to the Greenland ice sheet